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50070 Sigma-Aldrich

Glycinamide hydrochloride

≥99.0% (AT)

  • CAS Number 1668-10-6

  • Linear Formula NH2CH2CONH2 · HCl

  • Molecular Weight 110.54

  •  Beilstein Registry Number 3554199

  •  EC Number 216-789-1

  •  MDL number MFCD00013008

  •  PubChem Substance ID 24873333

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Properties

Related Categories A - H, Amides, Amino Acids, Biochemicals and Reagents, Building Blocks,
InChI Key   WKNMKGVLOWGGOU-UHFFFAOYSA-N
assay   ≥99.0% (AT)
pKa (20 °C)   8.20
solubility   H2O: soluble0.1 g/mL, clear, colorless
anion traces   sulfate (SO42-): ≤50 mg/kg
cation traces   Ca: ≤10 mg/kg
  Cd: ≤5 mg/kg
  Co: ≤5 mg/kg
  Cr: ≤5 mg/kg
  Cu: ≤5 mg/kg
  Fe: ≤5 mg/kg
  K: ≤50 mg/kg
  Mg: ≤5 mg/kg
  Mn: ≤5 mg/kg
  Na: ≤50 mg/kg
  Ni: ≤5 mg/kg
  Pb: ≤5 mg/kg
  Zn: ≤5 mg/kg
λ   0.5 M in H2O
UV absorption   λ: 260 nm Amax: 0.1

Description

Other Notes

Use in peptide coupling.

Same product — same quality — now Sigma-Aldrich brand

Application

Glycinamide hydrochloride may be used in the synthesis of [M(glycinamidato-N,N′)(ptpy)2] where ptpy = 2-(p-tolyl)pyridinato) and M= Rh or Ir.
It may be used in the synthesis of the following glycinamide-based imidazolidinones:
• (±)-2-(2-phenylpropyl)imidazolidin-4-one
• (±)-2-(2,4,4-trimethylpentyl)imidazolidin-4-one
• (±)-2-[(R)-2,6-dimethyl-5-heptenyl]imidazolidin-4-one
• (5R,6S,9R)-6-isopropyl-9-methyl-1,4-diazaspiro[4.5]decan-2-one
• (5S,6S,9R)-6-isopropyl-9-methyl-1,4-diazaspiro[4.5]decan-2-one
• (±)-2-methyl-2-pentylimidazolidin-4-one
• (±)-2-ethyl-2-(2-methylbutyl)imidazolidin-4-one
• (±)-2-(undecan-2-yl)imidazolidin-4-one
• (±)-2-pentylimidazolidin-4-one
• 2-(2,4-dimethylcyclohex-3-en-1-yl)imidazolidin-4-one

Price and Availability

Suggested Laboratory Gloves


Laboratory GlovesThis substance has been tested against several types of hand protection for CE compliance. Click below to find the recommended gloves for handling this product.



Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3

Documents

Certificate of Analysis

Certificate of Origin

Protocols & Articles
Peer-Reviewed Papers
15

References

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