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18697 Sigma-Aldrich

(2-Bromovinyl)trimethylsilane

purum, ~87% (trans + ~13% cis)

Synonym: β-(Trimethylsilyl)vinyl bromide, 1-Bromo-2-(trimethylsilyl)ethylene

  • CAS Number 41309-43-7

  • Linear Formula BrCH=CHSi(CH3)3

  • Molecular Weight 179.13

  •  Beilstein Registry Number 1700085

  •  MDL number MFCD00040824

  •  PubChem Substance ID 329751733

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Properties

Related Categories Alkenyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks More...
InChI Key   FKXCNOSKBLGEMQ-SNAWJCMRSA-N
grade   purum
assay   ~87% (trans + ~13% cis)
refractive index   n20/D 1.466(lit.)
  n20/D 1.466
bp   50-51 °C/52 mmHg(lit.)
density   1.167 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Other Notes

Starting material for the synthesis of various vinyl silanes [via the lithium, zinc or magnesium (Grignard) derivative or the cuprate]; Synthesis of (E)-1,2-bis(trimethylsilyl)ethylene

Same product — same quality — now Sigma-Aldrich brand

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 1993C 3 / PGIII
WGK Germany 
3
Flash Point(F) 
84.2 °F
Flash Point(C) 
29 °C
Protocols & Articles
Peer-Reviewed Papers
15

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