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320110 Sigma-Aldrich

Acetone

ACS reagent, ≥99.5%

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Properties

Related Categories ACS Grade, ACS Grade Solvents, ACS and Reagent Grade Solvents, Acetone, PVC Coated Bottles,
grade   ACS reagent
vapor density   2 (vs air)
vapor pressure   184 mmHg ( 20 °C)
assay   ≥99.5%
expl. lim.   13.2 %
impurities   ≤0.0003 meq/g Titr. acid
  ≤0.0006 meq/g Titr. base
  ≤0.002% aldehyde as formaldehyde
  ≤0.05% isopropanol
  ≤0.05% methanol
  ≤0.5% water
evapn. residue   ≤0.001%
color   APHA: ≤10
refractive index   n20/D 1.359(lit.)
bp   56 °C/760 mmHg(lit.)
mp   −94 °C(lit.)
density   0.791 g/mL at 25 °C(lit.)

Description

Packaging

1, 4, 4×4 L in PVC coated

View returnable container options.

200 L in Pure-Pac™ 1

Application

Acetone′s luminesence intensity is dependent upon the solution components 1. The absorption of UV light by acetone, results in its photolysis and the production of radials 1.

Price and Availability

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Repeated exposure may cause skin dryness or cracking.
Hazard Codes (Europe) 
Risk Statements (Europe) 
Safety Statements (Europe) 
9-16-26
RIDADR 
UN 1090 3 / PGII
WGK Germany 
1
RTECS 
AL3150000
Flash Point(F) 
3.2 °F
Flash Point(C) 
-16 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Articles

Determination of Water Content in Acetone Using Karl Fischer Titration

Ketones have a tendency to form ketals. At the same time water is formed. Cyclohexanone and acetone react rapidly, long chain ketones react more slowly. Aromatically substituted ketones only react ve...
Keywords: Titrations

Enzymatic Assay Kits for Nutrients

Enzymes have found widespread use as analytical tools in food, biochemical and pharmaceutical industries. Because they provide specific, reproducible, sensitive and rapid measurements, they are ideal...
Andrea Felgner
AnalytiX Volume 7 Article 4
Keywords: Absorption, Catalysis, Centrifugation, Filtration, Industries, Metabolism, Nucleic acid denaturation, Oxidations, Pharmaceutical, Reductions, Sample preparations, Solvents

Enzymatic Food Analysis

Enzymatic methods for food analysis are highly specific and offer considerable time and cost savings over other methods, especially from the sample preparation standpoint. Sigma-Aldrich offers a wide...
Jvo Siegrist
Product Manager Microbiology ivo.siegrist@sial.com, AnalytiX Volume 9 Article 2
Keywords: Absorption, Clinical, Degradations, Diabetes, Enzyme activity, Food Analysis, Nutrition, Obesity, Sample preparations

Related Content

Specification Comparison

For a complete list of all available unit sizes and product specifications, simply click on the product numbers above!
Keywords: Absorption, Evaporation, High performance liquid chromatography

Peer-Reviewed Papers

References

Set your institution to view full text papers.

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Prediction of skeletal muscle and fat mass in patients with advanced cancer using a metabolomic approach. Stretch C, Eastman T, Mandal R, et al. J. Nutr. 142(1), 14-21, (2012)

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Toxicokinetic interactions between orally ingested chlorzoxazone and inhaled acetone or toluene in male volunteers. Ernstgård L, Gullstrand E, Johanson G, et al. Toxicol. Sci. 48(2), 189-96, (1999)

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Hydrogen-driven asymmetric reduction of hydroxyacetone to (R)-1,2-propanediol by Ralstonia eutropha transformant expressing alcohol dehydrogenase from Kluyveromyces lactis. Oda T, Oda K, Yamamoto H, et al. Microb. Cell Fact. 12(1), 2, (2013)

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Acetone as an anticonvulsant. Likhodii S, Nylen K, and Burnham WM Epilepsia 49 Suppl 8, 83-6, (2008)

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Carbon X-ray absorption spectra of fluoroethenes and acetone: a study at the coupled cluster, density functional, and static-exchange levels of theory. Fransson T, Coriani S, Christiansen O, et al. J. Chem. Phys. 138(12), 124311, (2013)

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Plasma amino acid profile on nocturnal hemodialysis. Raj DS, Ouwendyk M, Francoeur R, et al. Blood Purif. 18(2), 97-102, (2000)

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Effects of LB broth, naphthalene concentration, and acetone on the naphthalene degradation activities by Pseudomonas putida G7. Chang SY, Liu XG, Ren BQ, et al. Water Environ. Res. 87(1), 61-7, (2015)

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Breath metabolite response to major upper gastrointestinal surgery. Boshier PR, Mistry V, Cushnir JR, et al. J. Surg. Res. 193(2), 704-12, (2015)

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Aminoacetone oxidase from Streptococcus oligofermentans belongs to a new three-domain family of bacterial flavoproteins. Molla G, Nardini M, Motta P, et al. Biochem. J. 464(3), 387-99, (2014)

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Construction of monomer-free, highly crosslinked, water-compatible polymers. Dailing EA, Lewis SH, Barros MD, et al. J. Dent. Res. 93(12), 1326-31, (2014)

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[Alternative type of fuel--biobutanol]. Tigunova EA, Shul'ga SM, and Blium IaB Tsitol. Genet. 47(6), 51-71, (2013)

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[Death after explosion of an "empty" acetone barrel]. Preuss-Wössner J and Gerling I Arch. Kriminol. 232(3-4), 113-8, (2013)

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Chemical composition and biological evaluation of Physalis peruviana root as hepato-renal protective agent. El-Gengaihi SE, Hassan EE, Hamed MA, et al. J. Diet. Suppl. 10(1), 39-53, (2013)

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You can get there from here: acetone, anionic ketones and even-carbon fatty acids can provide substrates for gluconeogenesis. Glew RH Niger. J. Physiol. Sci. 25(1), 2-4, (2010)

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Medicinal properties of fractionated acetone/water neem [Azadirachta indica] leaf extract from Nigeria: a review. Anyaehie UB Niger. J. Physiol. Sci. 24(2), 157-9, (2009)

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Hyperventilation in severe diabetic ketoacidosis. Tasker RC, Lutman D, and Peters MJ Pediatr. Crit. Care Med. 6(4), 405-11, (2005)

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Antidiabetic agents and lactation. Benz J J. Hum. Lact. 8(1), 27-8, (1992)

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[Isopropanol and acetone level in serum after preoperative surface disinfection with antiseptics containing isopropanol]. Wittmann S, Gilg T, Dietz HG, et al. Blutalkohol 29(5), 326-35, (1992)

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Synthesis, characterization and application of a novel starch-based flocculant with high flocculation and dewatering properties. Wang JP, Yuan SJ, Wang Y, et al. Water Res. 47(8), 2643-8, (2013)

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Magnetic microsphere-confined graphene for the extraction of polycyclic aromatic hydrocarbons from environmental water samples coupled with high performance liquid chromatography-fluorescence analysis. Wang W, Ma R, Wu Q, et al. J. Chromatogr. A 1293, 20-7, (2013)

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Calculating virtual log P in the alkane/water system (log P(N)(alk)) and its derived parameters deltalog P(N)(oct-alk) and log D(pH)(alk). Giulia Caron et al J. Med. Chem. 48, 3269-79, (2005)

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Accumulation of trimethylamine and trimethylamine-N-oxide in end-stage renal disease patients undergoing haemodialysis. Bain MA, Faull R, Fornasini G, et al. Nephrol. Dial. Transplant. 21(5), 1300-4, (2006)

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Diversonol and blennolide derivatives from the endophytic fungus Microdiplodia sp.: absolute configuration of diversonol. Imran Nafees Siddiqui et al J. Nat. Prod. 74, 365-73, (2011)

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Chemical modification of reactive multilayered films fabricated from poly(2-alkenyl azlactone)s: design of surfaces that prevent or promote mammalian cell adhesion and bacterial biofilm growth. Buck ME Biomacromolecules 10(6), 1564-74, (2009)

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1,5-anhydroglucitol and postprandial hyperglycemia as measured by continuous glucose monitoring system in moderately controlled patients with diabetes. Dungan KM, Buse JB, Largay J, et al. Diabetes Care 29(6), 1214-9, (2006)

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Keratinocyte-specific Smad2 ablation results in increased epithelial-mesenchymal transition during skin cancer formation and progression. Hoot KE J. Clin. Invest. 118(8), 2722-32, (2008)

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Novel and neglected issues of acetone-butanol-ethanol (ABE) fermentation by clostridia: Clostridium metabolic diversity, tools for process mapping and continuous fermentation systems. Patakova P, Linhova M, Rychtera M, et al. Biotechnol. Adv. 31(1), 58-67, (2013)

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Dimethylglycine accumulates in uremia and predicts elevated plasma homocysteine concentrations. McGregor DO, Dellow WJ, Lever M, et al. Kidney Int. 59(6), 2267-72, (2001)

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The acetone-butanol-ethanol fermentation: recent progress in technology. Maddox IS Biotechnol. Genet. Eng. Rev. 7, 189-220, (1989)

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Achievements and perspectives to overcome the poor solvent resistance in acetone and butanol-producing microorganisms. Ezeji T, Milne C, Price ND, et al. Appl. Microbiol. Biotechnol. 85(6), 1697-712, (2010)

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Analysis of submicron-sized niflumic acid crystals prepared by electrospray crystallization. Ambrus R, Radacsi N, Szunyogh T, et al. J. Pharm. Biomed. Anal. 76, 1-7, (2013)

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Solid phase microextraction, mass spectrometry and metabolomic approaches for detection of potential urinary cancer biomarkers--a powerful strategy for breast cancer diagnosis. Silva CL, Passos M, and Câmara JS Talanta 89, 360-8, (2012)

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Recent progress on industrial fermentative production of acetone-butanol-ethanol by Clostridium acetobutylicum in China. Ni Y and Sun Z Appl. Microbiol. Biotechnol. 83(3), 415-23, (2009)

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Analysis of volatile organic compounds in human urine by headspace gas chromatography-mass spectrometry with a multipurpose sampler. Wahl HG, Hoffmann A, Luft D, et al. J. Chromatogr. A 847(1-2), 117-25, (1999)

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Detection of autosomal dominant polycystic kidney disease by NMR spectroscopic fingerprinting of urine. Gronwald W, Klein MS, Zeltner R, et al. Kidney Int. 79(11), 1244-53, (2011)

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Bacterial acetone and butanol production by industrial fermentation in the Soviet Union: use of hydrolyzed agricultural waste for biorefinery. Zverlov VV, Berezina O, Velikodvorskaya GA, et al. Appl. Microbiol. Biotechnol. 71(5), 587-97, (2006)

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Increased plasma phenylacetic acid in patients with end-stage renal failure inhibits iNOS expression. Jankowski J, van der Giet M, Jankowski V, et al. J. Clin. Invest. 112(2), 256-64, (2003)

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Characteristics and antioxidative ability of defatted rice bran extracts obtained using several extractants under subcritical conditions. Chiou TY, Ogino A, Kobayashi T, et al. J. Oleo Sci. 62(1), 1-8, (2013)

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Nonaggregational shape-persistent cyclo[6]aramide and its macrocyclic effect toward binding secondary ammonium salts in moderately polar media. Hu J, Chen L, Ren Y, et al. Org. Lett. 15(18), 4670-3, (2013)

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pi-Acidic alkene ligand effects in Pd-catalysed cross-coupling processes: exploiting the interaction of dibenzylidene acetone (dba) and related ligands with Pd(0) and Pd(II). Fairlamb IJ Org. Biomol. Chem. 6(20), 3645-56, (2008)

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Can serum beta-hydroxybutyrate be used to diagnose diabetic ketoacidosis? Sheikh-Ali M, Karon BS, Basu A, et al. Diabetes Care 31(4), 643-7, (2008)

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A quantitative study of the influence of inhaled compounds on their concentrations in exhaled breath. Spaněl P, Dryahina K, and Smith D J. Breath Res. 7(1), 017106, (2013)

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Improvement on the catalytic performance of Mg-Zr mixed oxides for furfural-acetone aldol condensation by supporting on mesoporous carbons. Faba L, Díaz E, and Ordóñez S ChemSusChem 6(3), 463-73, (2013)

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High throughput proteomic analysis of the secretome in an explant model of articular cartilage inflammation. Abigail L. Clutterbuck et al J. Proteomics 74, 704-15, (2011)

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Scale-up of polyamide and polyester Parsol® MCX nanocapsules by interfacial polycondensation and solvent diffusion method. Stumpo M, Anselmi C, Vauthier C, et al. Int. J. Pharm. 454(2), 678-85, (2013)

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Global response of Plasmodium falciparum to hyperoxia: a combined transcriptomic and proteomic approach. Torrentino-Madamet M Malaria Journal 10, 4, (2011)

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Relationship between skin acetone and blood beta-hydroxybutyrate concentrations in diabetes. Yamane N, Tsuda T, Nose K, et al. Clin. Chim. Acta 365(1-2), 325-9, (2006)

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Ferricytochrome (c) directly oxidizes aminoacetone to methylglyoxal, a catabolite accumulated in carbonyl stress. Sartori A, Mano CM, Mantovani MC, et al. PLoS ONE 8(3), e57790, (2013)

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Bacteriophage infections in the industrial acetone butanol (AB) fermentation process. Jones DT, Shirley M, Wu X, et al. J. Mol. Microbiol. Biotechnol. 2(1), 21-6, (2000)

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Orientation correlation of p-nitroaniline molecules in acetone solution observed by hyper-Rayleigh scattering. Shelton DP J. Chem. Phys. 138(5), 054502, (2013)

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Air to lung partition coefficients for volatile organic compounds and blood to lung partition coefficients for volatile organic compounds and drugs. Michael H Abraham et al Eur. J. Med. Chem. 43, 478-85, (2008)

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Plasma pteridine concentrations in patients with chronic renal failure. Yokoyama K, Tajima M, Yoshida H, et al. Nephrol. Dial. Transplant. 17(6), 1032-6, (2002)

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A new method for pH triggered curcumin release by applying poly(L-lysine) mediated nanoparticle-congregation. Patra D and Sleem F Anal. Chim. Acta 795, 60-8, (2013)

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Development of a one-step microwave-assisted extraction method for simultaneous determination of organophosphorus pesticides and fungicides in soils by gas chromatography-mass spectrometry. Merdassa Y, Liu JF, and Megersa N Talanta 114, 227-34, (2013)

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Formation of dimethylketene and methacrolein by reaction of the CH radical with acetone. Goulay F, Derakhshan A, Maher E, et al. Phys. Chem. Chem. Phys. 15(11), 4049-58, (2013)

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High-performance liquid chromatographic determination of acetone in blood and urine in the clinical diagnostic laboratory. Brega A, Villa P, Quadrini G, et al. J. Chromatogr. A 553(1-2), 249-54, (1991)

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Determination of polyamines in hydrolysates of uremic plasma by high-performance cation-exchange column chromatography. Takagi T, Chung TG, and Saito A J. Chromatogr. A 272(2), 279-85, (1983)

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The acetone-butanol-ethanol fermentation. Awang GM, Jones GA, and Ingledew WM Crit. Rev. Microbiol 15 Suppl 1, S33-67, (1988)

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reliable Synthesis of Monodisperse Microparticles: Prevention of Oxygen Diffusion and Organic Solvents Using Conformal Polymeric Coating onto Poly(dimethylsiloxane) Micromold. Jeong JM, Oh MS, Kim BJ, et al. Langmuir 29(10), 3474-81, (2013)

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Integrative modelling of pH-dependent enzyme activity and transcriptomic regulation of the acetone-butanol-ethanol fermentation of Clostridium acetobutylicum in continuous culture. Millat T, Janssen H, Bahl H, et al. Microb. Biotechnol. 6(5), 526-39, (2013)

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[Association of plasma ammonia and GABA levels and the degree of hepatic encephalopathy]. Campollo O, MacGillivray BB, and McIntyre N Rev. Invest. Clin. 44(4), 483-90, (1992)

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Is breath acetone a biomarker of diabetes? A historical review on breath acetone measurements. Wang Z and Wang C J. Breath Res. 7(3), 037109, (2013)

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Real-time multi-marker measurement of organic compounds in human breath: towards fingerprinting breath. White IR, Willis KA, Whyte C, et al. J. Breath Res. 7(1), 017112, (2013)

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Fluorimetric assay of D-lactate. McLellan AC, Phillips SA, and Thornalley PJ Anal. Biochem. 206(1), 12-6, (1992)

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The economics of acetone-butanol fermentation: theoretical and market considerations. Gapes JR J. Mol. Microbiol. Biotechnol. 2(1), 27-32, (2000)

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Effects of tissue fixation on coherent anti-Stokes Raman scattering images of brain. Galli R, Uckermann O, Koch E, et al. J. Biomed. Opt. 19(7), 071402, (2014)

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Retention models and interaction mechanisms of acetone and other carbonyl-containing molecules with amylose tris[(S)-α-methylbenzylcarbamate] sorbent. Tsui HW, Hwang MY, Ling L, et al. J. Chromatogr. A 1279, 36-48, (2013)

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Determination of 3-methylhistidine and 1-methylhistidine in untreated urine samples by capillary electrophoresis. Tůma P, Samcová E, and Balínová P J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 821(1), 53-9, (2005)

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Increased oxidation and decreased conjugation of drugs in the liver caused by starvation. Altered metabolism of certain aromatic compounds and acetone. Mandl J, Bánhegyi G, Kalapos MP, et al. Chem. Biol. Interact. 96(2), 87-101, (1995)

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Elimination half-life of acetone in humans: case reports and review of the literature. Jones AW J. Anal. Toxicol. 24(1), 8-10, (2000)

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An analysis of human response to the irritancy of acetone vapors. Arts JH, Mojet J, van Gemert LJ, et al. Crit. Rev. Toxicol. 32(1), 43-66, (2002)

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Quantification of endogenous aliphatic alcohols in serum and urine. Liebich HM, Buelow HJ, and Kallmayer R J. Chromatogr. A 239, 343-9, (1982)

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Characteristics and antioxidative activity of the acetone-soluble and -insoluble fractions of a defatted rice bran extract obtained by using an aqueous organic solvent under subcritical conditions. Chiou TY, Kobayashi T, and Adachi S Biosci. Biotechnol. Biochem. 77(3), 624-30, (2013)

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Relationship between omega-3 fatty acids and plasma neuroactive steroids in alcoholism, depression and controls. Nieminen LR, Makino KK, Mehta N, et al. Prostaglandins Leukot. Essent. Fatty Acids 75(4-5), 309-14, (2006)

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Stimulation of tolbutamide hydroxylation by acetone and acetonitrile in human liver microsomes and in a cytochrome P-450 2C9-reconstituted system. Palamanda J, Feng WW, Lin CC, et al. Drug Metab. Dispos. 28(1), 38-43, (2000)

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Dimethylamine in human urine. Zhang AQ, Mitchell SC, and Smith RL Clin. Chim. Acta 233(1-2), 81-8, (1995)

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Serum 7 alpha-hydroxy-4-cholesten-3-one and selenohomocholyltaurine (SeHCAT) whole body retention in the assessment of bile acid induced diarrhoea. Brydon WG, Nyhlin H, Eastwood MA, et al. Eur. J. Gastroenterol. Hepatol. 8(2), 117-23, (1996)

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Structure-activity relationships of 1'S-1'-acetoxychavicol acetate for inhibitory effect on NO production in lipopolysaccharide-activated mouse peritoneal macrophages. Hisashi Matsuda et al Bioorg. Med. Chem. Lett. 15, 1949-53, (2005)

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The acetone-butanol fermentation in pilot plant and pre-industrial scale. Nimcevic D and Gapes JR J. Mol. Microbiol. Biotechnol. 2(1), 15-20, (2000)

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Unchanged serum levels of advanced glycation endproducts in patients with liver disease. Butscheid M, Schäfer C, Brenner S, et al. Naunyn Schmiedebergs Arch. Pharmacol. 375(6), 401-6, (2007)

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Monitoring breath during oral glucose tolerance tests. Ghimenti S, Tabucchi S, Lomonaco T, et al. J. Breath Res. 7(1), 017115, (2013)

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Non-(13)CO2 targeted breath tests: a feasibility study. Ruzsanyi V, Lederer W, Seger C, et al. J. Breath Res. 8(4), 046005, (2014)

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Plasma histamine in patients with chronic renal failure and nephrotic syndrome. Gill DS, Fonseca VA, Barradas MA, et al. J. Clin. Pathol. 44(3), 243-5, (1991)

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Serum 1,5-anhydroglucitol (Glycomark) levels in children with and without type 1 diabetes mellitus. Nguyen TM, Rodriguez LM, Mason KJ, et al. Pediatr. Diabetes 8(4), 214-9, (2007)

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Effects of oral administration of zinc and diiodohydroxyquinolein on plasma zinc levels of uremic patients. Paniagua R, Claure R, Amato D, et al. Nephron 69(2), 147-50, (1995)

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Molecular dynamics study of self-agglomeration of charged fullerenes in solvents. Banerjee S J. Chem. Phys. 138(4), 044318, (2013)

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Fixation requirements for the immunohistochemical reactivity of PCNA antibody PC10 on cryostat sections. Baum HP, Reichrath J, Theobald A, et al. Histochem. J. 26(12), 929-33, (1994)

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Contribution of 3-hydroxyisobutyrate to the measurement of 3-hydroxybutyrate in human plasma: comparison of enzymatic and gas-liquid chromatography-mass spectrometry assays in normal and in diabetic subjects. Avogaro A and Bier DM J. Lipid Res. 30(11), 1811-7, (1989)

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Plasma 3-methylbutanal in man and its relationship to hepatic encephalopathy. Marshall AW, DeSouza M, and Morgan MY Clin. Physiol. 5(1), 53-62, (1985)

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Merck 14,66

Beil. 1,IV,3180

Fieser 2,13 / Fieser 3,4 / Fieser 6,9

Aldrich MSDS 1, 12:B / Arctander, 18 / Corp MSDS 1 (1), 20:A / FT-IR 2 (1), 640:A / FT-IR 1 (1), 405:A / FT-NMR 1 (1), 631:A / Fenaroli / IR-Spectra (2), 214:A / IR-Spectra (3), 240:A / NMR-Reference 2 (1), 369:A / RegBook 1 (1), 447:A / Sax 6, 89 / Structure Index 1, 64:A:1 / Vapor Phase 3, 487:A

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