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8.20876 EMD Millipore

Raney nickel catalyst

activated for hydrogenation (with about 50% water) for synthesis

Synonym: Nickel catalyst acc. Raney

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Properties

packaging   100 g in Plastic bottle (8208760100)
  250 g in Plastic bottle (8208760250)
density   >1.2 g/cm3
pH   9 - 11 (H₂O, 20 °C) suspension
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay of Ni, calc. on dried substance: ≥ 90.0 %
  Assay od Al, calc. on dried substance: ≤ 10.0 %
  Suitable for hydrogenation catalyst: passes test

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Safety & Documentation

Safety Information

HS Code 
3815 11 00
Hazard Statement(s) 
H251: Self-heating: may catch fire.
H351: Suspected of causing cancer.
H372: Causes damage to organs through prolonged or repeated exposure.
H317: May cause an allergic skin reaction.
H412: Harmful to aquatic life with long lasting effects.
Precautionary Statement(s) 
P273: Avoid release to the environment.
P281: Use personal protective equipment as required.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P308 + P313: IF exposed or concerned: Get medical advice/ attention.
Storage class 
4.2 Pyrophoric and self-heating hazardous materials
WGK 
WGK 2 water endangering
Disposal 
26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS07  GHS07
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 1378 , 4.2, II
Declaration (transport by air) IATA-DGR 
UN 1378 , 4.2, II
Declaration (transport by sea) IMDG-Code 
UN 1378 , 4.2, II
Categories of danger 
carcinogenic, highly flammable, sensitizing, toxic, dangerous for the environment
R Phrase 
R 40-43-48/23-52/53
Limited evidence of a carcinogenic effect.May cause sensitisation by skin contact.Toxic: danger of serious damage to health by prolonged exposure through inhalation.Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase 
S 15-36/37-45-61
Keep away from heat.Wear suitable protective clothing and gloves.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).Avoid release to the environment. Refer to special instructions/ Safety data sheets.
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