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471305 Sigma-Aldrich

Butylamine

99.5%

Synonym: 1-Aminobutane, n-Butylamine

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Properties

vapor density   2.5 (vs air)
vapor pressure   68 mmHg ( 20 °C)
assay   99.5%
autoignition temp.   594 °F
expl. lim.   9.8 %
refractive index   n20/D 1.401(lit.)
bp   78 °C(lit.)
mp   −49 °C(lit.)
density   0.74 g/mL at 25 °C(lit.)

Description

Packaging

1, 2, 2.5 L in glass bottle

25, 250 mL in glass bottle

Price and Availability

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Hazard Codes (Europe) 
F,C
Risk Statements (Europe) 
Safety Statements (Europe) 
3-16-26-29-36/37/39-45
RIDADR 
UN 1125 8(3) / PGII
WGK Germany 
1
RTECS 
EO2975000
Flash Point(F) 
21.2 °F
Flash Point(C) 
-6 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

Articles

Determination of Water Content in n-Butylamine Using Karl Fischer Titration

Nitrogen compounds, acid amides and weakly basic amines (heterocyclenes) give no problems. They can be titrated according to the standard procedures. Strongly basic amines alter the pH value and must...
Keywords: Titrations

Peer-Reviewed Papers

References

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Lipophilicity of basic drugs measured by hydrophilic interaction chromatography. Bruno Bard et al J. Med. Chem. 52, 3416-9, (2009)

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One-step advanced preparation of surface-functional peptide nanospheres by the polymerization of L-phenylalanine N-carboxyanhydride with dual initiators. Matsusaki M, Waku T, Kaneko T, et al. Langmuir 22(4), 1396-9, (2006)

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[Newly leaching method of copper from waste print circuit board using hydrochloric acid/n-butylamine/copper sulfate]. Wang HY, Cui ZJ, and Yao YW Huan Jing Ke Xue 31(12), 3099-103, (2010)

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Calculating virtual log P in the alkane/water system (log P(N)(alk)) and its derived parameters deltalog P(N)(oct-alk) and log D(pH)(alk). Giulia Caron et al J. Med. Chem. 48, 3269-79, (2005)

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Chemistry-toxicity relationships for the effects of di- and trihydroxybenzenes to Tetrahymena pyriformis. Aptula AO, Roberts DW, Cronin MT, et al. Chem. Res. Toxicol. 18(5), 844-54, (2005)

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Homochiral oligopeptides via a lattice-controlled polymerisation in racemic crystals of valine N-carboxyanhydride suspended in aqueous solutions. Eliash R, Nery JG, Rubinstein I, et al. Chemistry 13(36), 10140-51, (2007)

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Influence of short chain organic acids and bases on the wetting properties and surface energy of submicrometer ceramic powders. Neirinck B, Soccol D, Fransaer J, et al. J. Colloid. Interface Sci. 348(2), 654-60, (2010)

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Water soluble cationic trans-platinum complexes which induce programmed cell death in the protozoan parasite Leishmania infantum. Nguewa PA, Fuertes MA, Iborra S, et al. J. Inorg. Biochem. 99(3), 727-36, (2005)

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Electrophilic reactions of skin-sensitizing sultones. Roberts DW, Williams DL, and Bethell D Chem. Res. Toxicol. 20(1), 61-71, (2007)

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Leishmania donovani polyamine biosynthetic enzyme overproducers as tools to investigate the mode of action of cytotoxic polyamine analogs. Sigrid C Roberts et al Antimicrob. Agents Chemother. 51, 438-45, (2007)

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A novel biosensing interfacial design produced by assembling nano-Au particles on amine-terminated plasma-polymerized films. Wang H, Wang C, Lei C, et al. Anal. Bioanal. Chem 377(4), 632-8, (2003)

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Polyamines as olfactory stimuli in the goldfish Carassius auratus. Rolen SH, Sorensen PW, Mattson D, et al. J. Exp. Biol. 206(Pt 10), 1683-96, (2003)

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Direct synthesis and bonding origins of monolayer-protected silver nanocrystals from silver nitrate through in situ ligand exchange. Lee KJ, Lee YI, Shim IK, et al. J. Colloid. Interface Sci. 304(1), 92-7, (2006)

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Reactivity of the insecticide fenitrothion toward O and N nucleophiles. Rougier NM, Vico RV, de Rossi RH, et al. J. Org. Chem. 75(10), 3427-36, (2010)

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Adsorption and binding of capping molecules for highly luminescent CdSe nanocrystals--DFT simulation studies. Chou HL, Tseng CH, Pillai KC, et al. Nanoscale 2(12), 2679-84, (2010)

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The water-hydrophobic interface: neutral and charged solute adsorption at fluorocarbon and hydrocarbon self-assembled monolayers (SAMs). Hopkins AJ and Richmond GL Appl. Spectrosc. 67(3), 261-73, (2013)

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Influence of different transition metals in phthalocyanines on their interaction energies with volatile organic compounds: an experimental and computational study. Fietzek C and Mack HG J. Mol. Model. 13(1), 11-7, (2007)

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Developmental toxicity of oral n-butylamine hydrochloride and inhaled n-butylamine in rats. Gamer AO, Hellwig J, and van Ravenzwaay B Food Chem. Toxicol. 40(12), 1833-42, (2002)

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Interaction of 2,3-dichloro-1,4-naphthoquinone with n-butylamine in halocarbon solvents. Neelgund GM and Budni ML Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 61(8), 1729-35, (2005)

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Photocatalytic treatment of municipal wastewater using modified neodymium doped TiO(2) hybrid nanoparticles. Shahmoradi B, Ibrahim IA, Sakamoto N, et al. J. Environ. Sci. Health. A. Tox. Hazard. Subst. Environ. Eng. 45(10), 1248-55, (2010)

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Dual buffer gases for ion manipulation in a miniature ion trap mass spectrometer with a discontinuous atmospheric pressure interface. Chen TC, Xu W, and Ouyang Z Rapid Commun. Mass Spectrom. 25(21), 3274-80, (2011)

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Fluorescence quenching of Rhodamine B base by two amines. Bakkialakshmi S, Selvarani P, and Chenthamarai S Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 105, 557-62, (2013)

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Mammalian spermidine synthase--identification of cysteine residues and investigation of the putrescine binding site--. Goda H, Watanabe T, Takeda N, et al. Biol. Pharm. Bull. 27(9), 1327-32, (2004)

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Interaction of protonated merocyanine dyes with amines in organic solvents. Ribeiro EA, Sidooski T, Nandi LG, et al. Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 81(1), 745-53, (2011)

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Chemiluminescence associated with amino acid oxidation mediated by hypochlorous acid. Aspée A and Lissi EA Luminescence 17(3), 158-64, (2002)

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Novel enamine derivatives of 5,6-dihydro-2'-deoxyuridine formed in reductive amination of 5-formyl-2'-deoxyuridine. Sochacka E and Smuga D Nucleosides Nucleotides Nucleic Acids 27(9), 1045-60, (2008)

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[Preparation and FTIR properties of amino compounds modified glutaraldehyde crosslinked chitosan resin activated with cyanuric chloride]. Feng CG, Bai LS, and Ren QS Guang Pu Xue Yu Guang Pu Fen Xi 24(11), 1315-8, (2004)

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The many roles for fluorine in medicinal chemistry. William K Hagmann et al J. Med. Chem. 51, 4359-69, (2008)

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Merck 14,1543

Beil. 4,IV,540

Corp MSDS 1 (1), 614:B / FT-IR 1 (1), 281:A / FT-NMR 1 (1), 450:C / Fenaroli / NMR-Reference 2 (1), 239:B / RegBook 1 (1), 301:K / Sax 6, 565 / Structure Index 1, 41:A:3 / Vapor Phase 3, 364:D

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