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02610 Sigma-Aldrich

Ethyl dimethylphosphonoacetate

technical, ≥90% (GC)

Synonym: Ethoxycarbonylmethylphosphonic acid dimethylester, Phosphonoacetic acid P,P-dimethyl ethylester

  • CAS Number 311-46-6

  • Linear Formula (CH3O)2P(O)CH2COOC2H5

  • Molecular Weight 196.14

  •  Beilstein Registry Number 1777603

  •  EC Number 206-222-6

  •  MDL number MFCD00015677

  •  PubChem Substance ID 329747474

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Properties

Related Categories C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents More...
InChI Key   HUNISAHOCCASGM-UHFFFAOYSA-N
grade   technical
assay   ≥90% (GC)
refractive index   n20/D 1.435(lit.)
  n20/D 1.435
bp   134 °C/10 mmHg(lit.)
density   1.188 g/mL at 25 °C(lit.)

Description

Other Notes

Horner-Wittig reagent

Application

Reactant for synthesis of:
• Non-nucleoside inhibitors of HCV polymerase NS5B
• Neuropeptide Y1 receptor antagonists
• Alkenylcarboxylates from Horner-Wadsworth-Emmons reactions

Reactant for:
• Enantioselective transfer hydrogenation for preparation of the C7-C14 fragment of ulapualide A
• Intramolecular Michael reactions
• Olefination of peptidyl aldehydes with stabilized ylides

Price and Availability

Safety & Documentation

Safety Information

Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
210.2 °F
Flash Point(C) 
99 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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