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394904 Sigma-Aldrich

Pentafluoropropionic anhydride

for GC derivatization, 99%

Synonym: PFPA, Perfluoropropionic anhydride

  • CAS Number 356-42-3

  • Linear Formula (CF3CF2CO)2O

  • Molecular Weight 310.05

  •  Beilstein Registry Number 1806446

  •  EC Number 206-604-2

  •  MDL number MFCD00000429

  •  PubChem Substance ID 329755875

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Properties

Related Categories β-Glucuronidase Drug Analysis Bundle, Analytical and Industrial Enzymes, Biochemicals and Reagents, Building Blocks, Carbonyl Compounds,
grade   for GC derivatization
InChI Key   XETRHNFRKCNWAJ-UHFFFAOYSA-N
assay   99%
bp   69-70 °C/735 mmHg(lit.)
density   1.571 g/mL at 25 °C(lit.)

Description

Other Notes

Same product — same quality — now Sigma-Aldrich brand

Packaging

10×1, 5, 25, 100 mL in ampule

Application

Pentafluoropropionic anhydride (PFPA) was used as derivatization reagent for urine samples to determine the presence of codeine, morphine, 6-monoacetylmorphine, ethylmorphine, and dihydrocodeine using GC-MS in selected ion monitoring (SIM) mode. It was also used to derivatize the dry pericardial fluid sample extracts for quantification of cocaine, benzoylecgonine, and cocaethylene in pericardial fluid using GC-MS.

Price and Availability

Safety & Documentation

Safety Information

Symbol 
GHS05  GHS05
Signal word 
Danger
Hazard statements 
Precautionary statements 
Supplemental Hazard Statements 
Reacts violently with water.
RIDADR 
UN 3265 8 / PGII
WGK Germany 
3
Protocols & Articles
Peer-Reviewed Papers
15

References

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