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8.43838 EMD Millipore

Triphenylphosphine copper(I) hydride

Triphenylphosphine copper(I) hydride hexamer for synthesis. CAS 33636-93-0, chemical formula (C₆H₅)₃PCuH₆., hexamer for synthesis

  • CAS Number 33636-93-0

  • Linear Formula C₁₀₈H₉₆Cu₆P₆

  • Molecular Weight 1961.08 g/mol

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Properties

packaging   5 g in Glass bottle (8438380005)
shipped in   ambient
storage temp.   Store below +30°C.
specifications   Assay (Cu): ≥ 97.0 %

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Safety Information

HS Code 
2931 39 90
Hazard Statement(s) 
H228: Flammable solid.
Storage class 
4.1B Flammable solid hazardous materials
WGK 
WGK 3 highly water endangering
Disposal 
26
Alkali and alkaline-earth metals should be taken up in an inert solvent and neutralized by adding 2-propanol (Cat. No. 100995) dropwise with stirring. Should the reaction be more violent than expected, conversion should be carried out with tert-butanol or octanol. Caution: This reaction produces hydrogen, which can form explosive mixtures; take necessary precautions. When the reaction has ceased, add water dropwise; neutralize; container D. In the case of alkali or alkaline-earth borohydrides, add methanol (Cat. No. 106008) with stirring; in the case of alkali or alkaline-earth amides and hydrides, organoaluminium and organotin hydrides, add 2-propanol (Cat. No. 100995) dropwise. The substances, which are usually in solid form, should be previously suspended in an ether! When the respective reaction has ceased, hydrolize with water; then neutralize. Container D or E. Lithium aluminium hydride must also be destroyed by slurrying in an ether. Under an inert gas and with thorough stirring, add dropwise a 1:4 mixture of ethyl acetate (Cat. No. 822277) and the ether used to prepare the slurry. Always ensure thorough mixing (stirring)! Container A.
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Symbols 
Flammable  Flammable
Declaration (railroad and road) ADR, RID 
UN 3182 , 4.1, III
Declaration (transport by air) IATA-DGR 
UN 3182 , 4.1, III
Declaration (transport by sea) IMDG-Code 
UN 3182 , 4.1, III
Categories of danger 
highly flammable
R Phrase 
R 11
Highly flammable.
S Phrase 
S 16
Keep away from sources of ignition - No smoking.
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