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215155 Sigma-Aldrich

Hydrazine

anhydrous, 98%

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Properties

Related Categories Chemical Deglycosylation, Deglycosylation Strategies, Glycobiology, Hydrazinolysis, Molecular Biology,
grade   anhydrous
vapor density   1 (37 °C, vs air)
vapor pressure   10 mmHg ( 30.7 °C)
assay   98%
expl. lim.   99.99 %
refractive index   n20/D 1.47(lit.)
bp   113.5 °C(lit.)
mp   1.4 °C(lit.)
density   1.021 g/mL at 25 °C(lit.)

Description

Packaging

1 kg in Sure/Seal™

50, 100, 500 g in Sure/Seal™

Price and Availability

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reagent grade, N2H4 50-60 %

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Safety & Documentation

Safety Information

Signal word 
Danger
RIDADR 
UN 2029 6.1(3)(8) / PGI
WGK Germany 
3
RTECS 
MU7175000
Flash Point(F) 
125.6 °F
Flash Point(C) 
52 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

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Peer-Reviewed Papers

References

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[9] hydrazinolysis. Schroeder, W.A. Meth. Enzymol. 25, 138, (1972)

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Akabori, S., et al. Bull. Chem. Soc. Jpn. 29, 508, (1956)

Discovery of novel inhibitors of LEDGF/p75-IN protein-protein interactions. Sanchez TW, Debnath B, Christ F, et al. Bioorg. Med. Chem. 21(4), 957-63, (2013)

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Mild and rapid Pd-catalyzed cross-coupling with hydrazine in continuous flow: application to the synthesis of functionalized heterocycles. DeAngelis A, Wang DH, and Buchwald SL Angew. Chem. Int. Ed. Engl. 52(12), 3434-7, (2013)

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Configurational and constitutional information storage: multiple dynamics in systems based on pyridyl and acyl hydrazones. Chaur MN, Collado D and Collado JM Chemistry 17(1), 248-58, (2011)

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Hydrazine sulfate: a current perspective. Gold J Nutr. Cancer 9(2-3), 59-66, (1987)

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You're the flight surgeon: hydrazine exposure. Cromar JW Aviat. Space. Environ. Med. 84(5), 540-1, (2013)

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Quantitative proteomic analysis of N-linked glycoproteins in human tear fluid. Zhou L and Beuerman RW Methods Mol. Biol. 951, 297-306, (2013)

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Quantitative characterization of glycoproteins in neurodegenerative disorders using iTRAQ. Shi M, Hwang H, and Zhang J Methods Mol. Biol. 951, 279-96, (2013)

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Sialic acid capture-and-release and LC-MS(n) analysis of glycopeptides. Nilsson J and Larson G Methods Mol. Biol. 951, 79-100, (2013)

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Hydrazine. IARC Monogr. Eval. Carcinog. Risks Hum. 71 Pt 3, 991-1013, (1999)

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Hydrazine reagents as derivatizing agents in environmental analysis--a critical review. Vogel M, Büldt A, and Karst U Fresenius J. Anal. Chem. 366(8), 781-91, (2000)

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High sensitivity hydrogen peroxide and hydrazine sensor based on silver nanocubes with rich {100} facets as an enhanced electrochemical sensing platform. Wang Y, Yang X, Bai J, et al. Biosens. Bioelectron. 43, 180-5, (2013)

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Base-induced dehydrogenation of ruthenium hydrazine complexes. Field LD, Li HL, Dalgarno SJ, et al. Inorg. Chem. 52(3), 1570-83, (2013)

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NIR- and FRET-based sensing of Cu2+ and S2- in physiological conditions and in live cells. Kar C, Adhikari MD, Ramesh A, et al. Inorg. Chem. 52(2), 743-52, (2013)

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Evaluation of a published in silico model and construction of a novel Bayesian model for predicting phospholipidosis inducing potential. Dennis J Pelletier et al J. Chem. Inf. Model. 47, 1196-205, (2007)

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Homogeneous iron complexes for the conversion of dinitrogen into ammonia and hydrazine. Hazari N Chem. Soc. Rev. 39(11), 4044-56, (2010)

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Developing structure-activity relationships for the prediction of hepatotoxicity. Nigel Greene et al Chem. Res. Toxicol. 23, 1215-22, (2010)

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Electrochemical detection of individual DNA hybridization events. Alligrant TM, Nettleton EG, and Crooks RM Lab Chip 13(3), 349-54, (2013)

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Magnetic loading of graphene-nickel nanoparticle hybrid for electrochemical sensing of carbohydrates. Qu W, Zhang L, and Chen G Biosens. Bioelectron. 42, 430-3, (2013)

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Control and analysis of hydrazine, hydrazides and hydrazones--genotoxic impurities in active pharmaceutical ingredients (APIs) and drug products. Elder DP, Snodin D, and Teasdale A J. Pharm. Biomed. Anal. 54(5), 900-10, (2011)

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Solvent properties of hydrazine in the preparation of metal chalcogenide bulk materials and films. Yuan M and Mitzi DB Dalton Trans. (31), 6078-88, (2009)

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The usefulness of hydrazine derivatives for mass spectrometric analysis of carbohydrates. Lattová E and Perreault H Mass Spectrom. Rev. 32(5), 366-85, (2013)

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A predictive ligand-based Bayesian model for human drug-induced liver injury. Sean Ekins et al Drug Metab. Dispos. 38, 2302-8, (2010)

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Origin and nature of bond rotation barriers: a unified view. Liu S J. Phys. Chem. A 117(5), 962-5, (2013)

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Direct N(2)H(4)/H(2)O(2) fuel cells powered by nanoporous gold leaves. Yan X, Meng F, Xie Y, et al. Sci. Rep. 2, 941, (2012)

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"Test kit" for detection of biologically important anions: a salicylidene-hydrazine based Schiff base. Dalapati S, Alam MA, Jana S, et al. Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 102, 314-8, (2013)

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Ultrasound accelerated gelation of novel L-lysine based hydrogelators. Pan S, Luo S, Li S, et al. Chem. Commun. (Camb.) 49(73), 8045-7, (2013)

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Investigation of basic mobile phases with positive ESI LC-MS for metabonomics studies. Rainville PD, Smith NW, Cowan D, et al. Bioanalysis 4(23), 2833-42, (2012)

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Copper nanoparticles mediated by chitosan: synthesis and characterization via chemical methods. Usman MS, Ibrahim NA, Shameli K, et al. Molecules 17(12), 14928-36, (2012)

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Unconventional therapies for cancer: 4. Hydrazine sulfate. Task Force on Alternative Therapies of the Canadian Breast Cancer Research Initiative. Kaegi E CMAJ 158(10), 1327-30, (1998)

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Protective Role of Ficus carica Stem Extract against Hepatic Oxidative Damage Induced by Methanol in Male Wistar Rats. Mongi Saoudi et al Evid. Based. Complement. Alternat. Med. 2012, 150458, (2012)

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A kinetic and theoretical study of the borate catalysed reactions of hydrogen peroxide: the role of dioxaborirane as the catalytic intermediate for a wide range of substrates. Deary ME, Durrant MC, and Davies DM Org. Biomol. Chem. 11(2), 309-17, (2013)

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One-step conversion of azine N-oxides to α-N-aryltriflamidoazines. Keith JM J. Org. Chem. 77(24), 11313-8, (2012)

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Patterning of solution-processable materials on templates fabricated from mixed Langmuir-Blodgett films. Watanabe S, Akiyoshi Y, and Matsumoto M J. Oleo Sci. 62(2), 65-71, (2013)

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The reaction of ethyl 2-oxo-2H-chromene-3-carboxylate with hydrazine hydrate. Abdel-Aziz HA, Elsaman T, Attia MI, et al. Molecules 18(2), 2084-95, (2013)

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Electrocatalytic oxidation of hydrazine and hydroxylamine by graphene oxide-Pd nanoparticle-modified glassy carbon electrode. Lee E, Kim D, You JM, et al. J. Nanosci. Nanotechnol. 12(12), 8886-92, (2012)

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Multiple basal cell carcinomas after long-term exposure to hydrazine: case report and review of the literature. Aigner BA, Darsow U, Grosber M, et al. Dermatology 221(4), 300-2, (2010)

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Discrete Fourier Transform as applicable technique in electrochemical detection of hydrazine using multi-walled carbon nanotube/polyacrylonitrile ceramic fiber as working electrode. Doroodmand MM Mater. Sci. Eng. C. Mater. Biol. Appl. 33(4), 1969-74, (2013)

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Novel self-dyed wholly aromatic polyamide-hydrazides covalently bonded with azo groups in their main chains: 1. Structure-property relationships. Mohamed NA, Sammour MH, and Elshafai AM Molecules 17(12), 13969-88, (2012)

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A facile synthesis of new monoazo disperse dyes derived from 4-hydroxyphenylazopyrazole-5-amines: evaluation of microwave assisted dyeing behavior. Al-Etaibi AM, El-Apasery MA, Ibrahim MR, et al. Molecules 17(12), 13891-909, (2012)

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Synthesis, in vitro antibacterial and antifungal activity of some n-acetylated and non-acetylated pyrazolines. Baseer M, Ansari FL, and Ashraf Z Pak. J. Pharm. Sci. 26(1), 67-73, (2013)

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A review of the antineoplastic action of certain hydrazines and hydrazine-containing natural products. Toth B In Vivo 10(1), 65-96, (1996)

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Merck 14,4770

Fieser 1,434 / Fieser 2,211 / Fieser 3,153 / Fieser 4,248 / Fieser 5,327 / Fieser 6,280 / Fieser 7,170 / Fieser 8,245 / Fieser 9,236 / Fieser 11,255 / Fieser 12,241 / Fieser 13,144 / Fieser 16,174

Aldrich MSDS 1, 1044:D / Corp MSDS 1 (1), 1888:D / FT-IR 2 (3), 4712:A / RegBook 1 (3), 3201:C / Sax 6, 1539 / Structure Index 1, 509:A:3 / Vapor Phase 3, 363:C

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