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34854 Sigma-Aldrich

Chloroform

CHROMASOLV®, for HPLC, ≥99.8%, amylene stabilized

Synonym: Methylidyne trichloride, Trichloromethane

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Properties

Related Categories Amber Glass Bottles, Analytical Reagents, Analytical/Chromatography, Chloroform, Chromatography Reagents & Solvents,
grade   CHROMASOLV®
  for HPLC
vapor density   4.1 (vs air)
vapor pressure   160 mmHg ( 20 °C)
assay   ≥99.8%
quality   amylene stabilized
impurities   Free acid, in accordance
  acetone, aldehyde, in accordance (nessler test)
  free chlorine (Cl), in accordance
  ≤0.0005% non-volatile matter
  ≤0.001% free acid (as HCl)
  <0.01% water (Karl Fischer)
evapn. residue   ≤0.0005%
color   APHA: ≤10
transmittance   250 nm, ≥50%
  260 nm, ≥85%
  280 nm, ≥99%
refractive index   n20/D 1.445(lit.)
bp   60.5-61.5 °C(lit.)
mp   −63 °C(lit.)
density   1.48 g/mL at 25 °C
  1.492 g/mL at 25 °C(lit.)
anion traces   chloride (Cl-): in accordance
cation traces   Pb: ≤0.05 mg/kg
absorption   absorption/ in accordance
λ   H2O reference
UV absorption   λ: 250 nm Amax: ≤1.00
  λ: 260 nm Amax: ≤0.30
  λ: 280 nm Amax: ≤0.005
suitability   passes test for reaction against H2SO4
  passes test for suitability of determ. w. dithizone

Description

Other Notes

A -D suffix exists for administrative purposes only.
All -D packages are 100% the same product, same quality, same specification as the package sizes previously sold without a -D.

Legal Information

CHROMASOLV is a registered trademark of Honeywell Specialty Chemicals Seelze GmbH

Price and Availability

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Precautionary statements 
RIDADR 
UN 1888 6.1 / PGIII
WGK Germany 
3
RTECS 
FS9100000

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles
Peer-Reviewed Papers

References

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Direct tandem mass spectrometric profiling of sulfatides in dry urinary samples for screening of metachromatic leukodystrophy. Kuchař L, Asfaw B, Poupětová H, et al. Clin. Chim. Acta 425, 153-9, (2013)

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Adhesion and hemifusion of cytoplasmic myelin lipid membranes are highly dependent on the lipid composition. Banquy X, Kristiansen K, Lee DW, et al. Biochim. Biophys. Acta 1818(3), 402-10, (2012)

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Photolysis of chloroform and other organic molecules in aqueous titanium dioxide suspensions. Kormann C, et al. Environ. Sci. Technol. 25(3), 494-500, (1991)

Differential regulation of microRNAs in end-stage failing hearts is associated with left ventricular assist device unloading. Barsanti C, Trivella MG, D'Aurizio R, et al. Biomed Res. Int. 2015, 592512, (2015)

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Evaluation and integration of genetic signature for prediction risk of nasopharyngeal carcinoma in Southern China. Guo X, Winkler CA, Li J, et al. Biomed Res. Int. 2014, 434072, (2014)

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Fabrication of enrofloxacin imprinted organic-inorganic hybrid mesoporous sorbent from nanomagnetic polyhedral oligomeric silsesquioxanes for the selective extraction of fluoroquinolones in milk samples. He HB, Dong C, Li B, et al. J. Chromatogr. A. 1361, 23-33, (2014)

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A real-time study of the benefits of co-solvents in polymer solar cell processing. van Franeker JJ, Turbiez M, Li W, et al. Nat. Commun. 6, 6229, (2015)

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Preservation of viral genomes in 700-y-old caribou feces from a subarctic ice patch. Ng TF, Chen LF, Zhou Y, et al. Proc. Natl. Acad. Sci. U. S. A. 111(47), 16842-7, (2014)

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A molecular nematic liquid crystalline material for high-performance organic photovoltaics. Sun K, Xiao Z, Lu S, et al. Nat. Commun. 6, 6013, (2015)

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Chondrogenesis of mesenchymal stem cells in an osteochondral environment is mediated by the subchondral bone. de Vries-van Melle ML, Narcisi R, Kops N, et al. Tissue Eng. Part A 20(1-2), 23-33, (2014)

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Impaired hematopoietic differentiation of RUNX1-mutated induced pluripotent stem cells derived from FPD/AML patients. Sakurai M, Kunimoto H, Watanabe N, et al. Leukemia 28(12), 2344-54, (2014)

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Ligand-engaged TCR is triggered by Lck not associated with CD8 coreceptor. Casas J, Brzostek J, Zarnitsyna VI, et al. Nat. Commun. 5, 5624, (2014)

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Cationic liposomes loaded with a synthetic long peptide and poly(I:C): a defined adjuvanted vaccine for induction of antigen-specific T cell cytotoxicity. Varypataki EM, van der Maaden K, Bouwstra J, et al. AAPS J. 17(1), 216-26, (2015)

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Effects of selective digestive decontamination (SDD) on the gut resistome. Buelow E, Gonzalez TB, Versluis D, et al. J. Antimicrob. Chemother. 69(8), 2215-23, (2014)

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Electrochemical detection of leukemia oncogenes using enzyme-loaded carbon nanotube labels. Lee AC, Du D, Chen B, et al. Analyst 139(17), 4223-30, (2014)

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Propagation of human corneal endothelial cells: a novel dual media approach. Peh GS, Chng Z, Ang HP, et al. Cell. Transplant. 24(2), 287-304, (2015)

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Dairy proteins, dairy lipids, and postprandial lipemia in persons with abdominal obesity (DairyHealth): a 12-wk, randomized, parallel-controlled, double-blinded, diet intervention study. Bohl M, Bjørnshave A, Rasmussen KV, et al. Am. J. Clin. Nutr. 101(4), 870-8, (2015)

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HepaRG cells as human-relevant in vitro model to study the effects of inflammatory stimuli on cytochrome P450 isoenzymes. Rubin K, Janefeldt A, Andersson L, et al. Drug Metab. Dispos. 43(1), 119-25, (2014)

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An HIV-encoded antisense long noncoding RNA epigenetically regulates viral transcription. Saayman S, Ackley A, Turner AM, et al. Mol. Ther. 22(6), 1164-75, (2014)

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Serum and adipose tissue amino acid homeostasis in the metabolically healthy obese. Badoud F, Lam KP, DiBattista A, et al. J. Proteome Res. 13(7), 3455-66, (2014)

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Proteomic analysis of human fetal atria and ventricle. Lu ZQ, Sinha A, Sharma P, et al. J. Proteome Res. 13(12), 5869-78, (2014)

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Staphylococcus aureus from 152 cases of bovine, ovine and caprine mastitis investigated by Multiple-locus variable number of tandem repeat analysis (MLVA). Bergonier D, Sobral D, Feßler AT, et al. Vet. Res. 45, 97, (2015)

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Short sequences can efficiently recruit histone H3 lysine 27 trimethylation in the absence of enhancer activity and DNA methylation. Jermann P, Hoerner L, Burger L, et al. Proc. Natl. Acad. Sci. U. S. A. 111(33), E3415-21, (2014)

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Taking the temperature of the interiors of magnetically heated nanoparticles. Dong J, Zink JI, et al. ACS Nano 8(5), 5199-207, (2014)

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Disaccharides impact the lateral organization of lipid membranes. Moiset G, López CA, Bartelds R, et al. J. Am. Chem. Soc. 136(46), 16167-75, (2015)

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VAV3 mediates resistance to breast cancer endocrine therapy. Aguilar H, Urruticoechea A, Halonen P, et al. Breast Cancer Res. 16(3), R53, (2014)

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Vma9p need not be associated with the yeast V-ATPase for fully-coupled proton pumping activity in vitro. Bueler SA, Rubinstein JL, et al. Biochemistry 54(3), 853-8, (2015)

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Osteotropic polypeptide nanoparticles with dual hydroxyapatite binding properties and controlled cisplatin delivery. de Miguel L, Popa I, Noiray M, et al. Pharm. Res. 32(5), 1794-803, (2015)

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Spontaneous transmembrane helix insertion thermodynamically mimics translocon-guided insertion. Ulmschneider MB, Ulmschneider JP, Schiller N, et al. Nat. Commun. 5, 4863, (2014)

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Coordination-driven folding and assembly of a short peptide into a protein-like two-nanometer-sized channel. Sawada T, Matsumoto A, Fujita M, et al. Angew. Chem. Int. Ed. Engl. 53(28), 7228-32, (2014)

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Quantitative phosphoproteomic analysis of signaling downstream of the prostaglandin e2/g-protein coupled receptor in human synovial fibroblasts: potential antifibrotic networks. Gerarduzzi C, He Q, Antoniou J, et al. J. Proteome Res. 13(11), 5262-80, (2014)

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Enhancing effects of salt formation on catalytic activity and enantioselectivity for asymmetric hydrogenation of isoquinolinium salts by dinuclear halide-bridged iridium complexes bearing chiral diphosphine ligands. Kita Y, Yamaji K, Higashida K, et al. Chemistry 21(5), 1915-27, (2015)

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Genome data from a sixteenth century pig illuminate modern breed relationships. Ramírez O, Burgos-Paz W, Casas E, et al. Heredity (Edinb.) 114(2), 175-84, (2015)

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In situ gelling polyvalerolactone-based thermosensitive hydrogel for sustained drug delivery. Mishra GP, Kinser R, Wierzbicki IH, et al. Eur. J. Pharm. Biopharm. 88(2), 397-405, (2014)

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Topical drug delivery to retinal pigment epithelium with microfluidizer produced small liposomes. Lajunen T, Hisazumi K, Kanazawa T, et al. Eur. J. Pharm. Sci. 62, 23-32, (2014)

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Isolation and immortalization of MIP-GFP neurons from the hypothalamus. Wang ZC, Wheeler MB, Belsham DD, et al. Endocrinology 155(6), 2314-9, (2014)

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C-type natriuretic peptide attenuates lipopolysaccharide-induced acute lung injury in mice. Kimura T, Nojiri T, Hosoda H, et al. J. Surg. Res. 194(2), 631-7, (2015)

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An integrated omics approach to the characterization of maize (Zea mays L.) mutants deficient in the expression of two genes encoding cytosolic glutamine synthetase. Amiour N, Imbaud S, Clément G, et al. BMC Genomics 15, 1005, (2014)

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Importance of branched-chain amino acid utilization in Francisella intracellular adaptation. Gesbert G, Ramond E, Tros F, et al. Infect. Immun. 83(1), 173-83, (2015)

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A comparative study of techniques for differential expression analysis on RNA-Seq data. Zhang ZH, Jhaveri DJ, Marshall VM, et al. PLoS ONE 9(8), e103207, (2014)

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Changing climate and the altitudinal range of avian malaria in the Hawaiian Islands - an ongoing conservation crisis on the island of Kaua'i. Atkinson CT, Utzurrum RB, Lapointe DA, et al. Glob. Chang. Biol. 20(8), 2426-36, (2014)

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Integrative cross-omics analysis in primary mouse hepatocytes unravels mechanisms of cyclosporin A-induced hepatotoxicity. Van den Hof WF, Van Summeren A, Lommen A, et al. Toxicology 324, 18-26, (2014)

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TLR4 accessory molecule RP105 (CD180) regulates monocyte-driven arteriogenesis in a murine hind limb ischemia model. Bastiaansen AJ, Karper JC, Wezel A, et al. PLoS ONE 9(6), e99882, (2014)

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Natural compounds boldine and menthol are antagonists of human 5-HT3 receptors: implications for treating gastrointestinal disorders. Walstab J, Wohlfarth C, Hovius R, et al. Neurogastroenterol. Motil. 26(6), 810-20, (2014)

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Chromosome conformation maps in fission yeast reveal cell cycle dependent sub nuclear structure. Grand RS, Pichugina T, Gehlen LR, et al. Nucleic Acids Res. 42(20), 12585-99, (2014)

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Simultaneous analysis for water- and fat-soluble vitamins by a novel single chromatography technique unifying supercritical fluid chromatography and liquid chromatography. Taguchi K, Fukusaki E, Bamba T, et al. J. Chromatogr. A. 1362, 270-7, (2014)

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Sema6a and Plxna2 mediate spatially regulated repulsion within the developing eye to promote eye vesicle cohesion. Ebert AM, Childs SJ, Hehr CL, et al. Development 141(12), 2473-82, (2014)

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Fibre-specific responses to endurance and low volume high intensity interval training: striking similarities in acute and chronic adaptation. Scribbans TD, Edgett BA, Vorobej K, et al. PLoS ONE 9(6), e98119, (2014)

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Nucleosome regulatory dynamics in response to TGF?. Enroth S, Andersson R, Bysani M, et al. Nucleic Acids Res. 42(11), 6921-34, (2014)

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Formation of oxidized phosphatidylinositol and 12-oxo-phytodienoic acid containing acylated phosphatidylglycerol during the hypersensitive response in Arabidopsis. Nilsson AK, Johansson ON, Fahlberg P, et al. Phytochemistry 101, 65-75, (2014)

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Merck 14,2141

Beil. 1,IV,42

Fieser 1,29 / Fieser 1,130 / Fieser 1,30 / Fieser 3,140 / Fieser 4,22 / Fieser 5,28 / Fieser 8,92 / Fieser 12,517 / Fieser 14,167 / Fieser 15,84

Aldrich MSDS 1, 405:C / Corp MSDS 1 (1), 786:C / FT-IR 1 (1), 83:A / FT-IR 2 (1), 117:D / FT-NMR 1 (1), 122:A / IR-Spectra (2), 49:E / IR-Spectra (3), 51:G / NMR-Reference 2 (1), 81:C / RegBook 1 (1), 81:D / Sax 6, 722 / Structure Index 1, 9:D:10 / Vapor Phase 3, 116:C

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