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274380 Sigma-Aldrich

Dimethyl sulfide

anhydrous, ≥99.0%

Synonym: DMS, Methyl sulfide

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Properties

Related Categories Anhydrous Solvents, Solvent Bottles, Solvent Packaging Options, Solvent by Application, Solvents,
grade   anhydrous
vapor density   2.1 (vs air)
vapor pressure   26.24 psi ( 55 °C)
  7.79 psi ( 20 °C)
assay   ≥99.0%
autoignition temp.   402 °F
expl. lim.   19.7 %
impurities   <0.003% water
  <0.005% water (100 mL pkg)
evapn. residue   <0.0005%
refractive index   n20/D 1.435(lit.)
bp   38 °C(lit.)
mp   −98 °C(lit.)
density   0.846 g/mL at 25 °C(lit.)
Gene Information   rat ... Maoa(29253), Maob(25750)

Description

Packaging

1 L in Sure/Seal™

100 mL in Sure/Seal™

Price and Availability

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1164 3 / PGII
WGK Germany 
1
RTECS 
PV5075000
Flash Point(F) 
-31 °F
Flash Point(C) 
-35 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Peer-Reviewed Papers

References

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Measurement and biological significance of the volatile sulfur compounds hydrogen sulfide, methanethiol and dimethyl sulfide in various biological matrices. Tangerman A J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 877(28), 3366-77, (2009)

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Dimethyl sulfone in human cerebrospinal fluid and blood plasma confirmed by one-dimensional (1)H and two-dimensional (1)H-(13)C NMR. Engelke UF, Tangerman A, Willemsen MA, et al. NMR Biomed. 18(5), 331-6, (2005)

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Halogen bonding from a hard and soft acids and bases perspective: investigation by using density functional theory reactivity indices. Pinter B, Nagels N, Herrebout WA, et al. Chemistry 19(2), 519-30, (2013)

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Metagenomic insights into strategies of carbon conservation and unusual sulfur biogeochemistry in a hypersaline Antarctic lake. Yau S, Lauro FM, Williams TJ, et al. ISME J. 7(10), 1944-61, (2013)

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Clinical utility of a novel colorimetric chair side test for oral malodour. Dadamio J, Van Tornout M, Vancauwenberghe F, et al. J. Clin. Periodontol. 39(7), 645-50, (2012)

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Dimethyl sulfide and dimethyl sulfoxide and their oxidation in the atmosphere. Barnes I, Hjorth J, and Mihalopoulos N Chem. Rev. 106(3), 940-75, (2006)

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Short term clinical efficacy of new meridol HALITOSIS tooth & tongue gel in combination with a tongue cleaner to reduce oral malodor. Wilhelm D, Himmelmann A, Krause C, et al. J. Clin. Dent. 24(1), 12-9, (2013)

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Dimethyl sulfide biofiltration using immobilized Hyphomicrobium VS and Thiobacillus thioparus TK-m in sugarcane bagasse. Treto Fernández H, Rodríguez Rico I, Jover de la Prida J, et al. Environ. Technol. 34(1-4), 257-62, (2013)

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[Halitosis in certain somatic diseases]. Bakhmutov DN, Fedorov IG, Kharchenko OI, et al. Stomatologiia. (Mosk.) 91(3), 24-6, (2012)

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[New opportunities of renal diseases diagnostics using gas chromatography]. Grabowska-Polanowska B, Faber J, Skowron M, et al. Prz. Lek. 69(3), 91-7, (2012)

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[Halitosis in oral diseases]. Bakhmutov DN, Kharchenko OI, and Ianushevich OO Stomatologiia. (Mosk.) 91(1), 13-5, (2012)

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[Influence of exogenous sulfur-containing compounds on the exchange fluxes of volatile organic sulfur compounds]. Yi ZG and Wang XM Huan Jing Ke Xue 32(8), 2236-9, (2011)

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Intravenous cysteamine therapy for nephropathic cystinosis. Gahl WA, Ingelfinger J, Mohan P, et al. Pediatr. Res. 38(4), 579-84, (1995)

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Interacting effects of ocean acidification and warming on growth and DMS-production in the haptophyte coccolithophore Emiliania huxleyi. Arnold HE, Kerrison P, and Steinke M Glob. Chang. Biol. 19(4), 1007-16, (2013)

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Calculating virtual log P in the alkane/water system (log P(N)(alk)) and its derived parameters deltalog P(N)(oct-alk) and log D(pH)(alk). Giulia Caron et al J. Med. Chem. 48, 3269-79, (2005)

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Large contribution of natural aerosols to uncertainty in indirect forcing. Carslaw KS, Lee LA, Reddington CL, et al. Nature 503(7474), 67-71, (2013)

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Multiphase halogen chemistry in the tropical Atlantic Ocean. Sommariva R and von Glasow R Environ. Sci. Technol. 46(19), 10429-37, (2012)

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Oxygen consumption and development of volatile sulfur compounds during bottle aging of two Shiraz wines. Influence of pre- and postbottling controlled oxygen exposure. Ugliano M, Dieval JB, Siebert TE, et al. J. Agric. Food Chem. 60(35), 8561-70, (2012)

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Environmental VOSCs--formation and degradation of dimethyl sulfide, methanethiol and related materials. Bentley R and Chasteen TG Chemosphere 55(3), 291-317, (2004)

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Halitosis in cystinosis patients after administration of immediate-release cysteamine bitartrate compared to delayed-release cysteamine bitartrate. Besouw M, Tangerman A, Cornelissen E, et al. Mol. Genet. Metab. 107(1-2), 234-6, (2012)

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Immunoquantitation of FMO1 in human liver, kidney, and intestine. Yeung CK, Lang DH, Thummel KE, et al. Drug Metab. Dispos. 28(9), 1107-11, (2000)

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Comparison of RNA- and DNA-based bacterial communities in a lab-scale methane-degrading biocover. Kim TG, Moon KE, Yun J, et al. Appl. Microbiol. Biotechnol. 97(7), 3171-81, (2013)

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Kinetics of the bio-oxidation of volatile reduced sulphur compounds in a biotrickling filter. Cáceres M, Silva J, Morales M, et al. Bioresour. Technol. 118, 243-8, (2012)

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Sulfur isotope homogeneity of oceanic DMSP and DMS. Amrani A, Said-Ahmad W, Shaked Y, et al. Proc. Natl. Acad. Sci. U. S. A. 110(46), 18413-8, (2013)

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QSPR modeling of octanol/water partition coefficient for vitamins by optimal descriptors calculated with SMILES. A A Toropov et al Eur. J. Med. Chem. 43, 714-40, (2008)

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A study of enzymatic activity in cell cultures via the analysis of volatile biomarkers. Chippendale TW, Hu B, El Haj AJ, et al. Analyst 137(20), 4677-85, (2012)

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Determination of dimethyl sulphide in blood and adipose tissue by headspace gas analysis. Terazawa K, Kaji H, Akabane H, et al. J. Chromatogr. A 565(1-2), 453-6, (1991)

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Prediction of periodontopathic bacteria in dental plaque of periodontal healthy subjects by measurement of volatile sulfur compounds in mouth air. Kishi M, Ohara-Nemoto Y, Takahashi M, et al. Arch. Oral Biol. 58(3), 324-30, (2013)

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Breath malodor in an asthmatic patient caused by side-effects of medication: a case report and review of the literature. Murata T, Fujiyama Y, Yamaga T, et al. Oral Dis. 9(5), 273-6, (2003)

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Perception of dimethyl sulfide (DMS) by loggerhead sea turtles: a possible mechanism for locating high-productivity oceanic regions for foraging. Endres CS and Lohmann KJ J. Exp. Biol. 215(Pt 20), 3535-8, (2012)

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Gas production by feces of infants. Jiang T, Suarez FL, Levitt MD, et al. J. Pediatr. Gastroenterol. Nutr. 32(5), 534-41, (2001)

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Scalping of light volatile sulfur compounds by wine closures. Silva MA, Jourdes M, Darriet P, et al. J. Agric. Food Chem. 60(44), 10952-6, (2012)

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Evaluation of the masking of dimethyl sulfide odors by citronellal, limonene and citral through the use of trained odor sensor mice. Osada K, Hanawa M, Tsunoda K, et al. Chem. Senses 38(1), 57-65, (2013)

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The determination of metabolites of garlic preparations in breath and human plasma. Rosen RT, Hiserodt RD, Fukuda EK, et al. Biofactors 13(1-4), 241-9, (2000)

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A heme-based redox sensor in the methanogenic archaeon Methanosarcina acetivorans. Molitor B, Stassen M, Modi A, et al. J. Biol. Chem. 288(25), 18458-72, (2013)

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The early events in the OH radical oxidation of dimethyl sulfide in water. Janik I and Tripathi GN J. Chem. Phys. 138(4), 044506, (2013)

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Integration of advanced oxidation processes at mild conditions in wet scrubbers for odourous sulphur compounds treatment. Vega E, Martin MJ, and Gonzalez-Olmos R Chemosphere 109, 113-9, (2014)

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Liquid-gas partitioning of selected volatile organic sulfur compounds in anaerobically digested sludges. Du W and Parker W Water Sci. Technol. 66(3), 573-9, (2012)

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Core level (S 2p) excitation and fragmentation of the dimethyl sulfide and dimethyldisulfide molecules. Bernini RB, da Silva LB, Rodrigues FN, et al. J. Chem. Phys. 136(14), 144307, (2012)

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Influence of the industrial processing and the floral origin into the volatile constituents of honeybee-collected pollen. Domínguez-Valhondo D, González-Gómez D, Hernández-Méndez T, et al. Food Sci. Technol. Int. 19(2), 167-76, (2013)

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Treatment of waste gas containing low concentration of dimethyl sulphide in a high performance biotrickling filter. Giri BS, Juwarkar A, Mudliar SN, et al. Indian J. Exp. Biol. 51(11), 1018-23, (2013)

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Phylogenetic diversity of the dddP gene for dimethylsulfoniopropionate-dependent dimethyl sulfide synthesis in mangrove soils. Peng M, Xie Q, Hu H, et al. Can. J. Microbiol. 58(4), 523-30, (2012)

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Merck 14,6123

Beil. 1,IV,1275

Fieser 2,156 / Fieser 4,190 / Fieser 5,260

Aldrich MSDS 1, 1308:A / Arctander, 1060 / Corp MSDS 1 (2), 2439:D / FT-IR 2 (1), 418:D / FT-IR 1 (1), 264:B / FT-NMR 1 (1), 425:A / Fenaroli / IR-Spectra (2), 139:C / IR-Spectra (3), 155:H / NMR-Reference 2 (1), 215:A / RegBook 60 (1), 285:A / RegBook 1 (1), 285:A / Sax 6, 2574 / Sigma FT-IR 1 (2), 511:A / Structure Index 1, 38:D:9 / Vapor Phase 3, 347:B

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