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  • 228036 - OXONE®, monopersulfate compound

228036 Sigma-Aldrich

OXONE®, monopersulfate compound

Synonym: Potassium peroxymonosulfate




1 kg in poly bottle

5 g in glass bottle

5 kg in poly drum

100 g in poly bottle

25 kg in fiber drum


A rapid, efficient synthesis of oxaziridines from imines using buffered OXONE has been reported.1 Also used to study fading of an artist′s colorants.2

Oxidant used for halogenation of a,b-unsaturated carbonyl compounds and catalytic generation of hypervalent iodine reagents for alcohol oxidation.

2-Iodoxybenzenesulfonic Acid as an Extremely Active Catalyst for the Selective Oxidation of Alcohols to Aldehydes, Ketones, Carboxylic Acids, and Enones with Oxone

A Convenient Halogenation of α,β-Unsaturated Carbonyl Compounds with OXONE® and Hydrohalic Acid (HBr, HCl)

Legal Information

OXONE is a registered trademark of E. I. du Pont de Nemours and Company

Price and Availability

Suggested Laboratory Gloves

Laboratory GlovesThis substance has been tested against several types of hand protection for CE compliance. Click below to find the recommended gloves for handling this product.

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predominantly endo, 97%

OXONE<SUP>®</SUP> tetrabutylammonium salt

technical, ~1.6% active oxygen basis

Safety & Documentation

Safety Information


Certificate of Analysis

Certificate of Origin

Protocols & Articles


Oxidizing and Reducing Agents

Oxidation and reduction reactions are some of the most common transformations encountered in organic synthesis, and are some of the organic chemist’s most powerful tools for creating novel products. ...
ChemFiles Volume 1 Article 3
Keywords: Organic synthesis, Oxidations, Reductions, Tools

Peer-Reviewed Papers


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1. J. Chem. Res. Synop., 388, (1992)

2. Atmos. Environ., Part A 27A, 765, (1993)

Sulfide oxidations for LC-MS analysis of methionine-containing microcystins in Dolichospermum flos-aquae NIVA-CYA 656. Miles CO, Melanson JE, Ballot A, et al. Environ. Sci. Technol. 48(22), 13307-15, (2014)


Peroxidation enhances the biogas production in the anaerobic digestion of biosolids. Dewil R, Appels L, Baeyens J, et al. J. Hazard. Mater. 146(3), 577-81, (2007)


[Influential factors and degradation pathway of imidacloprid by homogeneous Co/PMS system]. Chen XY, Chen JW, Yang P, et al. Huan Jing Ke Xue 28(12), 2816-20, (2007)


Effect of inorganic, synthetic and naturally occurring chelating agents on Fe(II) mediated advanced oxidation of chlorophenols. Rastogi A, Al-Abed SR, and Dionysiou DD Water Res. 43(3), 684-94, (2009)


Oxidative degradation of dyes in water using Co2+/H2O2 and Co2+/peroxymonosulfate. Ling SK, Wang S, and Peng Y J. Hazard. Mater. 178(1-3), 385-9, (2010)


Cobalt-mediated activation of peroxymonosulfate and sulfate radical attack on phenolic compounds. implications of chloride ions. Anipsitakis GP, Dionysiou DD, and Gonzalez MA Environ. Sci. Technol. 40(3), 1000-7, (2006)


Degradation of atrazine by cobalt-mediated activation of peroxymonosulfate: Different cobalt counteranions in homogenous process and cobalt oxide catalysts in photolytic heterogeneous process. Chan KH and Chu W Water Res. 43(9), 2513-21, (2009)


Influence of pH on the formation of sulfate and hydroxyl radicals in the UV/peroxymonosulfate system. Guan YH, Ma J, Li XC, et al. Environ. Sci. Technol. 45(21), 9308-14, (2011)


Efficient decolorization of azo dye Reactive Black B involving aromatic fragment degradation in buffered Co2+/PMS oxidative processes with a ppb level dosage of Co2+-catalyst. Huang YH, Huang YF, Huang CI, et al. J. Hazard. Mater. 170(2-3), 1110-8, (2009)


Chemical and microbial decontamination of pool water using activated potassium peroxymonosulfate. Anipsitakis GP, Tufano TP, and Dionysiou DD Water Res. 42(12), 2899-910, (2008)


Behavioral evidence of the dominant radicals and intermediates involved in bisphenol A degradation using an efficient Co2+/PMS oxidation process. Huang YF and Huang YH J. Hazard. Mater. 167(1-3), 418-26, (2009)


Kinetics of oxidative decolorization and mineralization of Acid Orange 7 by dark and photoassisted Co2+-catalyzed peroxymonosulfate system. Chen X, Qiao X, Wang D, et al. Chemosphere 67(4), 802-8, (2007)


Pattern of oxidation products derived from tetrabromobisphenol A in a catalytic system comprised of iron(III)-tetrakis(p-sulfophenyl)porphyrin, KHSO5 and humic acids. Fukushima M, Ishida Y, Shigematsu S, et al. Chemosphere 80(8), 860-5, (2010)


Peroxymonosulfate-Co(II) oxidation system for the removal of the non-ionic surfactant Brij 35 from aqueous solution. Pagano M, Volpe A, Mascolo G, et al. Chemosphere 86(4), 329-34, (2012)


(Bi)sulfite oxidation by copper, zinc-superoxide dismutase: Sulfite-derived, radical-initiated protein radical formation. Ranguelova K, Bonini MG, and Mason RP Environ. Health Perspect. 118(7), 970-5, (2010)


Application of a peroxymonosulfate/cobalt (PMS/Co(II)) system to treat diesel-contaminated soil. Do SH, Jo JH, Jo YH, et al. Chemosphere 77(8), 1127-31, (2009)


Kinetic modeling and synergy quantification in sono and photooxidative treatment of simulated dyehouse effluent. Grčić I, Papić S, Koprivanac N, et al. Water Res. 46(17), 5683-95, (2012)


Decontamination of soil washing wastewater using solar driven advanced oxidation processes. Bandala ER, Velasco Y, and Torres LG J. Hazard. Mater. 160(2-3), 402-7, (2008)


Synthesis of graft copolymer (CgOH-g-AGA): physicochemical properties, characterization and application. Sand A, Mishra DK, Pandey VS, et al. Carbohydr. Polym. 90(2), 901-7, (2012)


Inactivation of human norovirus surrogates by benzalkonium chloride, potassium peroxymonosulfate, tannic acid, and gallic acid. Su X and D'Souza DH Foodborne Pathog. Dis. 9(9), 829-34, (2012)


Synthesis, characterization and applications of graft copolymer (κ-carrageenan-g-vinylsulfonic acid). Yadav M, Sand A, Mishra MM, et al. Int. J. Biol. Macromol. 50(3), 826-32, (2012)


Promoted wet air oxidation of polynuclear aromatic hydrocarbons. Rivas FJ, García R, García-Araya JF, et al. J. Hazard. Mater. 153(1-2), 792-8, (2008)


Involvements of chloride ion in decolorization of Acid Orange 7 by activated peroxydisulfate or peroxymonosulfate oxidation. Wang P, Yang S, Shan L, et al. J. Environ. Sci. (China) 23(11), 1799-807, (2011)


Detailed kinetics and mechanism of the oxidation of thiocyanate ion (SCN-) by peroxomonosulfate ion (HSO5(-)). Formation and subsequent oxidation of hypothiocyanite ion (OSCN-). Kalmár J, Lente G, and Fábián I Inorg. Chem. 52(4), 2150-6, (2013)


Rapid dye degradation with reactive oxidants generated by chloride-induced peroxymonosulfate activation. Lou XY, Guo YG, Xiao DX, et al. Environ. Sci. Pollut. Res. Int. 20(9), 6317-23, (2013)


Chemiluminescence and energy transfer mechanism of lanthanide ions in different media based on peroxomonosulfate system. Zhang BT and Lin JM Luminescence 25(4), 322-7, (2010)


Enhanced chemiluminescence of peroxomonosulfate-cobalt (II) system in the presence of dicarboxylic acids. Zhou Y, Ogawa N, and Lin JM Luminescence 26(4), 280-8, (2011)


Fieser 1,952 / Fieser 11,442 / Fieser 12,413 / Fieser 13,259 / Fieser 14,267 / Fieser 16,285

Corp MSDS 2 (2), 2667:B / Sax 6, 2280

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