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21295 Sigma-Aldrich

(−)-Camphor

purum, ≥95.0% (sum of enantiomers, GC)

Synonym: (1S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one

  • CAS Number 464-48-2

  • Empirical Formula (Hill Notation) C10H16O

  • Molecular Weight 152.23

  •  Beilstein Registry Number 1907612

  •  EC Number 207-354-7

  •  MDL number MFCD00064148

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Ketones, Organic Building Blocks More...
InChI Key   DSSYKIVIOFKYAU-OIBJUYFYSA-N
grade   purum
assay   ≥95.0% (sum of enantiomers, GC)
optical activity   [α]20/D −43±2°, c = 10% in ethanol

Description

Other Notes

(-)-Camphor can be employed analogously to the natural (+)-camphor. Specific syntheses starting with (-)-camphor include the preparation of (-)-laurolenic acid; analogues of cis-sativenediol and helminthosporal; intermediates for the enantiospecific total synthesis of steroids; and of vitamin B-12

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 2717 4.1 / PGIII
WGK Germany 
1
RTECS 
EX1250000
Flash Point(F) 
149 °F
Flash Point(C) 
65 °C

Documents

Certificate of Analysis

Protocols & Articles
Peer-Reviewed Papers
15

References

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