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8.45120 EMD Millipore

Piperazine (anhydrous)

Piperazine (anhydrous) Msynth®plus. CAS 110-85-0, pH 12 (150 g/l, H₂O, 20 °C)., Msynth®plus

  • CAS Number 110-85-0

  • Linear Formula C₄H₁₀N₂

  • Molecular Weight 86.14 g/mol

  •  EC Number 203-808-3

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Properties

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packaging   250 g in Plastic bottle (8451200250)
vapor pressure   15 hPa (50 °C)
solubility   150 g/l
density   1.1 g/cm3 (20 °C)
mp   107 - 111 °C
pH   12 (150 g/l, H₂O, 20 °C)
bulk density   400 kg/m3
LD 50 oral   LD50 Rat 2600 mg/kg
LD 50 dermal   LD50 Rabbit 8300 mg/kg
storage temp.   Store below +30°C.
specifications   Colour (visual): white
  Appearance of substance (visual): chips
  Assay (GC, area%): ≥ 99.5 % (a/a)
  Melting range (lower value): ≥ 109 °C
  Melting range (upper value): ≤ 112 °C
  Water (K. F.): ≤ 1.00 %
  Identity (IR): passes test

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Safety & Documentation

Safety Information

HS Code 
2933 59 95
Hazard Statement(s) 
H228: Flammable solid.
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H361fd: Suspected of damaging fertility. Suspected of damaging the unborn child.
Precautionary Statement(s) 
P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P280: Wear protective gloves/ protective clothing/ eye protection/ face protection.
P301 + P330 + P331: IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P302 + P352: IF ON SKIN: Wash with plenty of soap and water.
P304 + P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308 + P310: IF exposed or concerned: immediately call a POISON CENTER or doctor/ physician.
RTECS 
TK7800000
Storage class 
8A Combustible, corrosive hazardous materials
WGK 
WGK 1 slightly water endangering
Disposal 
3
Relatively unreactive organic reagents should be collected in container A. If halogenated, they should be collected in container B. For solid residues use container C.
Hazard Pictogram(s) 
GHS02  GHS02
Hazard Pictogram(s) 
GHS05  GHS05
Hazard Pictogram(s) 
GHS08  GHS08
Hazard Symbols 
Corrosive  Corrosive
Hazard Symbols 
Flammable  Flammable
Hazard Symbols 
Harmful  Harmful
Declaration (railroad and road) ADR, RID 
UN 2579 , 8, III
Declaration (transport by air) IATA-DGR 
UN 2579 , 8, III
Declaration (transport by sea) IMDG-Code 
UN 2579 , 8, III, Segregation Group: 18 (Alkalis)
Categories of danger 
corrosive, sensitizing, toxic for reproduction
R Phrase 
R 34-42/43-62-63-11
Causes burns.May cause sensitisation by inhalation and skin contact.Possible risk of impaired fertility.Possible risk of harm to the unborn child.Highly flammable.
S Phrase 
S 22-26-36/37/39-45
Do not breathe dust.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Wear suitable protective clothing, gloves and eye/face protection.In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
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