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8.43668 EMD Millipore

Potassium bis(trimethylsilyl)amide

(0.5 molar solution in toluene) for synthesis

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Properties

packaging   100 ml in Glass bottle (8436680100)
expl. lim.     1 - 7.1 %(V)
vapor pressure   29 hPa (20 °C)
density   0.867 g/cm3 (20 °C)
flash point   7 °C
autoignition temp.   535 °C toluene
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (acidimetric): 0.4 - 0.6 mol/l

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Safety & Documentation

Safety Information

HS Code 
3824 99 92
Hazard Statement(s) 
H225: Highly flammable liquid and vapour.
H304: May be fatal if swallowed and enters airways.
H314: Causes severe skin burns and eye damage.
H336: May cause drowsiness or dizziness.
H361d: Suspected of damaging the unborn child.
H373: May cause damage to organs through prolonged or repeated exposure.
EUH014: Reacts violently with water.
Precautionary Statement(s) 
P210: Keep away from heat/sparks/open flames/hot surfaces. No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P331: Do NOT induce vomiting.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
P403 + P235: Store in a well-ventilated place. Keep cool.
Storage class 
3 Flammable liquids
WGK 
WGK 3 highly water endangering
Disposal 
8
Hydrolysis-sensitive organoelement compounds and metal alkyls, which are as a rule dissolved in organic solvents, should be carefully stirred dropwise into 1-butanol (Cat. No. 822262) in a hood with the front screen closed. Any flammable gases formed should be fed via a tube directly into the extractor duct. When gas development has ceased, continue stirring for one hour and add an excess of water. Container A.
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS07  GHS07
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Symbols 
Corrosive  Corrosive
Hazard Symbols 
Flammable  Flammable
Declaration (railroad and road) ADR, RID 
UN 2924 , 3 (8), II
Declaration (transport by air) IATA-DGR 
UN 2924 , 3 (8), II
Declaration (transport by sea) IMDG-Code 
UN 2924 , 3 (8), II, Segregation Group: 18 (Alkalis)
Categories of danger 
highly flammable, corrosive, harmful, toxic for reproduction
R Phrase 
R 11-14-34-48/20-63-65-67
Highly flammable.Reacts violently with water.Causes burns.Harmful: danger of serious damage to health by prolonged exposure through inhalation.Possible risk of harm to the unborn child.Harmful: may cause lung damage if swallowed.Vapours may cause drowsiness and dizziness.
S Phrase 
S 26-36/37/39-45
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
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