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471356 Sigma-Aldrich

Methanesulfonic acid

≥99.5%

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Properties

Related Categories Acids, Acids & Bases, Chemical Synthesis, Organic Acids, Synthetic Reagents More...
vapor density   3.3 (vs air)
vapor pressure   1 mmHg ( 20 °C)
assay   ≥99.5%
refractive index   n20/D 1.429(lit.)
bp   167 °C/10 mmHg(lit.)
mp   17-19 °C(lit.)
density   1.481 g/mL at 25 °C(lit.)

Description

Packaging

2.5 L in glass bottle

5 L in poly drum

5, 25, 100, 500 mL in glass bottle

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PharmaGrade, Manufactured under appropriate GMP controls for pharma or biopharmaceutical production

Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN 3265 8 / PGII
WGK Germany 
1
RTECS 
PB1140000
Flash Point(F) 
372.2 °F
Flash Point(C) 
189 °C

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles

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Peer-Reviewed Papers

References

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The gas-phase reaction of methane sulfonic acid with the hydroxyl radical without and with water vapor. Jørgensen S, Jensen C, Kjaergaard HG, et al. Phys. Chem. Chem. Phys. 15(14), 5140-50, (2013)

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One-pot primary aminomethylation of aryl and heteroaryl halides with sodium phthalimidomethyltrifluoroborate. Murai N, Miyano M, Yonaga M, et al. Org. Lett. 14(11), 2818-21, (2012)

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1H-1,2,4-Triazole as solvent for imidazolium methanesulfonate. Luo J, Tan TV, Conrad O, et al. Phys. Chem. Chem. Phys. 14(32), 11441-7, (2012)

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A highly stable, efficient visible-light driven water photoelectrolysis system using a nanocrystalline WO3 photoanode and a methane sulfonic acid electrolyte. Solarska R, Jurczakowski R, and Augustynski J Nanoscale 4(5), 1553-6, (2012)

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Cyclopropenone catalyzed substitution of alcohols with mesylate ion. Nacsa ED and Lambert TH Org. Lett. 15(1), 38-41, (2013)

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Synthesis, antimicrobial and antiproliferative activity of novel silver(I) tris(pyrazolyl)methanesulfonate and 1,3,5-triaza-7-phosphadamantane complexes. Pettinari C, Marchetti F, Lupidi G, et al. Inorg. Chem. 50(21), 11173-83, (2011)

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Synthesis of aryl ethers via a sulfonyl transfer reaction. Sach NW, Richter DT, Cripps S, et al. Org. Lett. 14(15), 3886-9, (2012)

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Low-cost gas sensors produced by the graphite line-patterning technique applied to monitoring banana ripeness. Manzoli A, Steffens C, Paschoalin RT, et al. Sensors (Basel.) 11(6), 6425-34, (2011)

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Real-Time detection and mixing state of methanesulfonate in single particles at an inland urban location during a phytoplankton bloom. Gaston CJ, Pratt KA, Qin X, et al. Environ. Sci. Technol. 44(5), 1566-72, (2010)

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In vivo reactivation by oximes of inhibited blood, brain and peripheral tissue cholinesterase activity following exposure to nerve agents in guinea pigs. Shih TM, Skovira JW, O'Donnell JC, et al. Chem. Biol. Interact. 187(1-3), 207-14, (2010)

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Internal structure, hygroscopic and reactive properties of mixed sodium methanesulfonate-sodium chloride particles. Liu Y, Minofar B, Desyaterik Y, et al. Phys. Chem. Chem. Phys. 13(25), 11846-57, (2011)

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Synthesis and chromatographic enantioresolution of anti-HIV quinolone derivatives. Natalini B, Sardella R, Massari S, et al. Talanta 85(3), 1392-7, (2011)

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Prediction of the effects of methanol and competing ion concentration on retention in the ion chromatographic separation of anionic and cationic pharmaceutically related compounds. Zakaria P, Dicinoski G, Hanna-Brown M, et al. J. Chromatogr. A 1217(39), 6069-76, (2010)

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One pot synthesis and anticancer activity of dimeric phloroglucinols. Chauthe SK, Bharate SB, Periyasamy G, et al. Bioorg. Med. Chem. Lett. 22(6), 2251-6, (2012)

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Interfacial molecular organization at aqueous solution surfaces of atmospherically relevant dimethyl sulfoxide and methanesulfonic Acid using sum frequency spectroscopy and molecular dynamics simulation. Chen X, Minofar B, Jungwirth P, et al. J. Phys. Chem. B 114(47), 15546-53, (2010)

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RB·E2F1 complex mediates DNA damage responses through transcriptional regulation of ZBRK1. Liao CC, Tsai CY, Chang WC, et al. J. Biol. Chem. 285(43), 33134-43, (2010)

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Degrees of freedom effect on fragmentation in tandem mass spectrometry of singly charged supramolecular aggregates of sodium sulfonates. Indelicato S, Bongiorno D, Indelicato S, et al. J. Mass Spectrom. 48(3), 379-83, (2013)

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Isolation and structure characterization of related impurities in 10-O-(N,N-dimethylaminoethyl)-ginkgolide B methanesulfonate (XQ-1H) bulk drug and quantitation by a validated RP-LC. Liu W, Li P, Feng F, et al. J. Pharm. Biomed. Anal. 52(4), 603-8, (2010)

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Distribution of stable free radicals among amino acids of isolated soy proteins. Lei Q, Liebold CM, Boatright WL, et al. J. Food Sci. 75(7), C633-40, (2010)

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Conformational behaviour of peptides containing a 2-pyrrolidinemethanesulfonic acid (2PyMS) residue. Grygorenko OO, Zhersh S, Oliinyk BV, et al. Org. Biomol. Chem. 11(6), 975-83, (2013)

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Application of hydrophilic interaction chromatography retention coefficients for predicting peptide elution with TFA and methanesulfonic acid ion-pairing reagents. Wujcik CE, Tweed J, and Kadar EP J. Sep. Sci. 33(6-7), 826-33, (2010)

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Evaluation of dibutyrylchitin as new excipient for sustained drug release. Casettari L, Cespi M, and Castagnino E Drug Dev. Ind. Pharm. 38(8), 979-84, (2012)

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Simultaneous determination of organic and cationic species in explosives residues with column-switching liquid chromatography-ion chromatography system. Xie P, Xu J, Hu Z, et al. J. Chromatogr. Sci. 49(8), 622-7, (2011)

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Ethyl methanesulphonate in a parenteral formulation of BMS-214662 mesylate, a selective farnesyltransferase inhibitor: formation and rate of hydrolysis. Nassar MN, Cucolo M, and Miller SA Pharm. Dev. Technol. 14(6), 672-7, (2009)

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Statistically sound calibration curves for chromatographic methods involving negative response data. Vanatta LE and Cowles DC J. Chromatogr. Sci. 49(8), 610-1, (2011)

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