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21287 Sigma-Aldrich

(1S)-(−)-Camphanic chloride

for chiral derivatization, ≥98.0%

Synonym: (−)-Camphanoyl chloride, (1S)-3-Oxo-4,7,7-trimethyl-2-oxabicyclo[2.2.1]heptane-1-carbonyl chloride

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Properties

Related Categories Analytical Reagents, Analytical/Chromatography, Chiral, Chiral Derivatization Reagents, Chiral GC Derivatization Reagents,
grade   for chiral derivatization
InChI Key   PAXWODJTHKJQDZ-VHSXEESVSA-N
assay   ≥98.0% (AT)
  ≥98.0%
optical activity   [α]20/D −18±1°, c = 2% in carbon tetrachloride
optical purity   enantiomeric ratio: ≥99.5:0.5 (GC)
mp   67-70 °C
  71-73 °C(lit.)
storage temp.   −20°C

Description

Other Notes

Chiral derivatizing reagent used for the determination of enantiomeric purity of alcohols and amines by HPLC

Same product — same quality — now Sigma-Aldrich brand

Application

(1S)-(-)-Camphanic chloride may be used in esterification of enantiomers in volatiles releasedf from wheat, in order to determine the proportion of enantiomers and also in quantifying the esters.

General description

(1S)-(-)-Camphanic chloride is a derivatizing agent.

Price and Availability

Suggested Laboratory Gloves


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Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 3261 8 / PGII
WGK Germany 
3

Documents

Certificate of Analysis

Protocols & Articles
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