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8.20196 EMD Millipore

METHYL BROMOACETATE

METHYL BROMOACETATE FOR SYNTHESIS. CAS 96-32-2, EC Number 202-499-2, chemical formula BrCH₂COOCH₃., FOR SYNTHESIS

Synonym: Bromoacetic acid methyl ester

  • CAS Number 96-32-2

  • Linear Formula C₃H₅BrO₂

  • Molecular Weight 152.98 g/mol

  •  EC Number 202-499-2

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Properties

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packaging   100 ml in Glass bottle (8201960100)
bp   144 - 146 °C (1013 hPa)
vapor pressure   18 hPa (50 °C)
density   1.65 g/cm3 (20 °C)
flash point   64 °C
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (GC, area%): ≥ 97.0 % (a/a)
  Density (d 20 °C/ 4 °C): 1.653 - 1.658
  Identity (IR): passes test

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Safety & Documentation

Safety Information

HS Code 
2915 90 70
Hazard Statement(s) 
H301: Toxic if swallowed.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H335: May cause respiratory irritation.
Precautionary Statement(s) 
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Storage class 
6.1A Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK 
WGK 2 water endangering
Disposal 
9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Symbols 
Corrosive  Corrosive
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 2643 , 6.1, II
Declaration (transport by air) IATA-DGR 
UN 2643 , 6.1, II
Declaration (transport by sea) IMDG-Code 
UN 2643 , 6.1, II
Categories of danger 
toxic, irritant
R Phrase 
R 25-34-37-43
Toxic if swallowed.Causes burns.Irritating to respiratory system.May cause sensitisation by skin contact.
S Phrase 
S 9-26-36/37/39-45
Keep container in a well-ventilated place.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
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