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410241 Sigma-Aldrich

Sodium perchlorate

ACS reagent, ≥98.0%

Synonym: Hyperchloric acid sodium salt

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Properties

Related Categories Chemical Synthesis, Essential Chemicals, Oxidizing Agents, Perchlorates, Research Essentials,
grade   ACS reagent
assay   ≥98.0%
impurities   ≤0.005% insolubles
pH   6.0-8.0 (25 °C, 5%)
mp   468 °C(lit.)
anion traces   chloride (Cl-): ≤0.003%
  sulfate (SO42-): ≤0.002%
cation traces   Ca: ≤0.02%
  Fe: ≤5 ppm
  K: ≤0.05%
  heavy metals (as Pb): ≤5 ppm

Description

Packaging

100, 500 g in glass bottle

2.5 kg in glass bottle

Price and Availability


Ultra-high Purity Salts

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Hazard Codes (Europe) 
Risk Statements (Europe) 
Safety Statements (Europe) 
13-22-27
RIDADR 
UN 1502 5.1 / PGII
WGK Germany 
1
RTECS 
SC9800000

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Articles

Determination of Water Content in Sodium perchlorate Using Karl Fischer Titration

Adherent water in salts can be easily determined. It is best to choose a working medium which will prevent the salt from dissolving, e.g. a Methanol-Chloroform mixture with an excess of Chloroform. T...
Keywords: Crystallization, Titrations

Peer-Reviewed Papers

References

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Inhibition of the š‘-carbonic anhydrase from Streptococcus pneumoniae by inorganic anions and small molecules: Toward innovative drug design of antiinfectives? Peter Burghout et al Bioorg. Med. Chem. 19, 243-8, (2011)

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Ultrafast dynamics of hydrogen bond exchange in aqueous ionic solutions. Park S, Odelius M, and Gaffney KJ J. Phys. Chem. B 113(22), 7825-35, (2009)

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Oxoammonium salt/NaClO2: an expedient, catalytic system for one-pot oxidation of primary alcohols to carboxylic acids with broad substrate applicability. Shibuya M, Sato T, Tomizawa M, et al. Chem. Commun. (Camb.) (13), 1739-41, (2009)

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[Heterotopic transplantation of non-immunogenic trachea populated with recipient bone marrow stromal cells]. Kisilevskiĭ MV, Anisimova NIu, Lebedinskaia OV, et al. Morfologiia. 141(1), 66-70, (2012)

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Fast and continuous preparation of high polymerization degree cellulose nanofibrils and their three-dimensional macroporous scaffold fabrication. Song J, Tang A, Liu T, et al. Nanoscale 5(6), 2482-90, (2013)

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Inhibition studies with anions and small molecules of two novel α-carbonic anhydrases from the bacterial pathogen Salmonella enterica serovar Typhimurium. Daniela Vullo et al Bioorg. Med. Chem. Lett. 21, 3591-5, (2011)

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New insights about the posttranscriptional mechanisms triggered by iodide excess on sodium/iodide symporter (NIS) expression in PCCl3 cells. Serrano-Nascimento C, Calil-Silveira J, Goulart-Silva F, et al. Mol. Cell. Endocrinol. 349(2), 154-61, (2012)

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Significance of oral administration of sodium perchlorate in planning liver-directed radioembolization. Sabet A, Ahmadzadehfar H, Muckle M, et al. J. Nucl. Med. 52(7), 1063-7, (2011)

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Interconnection of salt-induced hydrophobic compaction and secondary structure formation depends on solution conditions: revisiting early events of protein folding at single molecule resolution. Haldar S and Chattopadhyay K J. Biol. Chem. 287(14), 11546-55, (2012)

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Non-specific binding and general cross-reactivity of Y receptor agonists are correlated and should importantly depend on their acidic sectors. Parker MS, Sah R, et al. Peptides 32, 258-265, (2011)

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Effects of Hofmeister ions on the α-helical structure of proteins. Crevenna AH, Naredi-Rainer N, Lamb DC, et al. Biophys. J. 102(4), 907-15, (2012)

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Orientational relaxation dynamics in aqueous ionic solution: polarization-selective two-dimensional infrared study of angular jump-exchange dynamics in aqueous 6M NaClO4. Ji M and Gaffney KJ J. Chem. Phys. 134(4), 044516, (2011)

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Phase system selection with fractional factorial design for purification of recombinant cyanovirin-N from a hydroponic culture medium using centrifugal partition chromatography. Grudzień Ł, Madeira L, Fisher D, et al. J. Chromatogr. A 1285, 57-68, (2013)

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Sodium perchlorate effects on the helical stability of a mainly alanine peptide. Asciutto EK, General IJ, Xiong K, et al. Biophys. J. 98(2), 186-96, (2010)

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IGF-1 receptor deficiency in thyrocytes impairs thyroid hormone secretion and completely inhibits TSH-stimulated goiter. Ock S, Ahn J, Lee SH, et al. FASEB J. 27(12), 4899-908, (2013)

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Facing the nuclear threat: thyroid blocking revisited. Hänscheid H, Reiners C, Goulko G, et al. J. Clin. Endocrinol. Metab. 96(11), 3511-6, (2011)

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Purification and inhibition studies with anions and sulfonamides of an α-carbonic anhydrase from the Antarctic seal Leptonychotes weddellii. Alessandra Cincinelli et al Bioorg. Med. Chem. 19, 1847-51, (2011)

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Effect of sodium and acetate ions on 8-hydroxyguanine formation in irradiated aqueous solutions of DNA and 2'-deoxyguanosine 5'-monophosphate. Grygoryev D, Moskalenko O, and Zimbrick JD Int. J. Radiat. Biol. 87(9), 974-83, (2011)

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Arsenic speciation in natural and contaminated waters using CZE with in situ derivatization by molybdate and direct UV-detection. Koshcheeva OS, Shuvaeva OV, and Kuznetzova LI Electrophoresis 30(6), 1088-93, (2009)

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Comparative effects of in ovo exposure to sodium perchlorate on development, growth, metabolism, and thyroid function in the common snapping turtle (Chelydra serpentina) and red-eared slider (Trachemys scripta elegans). Eisenreich KM, Dean KM, Ottinger MA, et al. Comp. Biochem. Physiol. C. Toxicol. Pharmacol. 156(3-4), 166-70, (2012)

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Detection of paeoniflorin and albiflorin by immunostaining technique using anti-paeoniflorin monoclonal antibody. Morinaga O, Lu Z, Lin L, et al. Phytochem. Anal. 24(2), 124-8, (2013)

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Study of charge distribution on the surface of biocolloids. Dziubakiewicz E, Hrynkiewicz K, Walczyk M, et al. Colloids Surf. B Biointerfaces 104, 122-7, (2013)

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Notable effects of the metal salts on the formation and decay reactions of α-tocopheroxyl radical in acetonitrile solution. The complex formation between α-tocopheroxyl and metal cations. Kohno Y, Fujii M, Matsuoka C, et al. J. Phys. Chem. B 115(32), 9880-8, (2011)

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Anion inhibition studies of an α-carbonic anhydrase from the living fossil Astrosclera willeyana. Anna Ohradanova et al Bioorg. Med. Chem. Lett. 22, 1314-6, (2012)

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Pseudohypocalcemia caused by perchlorate (Irenat). Durner J, Winkler-Budenhofer U, Gahr S, et al. Clin. Chem. Lab Med. 49(4), 665-7, (2011)

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Electrochemical characterization of riboflavin-enhanced reduction of trinitrotoluene. Sumner JJ and Chu K Sensors (Basel.) 11(11), 10840-50, (2011)

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Impact of ion binding on poly-L-lysine (un)folding energy landscape and kinetics. Xiong K and Asher SA J. Phys. Chem. B 116(24), 7102-12, (2012)

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Effects of water temperature on perchlorate toxicity to the thyroid and reproductive system of Oryzias latipes. Lee S, Ji K, and Choi K Ecotoxicol. Environ. Saf. 108, 311-7, (2014)

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Vibrational spectroscopy and ionic conductivity of polyethylene oxide-NaClO4-CuO nanocomposite. Dey A, Das K, Karan S, et al. Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 83(1), 384-91, (2011)

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The effect of perchlorate medication on point-of-care testing. Hopf S, Bäumel M, Gruber M, et al. Clin. Lab. 58(9-10), 1067-70, (2012)

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Optimization of a method for preparation and repopulation of the tracheal matrix for allogenic transplantation. Kiselevsky MV, Anisimova NY, Lebedinskaya OV, et al. Bull. Exp. Biol. Med. 151(1), 107-13, (2011)

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Merck 14,8653

Aldrich MSDS 1, 1613:B / Corp MSDS 1 (2), 3150:A / FT-IR 2 (3), 4761:D / FT-IR 1 (2), 1253:C / RegBook 1 (3), 3455:G / Sax 6, 2145

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