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8.20967 EMD Millipore

tert-Butyl perbenzoate

tert-Butyl perbenzoate for synthesis. CAS 614-45-9, EC Number 210-382-2, chemical formula C₆H₅COOOC(CH₃)₃., for synthesis

Synonym: Perbenzoic acid tert-butyl ester, Peroxybenzoic acid tert-butyl ester

  • CAS Number 614-45-9

  • Linear Formula C₁₁H₁₄O₃

  • Molecular Weight 194.22 g/mol

  •  EC Number 210-382-2

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Properties

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packaging   250 ml in Plastic bottle (8209670250)
vapor pressure   0.43 hPa (50 °C)
density   1.04 g/cm3 (20 °C)
flash point   98 °C
mp   9 - 11 °C
LD 50 oral   LD50 Rat > 2000 mg/kg
LD 50 dermal   LD50 Rabbit > 2000 mg/kg
shipped in   ambient
storage temp.   Store at +15°C to +25°C.
specifications   Assay (iodometric): ≥ 98.0 %
  Density (d 20 °C/ 4 °C): 1.040 - 1.044
  Identity (IR): passes test
  Due to its specific melting range the product may be solid, liquid, a solidified melt or a supercooled melt.

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Safety & Documentation

Safety Information

HS Code 
2916 39 90
Hazard Statement(s) 
H242: Heating may cause a fire.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H332: Harmful if inhaled.
H410: Very toxic to aquatic life with long lasting effects.
Precautionary Statement(s) 
P273: Avoid release to the environment.
P280: Wear protective gloves.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
RTECS 
SD 9450000
Storage class 
4.1A Other explosive hazardous materials
WGK 
WGK 3 highly water endangering
Disposal 
10
Organic peroxides can be detected in aqueous solutions or organic solvents using the Perex-Test® (Cat. No. 116206). Pure peroxides are diluted to min. 10% in a suitable solvent or with water and added in small portions, with temperature control, to iron(II) chloride (Cat. No. 103860) solution. Test for complete reaction with the Perex-Test® (Cat. No. 116206). Container D. Explosive substances (storage class 4.1A) should be packed separately and tightly sealed for disposal. Ensure sufficient phlegmatization by water or the stated phlegmatizing agent!
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS07  GHS07
Hazard Pictogram(s) 
GHS09  GHS09
Hazard Symbols 
Explosive  Explosive
Hazard Symbols 
Dangerous for the environment  Dangerous for the environment
Hazard Symbols 
Harmful  Harmful
Declaration (railroad and road) ADR, RID 
UN 3103 , 5.2,
Declaration (transport by air) IATA-DGR 
UN 3103 , 5.2,
Declaration (transport by sea) IMDG-Code 
UN 3103 , 5.2,
Categories of danger 
explosive, oxidizing, irritant
R Phrase 
R 2- 7-20-38-43-50/53
Risk of explosion by shock, friction, fire or other sources of ignition.May cause fire.Harmful by inhalation.Irritating to skin.May cause sensitisation by skin contact.Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S Phrase 
S 3/7-14-36/37/39-61
Keep container tightly closed in a cool place.Keep away from reducing agents, heavy-metal compounds, acids and alkalis.Wear suitable protective clothing, gloves and eye/face protection.Avoid release to the environment. Refer to special instructions/ Safety data sheets.
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