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40239 Sigma-Aldrich

(R)-(+)-N,N-Dimethyl-1-ferrocenylethylamine

purum, ≥98.0% (T)

Synonym: (R)-(+)-[1-(Dimethylamino)ethyl]ferrocene

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Catalysts, Ligands, and Reagents, Other Chiral Ligands
InChI Key   ISOLNZQTVMCEOI-YCBDHFTFSA-N
grade   purum
assay   ≥98.0% (T)
optical activity   [α]20/D +14±1°, c = 1.5% in ethanol
color   dark brown
refractive index   n20/D 1.589(lit.)
bp   120-121 °C/0.7 mmHg(lit.)
density   1.222 g/mL at 20 °C(lit.)

Description

Other Notes

This chiral ferrocene derivative can be stereoselectively lithiated and derivatized; synthesis of chiral ferrocenyl phosphines, ligands for rhodium(I)

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Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
235.4 °F
Flash Point(C) 
113 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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344125 (R)-(+)-N,N-Dimethyl-1-ferrocenylethylamine, 97%

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