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13220 Sigma-Aldrich

Manganese(II) chloride monohydrate

≥97.0%

Synonym: Manganese dichloride monohydrate

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Manganese More...
InChI Key   BXRRQHBNBXJZBQ-UHFFFAOYSA-L
assay   ≥97.0%
impurities   ≤0.01% heavy metals (as Pb)
anion traces   sulfate (SO42-): ≤1000 mg/kg
cation traces   Fe: ≤200 mg/kg

Description

Application

Starting material for preparation of organomanganese chloride reagents; in combination with RLi or RMgX catalyzes reduction of vinyl and aryl halides, stereoselective coupling of vinyl iodides, and alkylation of enol triflates; also used for Mn-Cu-catalyzed conjugate addition of RMgX to enones and for Mn-catalyzed acylation of RMgX by acyl chlorides; in combination with NaBH4 is diastereoselective reducing agent; starting material for the preparation of Mn enolates regio- andstereo-selectively.

Price and Availability


Cross-Coupling Guide
Safety & Documentation

Safety Information

Symbol 
GHS07  GHS07
Signal word 
Warning
Hazard statements 
Personal Protective Equipment 
RIDADR 
NONH for all modes of transport
WGK Germany 
1
Protocols & Articles
Peer-Reviewed Papers
15

References

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