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14602 Sigma-Aldrich

Zirconium

≥97.0% Zr + Hf basis, powder

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Properties

Related Categories Catalysis and Inorganic Chemistry, Chemical Synthesis, Zirconium More...
assay   ≥97.0% Zr + Hf basis
form   powder
resistivity   40 μΩ-cm, 20°C
impurities   ≤3% hafnium (Hf)
bp   4377 °C(lit.)
mp   1852 °C(lit.)
density   6.5 g/mL at 25 °C(lit.)

Description

Packaging

bottled under inert gas

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Safety & Documentation

Safety Information

Symbol 
GHS02  GHS02
Signal word 
Danger
Hazard statements 
Precautionary statements 
Hazard Codes (Europe) 
F
Risk Statements (Europe) 
Safety Statements (Europe) 
7/8-43
RIDADR 
UN 2008 4.2 / PGII
WGK Germany 
nwg
RTECS 
ZH7070000

Protocols & Articles

Articles

Introduction to PAGE

Polyacrylamide gels are formed by the reaction of acrylamide and bis-acrylamide (N,N’-methylenebisacrylamide) that results in highly cross-linked gel matrix. The gel acts as a sieve through which the...
Keywords: Buffers, Cell disruption, Electrophoresis, Gel electrophoresis, PAGE, Protein electrophoresis, Sample preparations, Separation, Western blot

Peer-Reviewed Papers

References

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Coordinating radiometals of copper, gallium, indium, yttrium, and zirconium for PET and SPECT imaging of disease. Wadas TJ, Wong EH, Weisman GR, et al. Chem. Rev. 110(5), 2858-902, (2010)

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1-Benzyl-1,2,3,4-tetrahydroisoquinoline as a parkinsonism-inducing agent: a novel endogenous amine in mouse brain and parkinsonian CSF. Kotake Y, Tasaki Y, Makino Y, et al. J. Neurochem. 65(6), 2633-8, (1995)

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The rise of metal radionuclides in medical imaging: copper-64, zirconium-89 and yttrium-86. Ikotun OF and Lapi SE Future Med. Chem. 3(5), 599-621, (2011)

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Reliability and failure modes of two Y-TZP abutment designs. Mitsias ME, Thompson VP, Pines M, et al. Int. J. Prosthodont. 28(1), 75-8, (2015)

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Biophysics: using sound to move cells. Marx V Nature Methods 12(1), 41-4, (2015)

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[PET radiopharmaceuticals: novelties and new possibilities]. Környei J, Mikecz P, and Tóth G Magy. Onkol. 58(4), 245-50, (2014)

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Microtensile bond strength of lithium disilicate ceramics to resin adhesives. Aboushelib MN and Sleem D J. Adhes. Dent. 16(6), 547-52, (2014)

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Self-adhesive resin cements: adhesive performance to indirect restorative ceramics. Zorzin J, Belli R, Wagner A, et al. J. Adhes. Dent. 16(6), 541-6, (2014)

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Bond strength and monomer conversion of indirect composite resin restorations, Part 1: Light vs heat polymerization. Malta DA, Magne P, and Monteiro-Junior S J. Adhes. Dent. 16(6), 517-22, (2014)

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Selective infiltrated etching to surface treat zirconia using a modified glass agent. Jiang T, Chen C, and Lv P J. Adhes. Dent. 16(6), 553-7, (2014)

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Earth history. U-Pb geochronology of the Deccan Traps and relation to the end-Cretaceous mass extinction. Schoene B, Samperton KM, Eddy MP, et al. Science 347(6218), 182-4, (2015)

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Annotating STEAP1 regulation in prostate cancer with 89Zr immuno-PET. Doran MG, Watson PA, Cheal SM, et al. J. Nucl. Med. 55(12), 2045-9, (2014)

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A 21-year-old patient with a HER2-positive colorectal cancer. Bensch F, van Rooijen JM, Schröder CP, et al. Gastroenterology 148(1), 20-1, (2015)

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Effect of sodium zirconium cyclosilicate on potassium lowering for 28 days among outpatients with hyperkalemia: the HARMONIZE randomized clinical trial. Kosiborod M, Rasmussen HS, Lavin P, et al. JAMA 312(21), 2223-33, (2014)

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Zirconium cyclosilicate for treatment of hyperkalemia. Dixon BS JAMA 312(21), 2217-8, (2014)

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Glypican-3-targeting F(ab')2 for 89Zr PET of hepatocellular carcinoma. Sham JG, Kievit FM, Grierson JR, et al. J. Nucl. Med. 55(12), 2032-7, (2014)

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Emerging ceramic-based materials for dentistry. Denry I and Kelly JR J. Dent. Res. 93(12), 1235-42, (2014)

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Sequential enrichment with titania-coated magnetic mesoporous hollow silica microspheres and zirconium arsenate-modified magnetic nanoparticles for the study of phosphoproteome of HL60 cells. Yu QW, Li XS, Xiao Y, et al. J. Chromatogr. A 1365, 54-60, (2014)

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Comparison of marginal fit of Lava CAD/CAM crown-copings with two finish lines. Re D, Cerutti F, Augusti G, et al. Int. J. Esthet. Dent. 9(3), 426-35, (2014)

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An overview of zirconia dental implants: basic properties and clinical application of three cases. Bankoğlu Güngör M, Aydın C, Yılmaz H, et al. J. Oral Implantol. 40(4), 485-94, (2014)

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A modular labeling strategy for in vivo PET and near-infrared fluorescence imaging of nanoparticle tumor targeting. Pérez-Medina C, Abdel-Atti D, Zhang Y, et al. J. Nucl. Med. 55(10), 1706-11, (2014)

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Extreme masking: achieving predictable outcomes in challenging situations with lithium disilicate bonded restorations. Hatai Y Int. J. Esthet. Dent. 9(2), 206-22, (2014)

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Comparison of fracture resistance and fracture characterization of bilayered zirconia/fluorapatite and monolithic lithium disilicate all ceramic crowns. Altamimi AM, Tripodakis AP, Eliades G, et al. Int. J. Esthet. Dent. 9(1), 98-110, (2014)

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Degradation of phenol via wet-air oxidation over CuO/CeO2-ZrO2 nanocatalyst synthesized employing ultrasound energy: physicochemical characterization and catalytic performance. Parvas M, Haghighi M, and Allahyari S Environ. Technol. 35(9-12), 1140-9, (2014)

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Glypican-3-targeted 89Zr PET imaging of hepatocellular carcinoma: where antibody imaging dares to tread. Marquez BV, Zheleznyak A, and Lapi SE J. Nucl. Med. 55(5), 708-9, (2014)

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Using CAD/CAM technology to create a 10-unit zirconia fixed partial denture--a UTHSCSA dental school case report. Zimmermann R, Seitz S, Magness B, et al. Tex. Dent. J. 130(10), 1039-44, (2013)

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Use of high translucency zirconia in the aesthetic zone. Ritter RG Dent. Today 32(9), 116, 118-9, (2013)

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Evaluation of the adaptation of zirconia-based fixed partial dentures using micro-CT technology. Borba M, Miranda WG, Cesar PF, et al. Braz. Oral Res. 27(5), 396-402, (2013)

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Clinical evaluation of 1,132 zirconia-based single crowns: a retrospective cohort study from the AIOP clinical research group. Monaco C, Caldari M, and Scotti R Int. J. Prosthodont. 26(5), 435-42, (2013)

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The osseointegration of zirconia dental implants. Assal PA Schweiz. Monatsschr. Zahnmed. 123(7-8), 644-54, (2013)

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Creation of the final abutment before surgery in immediate tooth replacement: two different approaches to obtain a customized zirconia abutment. Mintrone F and Sighinolfi I Eur. J. Esthet. Dent. 8(3), 398-412, (2013)

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New CAD/CAM materials and blocks for chairside procedures. Zimmermann M, Mehl A, and Reich S Int. J. Comput. Dent. 16(2), 173-81, (2013)

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CAD/CAM single retainer zirconia-ceramic resin-bonded fixed dental prostheses: clinical outcome after 5 years. Sasse M and Kern M Int. J. Comput. Dent. 16(2), 109-18, (2013)

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Air abrasion of zirconia resin-bonded fixed dental prostheses prior to adhesive cementation: why and how? Ozcan M J. Adhes. Dent. 15(4), 394, (2013)

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Removing all-ceramic restorations with lasers. Cranska JP Dent. Today 32(6), 101-2, 104, (2013)

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[New bipolar electrosurgical tools based on zirconium dioxide]. Belov SV, Borik MA, Danileĭko IuK, et al. Med. Tekh. (2), 20-4, (2013)

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An ideal full-arch tooth replacement option: CAD/CAM zirconia screw-retained implant bridge. Tischler M, Ganz SD, and Patch C Dent. Today 32(5), 98-102, (2013)

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The enigma of the bilayered zirconia restoration. Keough BE, Sager RD, Kay HB, et al. Dent. Today 32(5), 68, 70-2; quiz 73, (2013)

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Surgical, biologic and implant-related factors affecting bone remodeling around implants. Capelli M Eur. J. Esthet. Dent. 8(2), 279-313, (2013)

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Effect of particle deposition parameters on silica coating of zirconia using a chairside air-abrasion device. Ozcan M, Raadschelders J, Vallittu P, et al. J. Adhes. Dent. 15(3), 211-4, (2013)

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Effect of surface conditioning modalities on the repair bond strength of resin composite to the zirconia core / veneering ceramic complex. Ozcan M, Valandro LF, Pereira SM, et al. J. Adhes. Dent. 15(3), 207-10, (2013)

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Evaluation and comparison of the internal fit and marginal accuracy of base metal (nickelchromium) and zirconia copings before and after ceramic veneering: a sem study. Regish KM, Sharma D, Prithviraj DR, et al. Eur. J. Prosthodont. Restor. Dent. 21(1), 44-8, (2013)

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Effect of artificial saliva and pH on shear bond strength of resin cements to zirconia-based ceramic. Geramipanah F, Majidpour M, Sadighpour L, et al. Eur. J. Prosthodont. Restor. Dent. 21(1), 5-8, (2013)

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Placental growth factor (PlGF)-specific uptake in tumor microenvironment of 89Zr-labeled PlGF antibody RO5323441. Oude Munnink TH, Tamas KR, Lub-de Hooge MN, et al. J. Nucl. Med. 54(6), 929-35, (2013)

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PET tracers based on Zirconium-89. Zhang Y, Hong H, and Cai W Curr. Radiopharm. 4(2), 131-9, (2011)

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Zirconium for esthetic rehabilitation: an overview. Raut A, Rao PL, and Ravindranath T Indian J. Dent. Res. 22(1), 140-3, (2011)

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Edentulous jaws rehabilitation with yttrium-stabilized zirconium dioxide implants: two years follow-up experience. Borgonovo AE, Arnaboldi O, Censi R, et al. Minerva Stomatol. 59(7-8), 381-92, (2010)

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[An electrosurgical tool on the basis of nanostructured dioxide zirconium crystals for dissection and coagulation of biological tissues]. Belov SV, Borik MA, Danileĭko IuK, et al. Med. Tekh. (4), 1-5, (2010)

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Elevated levels of methylmalonate and homocysteine in Parkinson's disease, progressive supranuclear palsy and amyotrophic lateral sclerosis. Levin J, Bötzel K, Giese A, et al. Dement. Geriatr. Cogn. Disord. 29(6), 553-9, (2010)

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Clinical applications of oxidized zirconium. Sheth NP, Lementowski P, Hunter G, et al. J. Surg. Orthop. Adv. 17(1), 17-26, (2008)

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Metals and oxidative stress in patients with Parkinson's disease. Forte G, Alimonti A, Pino A, et al. Ann. Ist. Super. Sanita 41(2), 189-95, (2005)

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Plasma beta-phenylethylamine in Parkinson's disease. Miura Y Kurume Med. J. 47(4), 267-72, (2000)

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One-pot anti-Markovnikov hydroamination of unactivated alkenes by hydrozirconation and amination. Strom AE and Hartwig JF J. Org. Chem. 78(17), 8909-14, (2013)

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Behavior and impact of zirconium in the soil-plant system: plant uptake and phytotoxicity. Shahid M, Ferrand E, Schreck E, et al. Rev. Environ. Contam. Toxicol. 221, 107-27, (2013)

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Alpha-tocopherol in the ventricular cerebrospinal fluid of Parkinson's disease patients: dose-response study and correlations with plasma levels. Pappert EJ, Tangney CC, Goetz CG, et al. Neurology 47(4), 1037-42, (1996)

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Liquid chromatography with amperometric detection at a nano crystalline Ce-doped lead dioxide film modified electrode for determination of (R)-Salsolinol, (R)-N-methylsalsolinol and monoamine neurotransmitters in Parkinsonian patients' cerebrospinal fluid. Zhang W, Xie Y, Gu J, et al. Analyst 129(3), 229-34, (2004)

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Zirconium: biomedical and nephrological applications. Lee DB, Roberts M, Bluchel CG, et al. ASAIO J. 56(6), 550-6, (2010)

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Oxidative dehydrogenation of n-butane over magnesium vanadate nano-catalysts supported on magnesia-zirconia: effect of vanadium content. Lee JK, Hong UG, Yoo Y, et al. J. Nanosci. Nanotechnol. 13(12), 8110-5, (2013)

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Markers of dopamine metabolism in Parkinson's disease. The Parkinson Study Group. LeWitt PA, Galloway MP, Matson W, et al. Neurology 42(11), 2111-7, (1992)

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Immediate loading of screw-retained all-ceramic crowns in immediate versus delayed single implant placement. Vandeweghe S, Nicolopoulos C, Thevissen E, et al. Int. J. Prosthodont. 26(5), 458-64, (2013)

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Amino acids and biogenic amines in cerebrospinal fluid of patients with Parkinson's disease. Engelborghs S, Marescau B, and De Deyn PP Neurochem. Res. 28(8), 1145-50, (2003)

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Fabrication of solution-processed InSnZnO/ZrO2 thin film transistors. Hwang SM, Lee SM, Choi JH, et al. J. Nanosci. Nanotechnol. 13(11), 7774-8, (2013)

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High temperature oxidation of ZrO2/Al2O3 thin films deposited on steel. Lee JC, Kim SK, Van Trung T, et al. J. Nanosci. Nanotechnol. 13(11), 7561-7, (2013)

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Cell death of dopamine neurons in aging and Parkinson's disease. Naoi M and Maruyama W Mech. Ageing Dev. 111(2-3), 175-88, (1999)

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Alteration of 8-hydroxyguanosine concentrations in the cerebrospinal fluid and serum from patients with Parkinson's disease. Abe T, Isobe C, Murata T, et al. Neurosci. Lett. 336(2), 105-8, (2003)

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A prospective pilot study of (89)Zr-J591/prostate specific membrane antigen positron emission tomography in men with localized prostate cancer undergoing radical prostatectomy. Osborne JR, Green DA, Spratt DE, et al. J. Urol. 191(5), 1439-45, (2014)

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Mapping strain rate dependence of dislocation-defect interactions by atomistic simulations. Fan Y, Osetskiy YN, Yip S, et al. Proc. Natl. Acad. Sci. U. S. A. 110(44), 17756-61, (2013)

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Mechanical resistance of zirconium implant abutments: a review of the literature. Velázquez-Cayón R, Vaquero-Aguilar C, Torres-Lagares D, et al. Med. Oral Patol. Oral Cir. Bucal 17(2), e246-50, (2012)

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Applying PET to broaden the diagnostic utility of the clinically validated CA19.9 serum biomarker for oncology. Viola-Villegas NT, Rice SL, Carlin S, et al. J. Nucl. Med. 54(11), 1876-82, (2013)

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Efficacy of surface treatments on the bond strength of resin cements to two brands of zirconia ceramic. Baldissara P, Querzè M, Monaco C, et al. J. Adhes. Dent. 15(3), 259-67, (2013)

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Evaluation of a commercial primer for bonding of zirconia to two different resin composite cements. Chen C, Xie H, Song X, et al. J. Adhes. Dent. 16(2), 169-76, (2014)

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Glypican-3-targeted 89Zr PET imaging of hepatocellular carcinoma. Sham JG, Kievit FM, Grierson JR, et al. J. Nucl. Med. 55(5), 799-804, (2014)

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High-temperature-pressure polymerized resin-infiltrated ceramic networks. Nguyen JF, Ruse D, Phan AC, et al. J. Dent. Res. 93(1), 62-7, (2014)

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Optical metal-organic framework sensor for selective discrimination of some toxic metal ions in water. Shahat A, Hassan HM, and Azzazy HM Anal. Chim. Acta 793, 90-8, (2013)

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Trypsin functionalization and zirconia coating of mesoporous silica nanotubes for matrix-assisted laser desorption/ionization mass spectrometry analysis of phosphoprotein. Zhang X, Wang F, and Xia Y J. Chromatogr. A 1306, 20-6, (2013)

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Direct-immersion solid-phase microextraction coupled to fast gas chromatography mass spectrometry as a purification step for polycyclic aromatic hydrocarbons determination in olive oil. Purcaro G, Picardo M, Barp L, et al. J. Chromatogr. A 1307, 166-71, (2013)

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Influence of dental materials on dental MRI. Tymofiyeva O, Vaegler S, Rottner K, et al. Dentomaxillofac. Radiol. 42(6), 20120271, (2013)

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Markers of dopamine depletion and compensatory response in striatum and cerebrospinal fluid. Loeffler DA, LeWitt PA, DeMaggio AJ, et al. J. Neural Transm. Park. Dis. Dement. Sect. 9(1), 45-53, (1995)

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Shock absorption capacity of restorative materials for dental implant prostheses: an in vitro study. Menini M, Conserva E, Tealdo T, et al. Int. J. Prosthodont. 26(6), 549-56, (2013)

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Zirconia implants supporting overdentures: a pilot study with novel prosthodontic designs. Osman RB, Payne AG, Duncan W, et al. Int. J. Prosthodont. 26(3), 277-81, (2013)

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Presence of N-methyl-norsalsolinol in the CSF: correlations with dopamine metabolites of patients with Parkinson's disease. Moser A, Scholz J, Nobbe F, et al. J. Neurol. Sci. 131(2), 183-9, (1995)

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The use of oxidized zirconium alloy in knee arthroplasty. Heyse TJ, Haas SB, and Efe T Expert Rev. Med. Devices 9(4), 409-21, (2012)

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Preparation and evaluation of Zr-beta-FeOOH for efficient arsenic removal. Sun X, Hu C, and Qu J J. Environ. Sci. (China) 25(4), 815-22, (2013)

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A comparative study of Mn/CeO2, Mn/ZrO2 and Mn/Ce-ZrO2 for low temperature selective catalytic reduction of NO with NH3 in the presence of SO2 and H2O. Shen B, Zhang X, Ma H, et al. J. Environ. Sci. (China) 25(4), 791-800, (2013)

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Simulated body fluid electrochemical response of Zr-based metallic glasses with different degrees of crystallization. Huang CH, Huang JC, Li JB, et al. Mater. Sci. Eng. C. Mater. Biol. Appl. 33(7), 4183-7, (2013)

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Electrophoretic bilayer deposition of zirconia and reinforced bioglass system on Ti6Al4V for implant applications: an in vitro investigation. Ananth KP, Suganya S, Mangalaraj D, et al. Mater. Sci. Eng. C. Mater. Biol. Appl. 33(7), 4160-6, (2013)

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Fabrication and characterization of a zirconia/multi-walled carbon nanotube mesoporous composite. Wang Z, Xia J, Xia Y, et al. Mater. Sci. Eng. C. Mater. Biol. Appl. 33(7), 3931-4, (2013)

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In vitro evaluation of osteoconductivity and cellular response of zirconia and alumina based ceramics. Pandey AK, Pati F, Mandal D, et al. Mater. Sci. Eng. C. Mater. Biol. Appl. 33(7), 3923-30, (2013)

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Nitrite and malondialdehyde content in cerebrospinal fluid of patients with Parkinson's disease. Shukla R, Rajani M, Srivastava N, et al. Int. J. Neurosci. 116(12), 1391-402, (2006)

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Preparation of graphene-ZrO2 nanocomposites by heat treatment and photocatalytic degradation of organic dyes. Cho BH and Ko WB J. Nanosci. Nanotechnol. 13(11), 7625-30, (2013)

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Control of the visible emission in the SrZrO3 nano-crystals with the rare earth ion doping. Kim DH, Kim JH, Chung JS, et al. J. Nanosci. Nanotechnol. 13(11), 7572-6, (2013)

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Effect of transition metal dopants on mechanical properties and biocompatibility of zirconia ceramics. Oh GJ, Park SW, Yun KD, et al. J. Nanosci. Nanotechnol. 13(6), 4252-5, (2013)

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The effect of thai glutinous rice starch on the synthesis of lead zirconate (PbZrO3) nanofibers via the electrospinning method. Nawanil C, Vittayakorn W, Muanghua R, et al. J. Nanosci. Nanotechnol. 13(5), 3700-4, (2013)

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Perovskite phase formation of monosized lead zirconate (PbZrO3) nanoparticles prepared by the sono-assisted co-precipitation method. Charoonsuk P and Vittayakorn N J. Nanosci. Nanotechnol. 13(5), 3529-34, (2013)

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Impact of nano and bulk ZrO2, TiO2 particles on soil nutrient contents and PGPR. Karunakaran G, Suriyaprabha R, Manivasakan P, et al. J. Nanosci. Nanotechnol. 13(1), 678-85, (2013)

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Three-dimensional accuracy of CAD/CAM titanium and ceramic superstructures for implant abutments using spiral scan microtomography. Prasad R and Al-Kheraif AA Int. J. Prosthodont. 26(5), 451-7, (2013)

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Effective dose to staff members in a positron emission tomography/CT facility using zirconium-89. Alzimami KS and Ma AK Br. J. Radiol. 86(1030), 20130318, (2013)

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Shear bond strength in zirconia veneered ceramics using two different surface treatments prior veneering. Gasparić LB, Schauperl Z, and Mehulić K Coll. Antropol. 37(1), 121-5, (2013)

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Effect of polishing and finishing procedures on the surface integrity of restorative ceramics. Odatsu T, Jimbo R, Wennerberg A, et al. Am. J. Dent. 26(1), 51-5, (2013)

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Treatment of congenitally missing maxillary lateral incisors: an interdisciplinary approach. Jackson BJ and Slavin MR J. Oral Implantol. 39(2), 187-92, (2013)

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Meta-analysis of bonding effectiveness to zirconia ceramics. Inokoshi M, De Munck J, Minakuchi S, et al. J. Dent. Res. 93(4), 329-34, (2014)

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Zirconium. An abnormal trace element in biology. Ghosh S, Sharma A, and Talukder G Biol. Trace Elem. Res. 35(3), 247-71, (1992)

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The effect of heat on the mechanical properties of glass ionomer cements. Kuter B, Eden E, and Yildiz H Eur. J. Paediatr. Dent. 14(2), 90-4, (2013)

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The formation of 3-hydroxy-4-methoxyphenylalanine and 3-hydroxy-4-methoxyphenethylamine in plasma during L-DOPA therapy in patients with Parkinson's disease. Ishimitsu T, Hirose S, Asahara K, et al. Chem. Pharm. Bull. 32(8), 3320-2, (1984)

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Abnormal trace metals in man: zirconium. Schroeder HA and Balassa JJ J. Chronic Dis. 19(5), 573-86, (1966)

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Enantioseparation of basic chiral compounds on a clindamycin phosphate-silica/zirconia hybrid monolith by capillary electrochromatography. Tran le N, Dixit S, and Park JH J. Chromatogr. A 1356, 289-93, (2014)

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Metal-organic framework UiO-66 coated stainless steel fiber for solid-phase microextraction of phenols in water samples. Shang HB, Yang CX, and Yan XP J. Chromatogr. A 1357, 165-71, (2014)

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Functionalized bio-artifact fabricated via selective slurry extrusion. Part 2: Fabrication of ceramic dental crown. Zhu DB, Liang JP, Qu YX, et al. J. Nanosci. Nanotechnol. 14(5), 3703-6, (2014)

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A nanoparticle formulation reduces the corneal toxicity of indomethacin eye drops and enhances its corneal permeability. Nagai N, Ito Y, Okamoto N, et al. Toxicology 319, 53-62, (2014)

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Determination of trace amounts of zirconium in real samples after microwave digestion and ternary complex dispersive liquid-liquid microextraction. Afzali D, Fathirad F, Ghaseminezhad S, et al. Environ. Monit. Assess. 186(6), 3523-9, (2014)

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Merck 14,10173

Aldrich MSDS 1, 1848:B / Corp MSDS 1 (2), 3633:A / Corp MSDS 1 (2), 3633:B / RegBook 1 (3), 3225:I / RegBook 1 (3), 3225:H / Sax 6, 2758

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