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8.41132 EMD Millipore

(1S)-(-)-ß-Pinene

(1S)-(-)-ß-Pinene for synthesis. CAS 18172-67-3, molar mass 136.23 g/mol., for synthesis

Synonym: (1S)-6,6-Dimethyl-2-methylenebicyclo[3.1.1]heptane

  • CAS Number 18172-67-3

  • Linear Formula C₁₀H₁₆

  • Molecular Weight 136.23 g/mol

  •  EC Number 242-060-2

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Properties

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packaging   100 ml in Glass bottle (8411320100)
vapor pressure   6.9 hPa (20 °C)
solubility   6.95 mg/l immiscible
density   0.872 g/cm3 (20 °C)
flash point   39 °C
autoignition temp.   255 °C
mp   -61 °C
LD 50 oral   LD50 Rat 4700 mg/kg
shipped in   ambient
storage temp.   Store at <= 20°C.
specifications   Assay (GC, area%): ≥ 98.0 % (a/a)
  Density (d 20 °C/ 4 °C): 0.869 - 0.873
  Spec. rotation [α²0/D (undiluted): -22.0 - -19.0 °
  Identity (IR): passes test

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Safety & Documentation

Safety Information

HS Code 
2902 19 00
Hazard Statement(s) 
H226: Flammable liquid and vapour.
H302 + H312 + H332: Harmful if swallowed, in contact with skin or if inhaled
H304: May be fatal if swallowed and enters airways.
H315: Causes skin irritation.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H411: Toxic to aquatic life with long lasting effects.
Precautionary Statement(s) 
P210: Keep away from heat.
P273: Avoid release to the environment.
P280: Wear protective gloves.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P331: Do NOT induce vomiting.
RTECS 
DT 5077000
Storage class 
3 Flammable liquids
WGK 
WGK 2 water endangering
Disposal 
3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS07  GHS07
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Pictogram(s) 
GHS09  GHS09
Hazard Symbols 
Dangerous for the environment  Dangerous for the environment
Hazard Symbols 
Harmful  Harmful
Declaration (railroad and road) ADR, RID 
UN 1993 , 3, II
Declaration (transport by air) IATA-DGR 
UN 1993 , 3, II
Declaration (transport by sea) IMDG-Code 
UN 1993 , 3, II
Categories of danger 
flammable, harmful, irritant, sensitizing, dangerous for the environment
R Phrase 
R 10-20/21/22-36/38-43-51/53-65
Flammable.Harmful by inhalation, in contact with skin and if swallowed.Irritating to eyes and skin.May cause sensitisation by skin contact.Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.Harmful: may cause lung damage if swallowed.
S Phrase 
S 36/37-46-61-62
Wear suitable protective clothing and gloves.If swallowed, seek medical advice immediately and show this container or label.Avoid release to the environment. Refer to special instructions/ Safety data sheets.If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
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