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8.40069 EMD Millipore

Tetrakis(hydroxymethyl)phosphonium chloride

(aqueous solution) for synthesis

Synonym: Tetramethylolphosphonium chloride

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Properties

packaging   500 ml in Glass bottle (8400690500)
density   1.341 g/cm3
flash point   96 °C
autoignition temp.   301 °C
pH   3.5 - 4.5 (H₂O)
LD 50 oral   LD50 Rat 50 - 200 mg/kg
LD 50 dermal   LD50 Rabbit 1000 - 2000 mg/kg
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (argentometric): 76.0 - 78.0 %

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Safety & Documentation

Safety Information

HS Code 
2931 39 90
Hazard Statement(s) 
H300: Fatal if swallowed.
H311: Toxic in contact with skin.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
Precautionary Statement(s) 
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
Storage class 
6.1A Combustible substances, toxic
WGK 
WGK 3 highly water endangering
Disposal 
9
Carcinogenic compounds and flammable compounds labelled "Highly toxic" or "Toxic": container F. Alkyl sulfates are carcinogenic; Take particular care to avoid inhalation and skin contact. To neutralize alkyl sulfates, add dropwise (from a dropping funnel) to concentrated ice-cool Ammonia solution (Cat.No. 105426) with vigorous stirring. Before placing in container D, check the pH with pH Universal indicator strips (Cat.No. 109535).
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS06  GHS06
Hazard Symbols 
Toxic  Toxic
Declaration (railroad and road) ADR, RID 
UN 2810 , 6.1, II
Declaration (transport by air) IATA-DGR 
UN 2810 , 6.1, II
Declaration (transport by sea) IMDG-Code 
UN 2810 , 6.1, II
Categories of danger 
toxic, irritant, corrosive, sensitizing
R Phrase 
R 25-34-43
Toxic if swallowed.Causes burns.May cause sensitisation by skin contact.
S Phrase 
S 26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
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