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271004 Sigma-Aldrich

Acetonitrile

anhydrous, 99.8%

Synonym: ACN, Methyl cyanide

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Properties

Related Categories Acetonitrile and Acetonitrile Solutions, Anhydrous, Anhydrous Solvents, Products, Returnable Containers,
grade   anhydrous
vapor density   1.41 (vs air)
vapor pressure   72.8 mmHg ( 20 °C)
assay   99.8%
autoignition temp.   973 °F
expl. lim.   16 %
impurities   <0.001% water
  <0.005% water (100 mL pkg)
evapn. residue   <0.0005%
refractive index   n20/D 1.344(lit.)
bp   81-82 °C(lit.)
mp   −48 °C(lit.)
density   0.786 g/mL at 25 °C(lit.)

Description

Packaging

1, 6×1, 2, 4×2 L in Sure/Seal™

18 L in Pure-Pac™ 1

20, 50 L in Pure-Pac™ 2

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100, 12×100 mL in Sure/Seal™

200 L in Pure-Pac™ 1

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Hazard Codes (Europe) 
Risk Statements (Europe) 
Safety Statements (Europe) 
16-36/37
RIDADR 
UN 1648 3 / PGII
WGK Germany 
2
RTECS 
AL7700000
Flash Point(F) 
35.6 °F
Flash Point(C) 
2 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

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Peer-Reviewed Papers

References

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Performance of different C18 columns in reversed-phase liquid chromatography with hydro-organic and micellar-organic mobile phases. Ruiz-Angel MJ, Pous-Torres S, Carda-Broch S, et al. J. Chromatogr. A 1344, 76-82, (2014)

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HPLC of flavanones and chalcones in different species and clones of Salix. Krauze-Baranowska M, Pobłocka-Olech L, Głód D, et al. Acta Pol. Pharm. 70(1), 27-34, (2013)

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Trace level determination of polyether ionophores in feed. Rokka M, Jestoi M, and Peltonen K Biomed Res. Int. 2013, 151363, (2013)

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Enantioseparation of basic chiral compounds on a clindamycin phosphate-silica/zirconia hybrid monolith by capillary electrochromatography. Tran le N, Dixit S, and Park JH J. Chromatogr. A 1356, 289-93, (2014)

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Assessment of the complementarity of temperature and flow-rate for response normalisation of aerosol-based detectors. Khandagale MM, Hilder EF, Shellie RA, et al. J. Chromatogr. A 1356, 180-7, (2014)

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Calculated and experimental chromatograms for distorted gradients and non-linear solvation strength retention models. Gritti F and Guiochon G J. Chromatogr. A 1356, 96-104, (2014)

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Separations by gradient elution: why are steep gradient profiles distorted and what is their impact on resolution in reversed-phase liquid chromatography. Gritti F and Guiochon G J. Chromatogr. A 1344, 66-75, (2014)

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Merck 14,70

Beil. 2,IV,419

Fieser 2,13

Aldrich MSDS 1, 13:C / Corp MSDS 1 (1), 22:A / FT-IR 2 (1), 1422:A / FT-IR 1 (1), 837:A / FT-NMR 1 (1), 1351:A / IR-Spectra (3), 1527:A / IR-Spectra (2), 444:A / IR-Spectra (3), 500:A / NMR-Reference 2 (1), 695:A / RegBook 1 (1), 987:A / Sax 6, 90 / Sigma FT-IR 1 (2), 233:C / Structure Index 1, 154:A:1 / Vapor Phase 3, 795:A

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