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89680 Sigma-Aldrich

Toluene

analytical standard

  • CAS Number 108-88-3

  • Linear Formula C6H5CH3

  • Molecular Weight 92.14

  •  Beilstein Registry Number 635760

  •  EC Number 203-625-9

  •  MDL number MFCD00008512

  •  PubChem Substance ID 329769525

  •  eCl@ss 39011102

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Properties

Related Categories Additional Standards, Alpha Sort, Analytical Standards, Analytical/Chromatography, Aromatics,
grade   analytical standard
vapor density   3.2 (vs air)
vapor pressure   22 mmHg ( 20 °C)
  26 mmHg ( 25 °C)
InChI Key   YXFVVABEGXRONW-UHFFFAOYSA-N
assay   ≥99.9% (GC)
form   neat
autoignition temp.   997 °F
shelf life   limited shelf life, expiry date on the label
expl. lim.   7 %
application(s)   HPLC: suitable
  gas chromatography (GC): suitable
color   colorless
refractive index   n/D 1.496(lit.)
bp   110-111 °C(lit.)
mp   -93 °C(lit.)
density   0.865 g/mL at 25 °C(lit.)
format   neat

Description

Packaging

5, 25 mL in glass bottle

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Price and Availability


Pharma QC
Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
RIDADR 
UN1294 - class 3 - PG 2 - Toluene
WGK Germany 
2
RTECS 
XS5250000
Flash Point(F) 
39.2 °F
Flash Point(C) 
4 °C
Protocols & Articles

Articles

ASTM D5134: GC Analysis of Hydrocarbons on Petrocol® DH 50.2

From our library of Articles, Sigma-Aldrich presents ASTM D5134: GC Analysis of Hydrocarbons on Petrocol® DH 50.2
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography

ASTM D6526: GC Analysis of Impurities in Toluene on SLB®-IL100, 30 m Column

From our library of Articles, Sigma-Aldrich presents ASTM D6526: GC Analysis of Impurities in Toluene on SLB®-IL100, 30 m Column
Keywords: Chromatography, Flame ionization detector, Gas chromatography

ASTM D6526: GC Analysis of Impurities in Toluene on SLB®-IL100, 60 m Column

From our library of Articles, Sigma-Aldrich presents ASTM D6526: GC Analysis of Impurities in Toluene on SLB®-IL100, 60 m Column
Keywords: Chromatography, Gas chromatography

GC Analysis of Aromatics in Reforµlated Gasoline on Equity®-1

From our library of Articles, Sigma-Aldrich presents GC Analysis of Aromatics in Reforµlated Gasoline on Equity®-1
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Aromatics in Reforµlated Gasoline on SLB®-IL111

From our library of Articles, Sigma-Aldrich presents GC Analysis of Aromatics in Reforµlated Gasoline on SLB®-IL111
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Separation

GC Analysis of Aromatics in Reforµlated Gasoline on SUPELCOWAX® 10

From our library of Articles, Sigma-Aldrich presents GC Analysis of Aromatics in Reforµlated Gasoline on SUPELCOWAX® 10
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of BTEX, Undecane, and Tridecane on SLB®-IL100

From our library of Articles, Sigma-Aldrich presents GC Analysis of BTEX, Undecane, and Tridecane on SLB®-IL100
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Class 2 Residual Solvents on Equity®-1 after SPME using 85 μm Polyacrylate Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Class 2 Residual Solvents on Equity®-1 after SPME using 85 μm Polyacrylate Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Pharmaceutical, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of Class 2 Residual Solvents on OVI-G43

From our library of Articles, Sigma-Aldrich presents GC Analysis of Class 2 Residual Solvents on OVI-G43
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Pharmaceutical, Size-exclusion chromatography

GC Analysis of Class 2 Residual Solvents on VOCOL® after SPME using 85 μm Polyacrylate Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Class 2 Residual Solvents on VOCOL® after SPME using 85 μm Polyacrylate Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Pharmaceutical, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of Gasoline Residue in Arson Samples on a 100% Methyl Column after SPME using 100 μm PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Gasoline Residue in Arson Samples on a 100% Methyl Column after SPME using 100 μm PDMS Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Sample preparations, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of Hydrocarbons in Gasoline on Equity®-1 (15 m x 0.10 mm I.D., 0.10 μm), Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents GC Analysis of Hydrocarbons in Gasoline on Equity®-1 (15 m x 0.10 mm I.D., 0.10 μm), Fast GC Analysis
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Size-exclusion chromatography

GC Analysis of Hydrocarbons in Gasoline on Petrocol® DH, Isothermal

From our library of Articles, Sigma-Aldrich presents GC Analysis of Hydrocarbons in Gasoline on Petrocol® DH, Isothermal
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Separation

GC Analysis of Hydrocarbons in Gasoline on Petrocol® DH

From our library of Articles, Sigma-Aldrich presents GC Analysis of Hydrocarbons in Gasoline on Petrocol® DH
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography

GC Analysis of Industrial Solvents on Equity®-1701

From our library of Articles, Sigma-Aldrich presents GC Analysis of Industrial Solvents on Equity®-1701
Keywords: Chromatography, Flame ionization detector, Gas chromatography

GC Analysis of Industrial Solvents on Equity®-1

From our library of Articles, Sigma-Aldrich presents GC Analysis of Industrial Solvents on Equity®-1
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography

GC Analysis of Industrial Solvents on SUPELCOWAX 10

From our library of Articles, Sigma-Aldrich presents GC Analysis of Industrial Solvents on SUPELCOWAX 10
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Ionic Liquid Test Mix on SLB®-IL100 (15 m x 0.10 mm I.D., 0.08 μm)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Ionic Liquid Test Mix on SLB®-IL100 (15 m x 0.10 mm I.D., 0.08 μm)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Ionic Liquid Test Mix on SLB®-IL100 (30 m x 0.25 mm I.D., 0.20 μm)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Ionic Liquid Test Mix on SLB®-IL100 (30 m x 0.25 mm I.D., 0.20 μm)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Ionic Liquid Test Mix on SLB®-IL59 (15 m x 0.10 mm I.D., 0.08 μm)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Ionic Liquid Test Mix on SLB®-IL59 (15 m x 0.10 mm I.D., 0.08 μm)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Ionic Liquid Test Mix on SLB®-IL59 (30 m x 0.25 mm I.D., 0.20 μm)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Ionic Liquid Test Mix on SLB®-IL59 (30 m x 0.25 mm I.D., 0.20 μm)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Ionic Liquid Test Mix on SLB®-IL76 (15 m x 0.10 mm I.D., 0.08 μm)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Ionic Liquid Test Mix on SLB®-IL76 (15 m x 0.10 mm I.D., 0.08 μm)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Ionic Liquid Test Mix on SLB®-IL76 (30 m x 0.25 mm I.D., 0.20 μm)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Ionic Liquid Test Mix on SLB®-IL76 (30 m x 0.25 mm I.D., 0.20 μm)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Refinery Grade Unleaded Gasoline on TCEP (15 m x 0.10 mm I.D., 0.18 μm), Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents GC Analysis of Refinery Grade Unleaded Gasoline on TCEP (15 m x 0.10 mm I.D., 0.18 μm), Fast GC Analysis
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Solvents on a Packed Column (3% SP-1500 on Carbopack™ B)

From our library of Articles, Sigma-Aldrich presents GC Analysis of Solvents on a Packed Column (3% SP-1500 on Carbopack™ B)
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of TCEP Test Mix on SLB®-IL100, 100 °C Oven Temp.

From our library of Articles, Sigma-Aldrich presents GC Analysis of TCEP Test Mix on SLB®-IL100, 100 °C Oven Temp.
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of TCEP Test Mix on SLB®-IL100, 110 °C Oven Temp.

From our library of Articles, Sigma-Aldrich presents GC Analysis of TCEP Test Mix on SLB®-IL100, 110 °C Oven Temp.
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of TCEP Test Mix on SLB®-IL100, 80 °C Oven Temp.

From our library of Articles, Sigma-Aldrich presents GC Analysis of TCEP Test Mix on SLB®-IL100, 80 °C Oven Temp.
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification

GC Analysis of Volatiles in Water on Equity®-1 after SPME using 30 μm PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles in Water on Equity®-1 after SPME using 30 μm PDMS Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography, Solid phase microextractions

GC Analysis of Volatiles in Water on SPB®-1 after SPME using 100 μm PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles in Water on SPB®-1 after SPME using 100 μm PDMS Fiber
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Solid phase microextractions

GC Analysis of Volatiles on SPB®-624, Direct Injection

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles on SPB®-624, Direct Injection
Keywords: Chromatography, Gas chromatography, Purification, Size-exclusion chromatography

GC Analysis of Volatiles on VOCOL® after SPME using 75 μm Carboxen/PDMS Fiber

From our library of Articles, Sigma-Aldrich presents GC Analysis of Volatiles on VOCOL® after SPME using 75 μm Carboxen/PDMS Fiber
Keywords: Chromatography, Gas chromatography, Mass spectrometry, Purification, Solid phase microextractions

GC Analysis of Xylene Isomers on SLB®-IL60

From our library of Articles, Sigma-Aldrich presents GC Analysis of Xylene Isomers on SLB®-IL60
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Separation, Size-exclusion chromatography

GC Analysis of a 56-Component Industrial Solvents Mix on SLB®-IL60, Comparison to a Polyethylene Glycol (PEG) Column

From our library of Articles, Sigma-Aldrich presents GC Analysis of a 56-Component Industrial Solvents Mix on SLB®-IL60, Comparison to a Polyethylene Glycol (PEG) Column
Keywords: Chromatography, Flame ionization detector, Gas chromatography

HPLC Analysis of Benzene and Deuterated Benzene on Ascentis® Express C18

From our library of Articles, Sigma-Aldrich presents HPLC Analysis of Benzene and Deuterated Benzene on Ascentis® Express C18
Keywords: Chromatography, High performance liquid chromatography

HPLC Analysis of Column Test Mix on Discovery® BIO Wide Pore C18, Effect of HPLC Column I.D. on Sensitivity

From our library of Articles, Sigma-Aldrich presents HPLC Analysis of Column Test Mix on Discovery® BIO Wide Pore C18, Effect of HPLC Column I.D. on Sensitivity
Keywords: Chromatography, High performance liquid chromatography

HPLC Analysis of Polar and Non-Polar Analytes on Ascentis® Express C18, Column Test Mixture

From our library of Articles, Sigma-Aldrich presents HPLC Analysis of Polar and Non-Polar Analytes on Ascentis® Express C18, Column Test Mixture
Keywords: Chromatography, High performance liquid chromatography, Pharmaceutical

HPLC Analysis of Polar and Non-Polar Analytes on Ascentis® Express C8, Column Test Mixture

From our library of Articles, Sigma-Aldrich presents HPLC Analysis of Polar and Non-Polar Analytes on Ascentis® Express C8, Column Test Mixture
Keywords: Chromatography, High performance liquid chromatography, Pharmaceutical

The Utility of Headspace Grade Solvents for the Analysis of Organic Volatile Impurities

Organic volatile impurities or “OVIs” sometimes remain behind in pharmaceutical preparations as a result of synthetic and manufacturing procedures. For reasons of health and safety, testing is done t...
Katherine Stenerson, Shyam Verma
Reporter US Volume 28.1
Keywords: Chromatography, Gas chromatography, Organic synthesis, Pharmaceutical, Solvents

UHPLC Analysis of Deuterated Isomers on Titan™ C18

From our library of Articles, Sigma-Aldrich presents UHPLC Analysis of Deuterated Isomers on Titan™ C18
Keywords: Anticonvulsants, Chromatography

US EPA Method 0030: GC Analysis of Volatiles on SPB®-624 after Collection/Desorption using VOST 100 Tube

From our library of Articles, Sigma-Aldrich presents US EPA Method 0030: GC Analysis of Volatiles on SPB®-624 after Collection/Desorption using VOST 100 Tube
Keywords: Air Monitoring, Chromatography, Flame ionization detector, Gas chromatography, Purification

US EPA Method 502.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap, ELCD Signal

From our library of Articles, Sigma-Aldrich presents US EPA Method 502.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap, ELCD Signal
Keywords: Chromatography, Gas chromatography, Hall electrolytic conductivity detector, Photo-ionization detector, Purge and trap, Sample preparations

US EPA Method 502.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap, PID Signal

From our library of Articles, Sigma-Aldrich presents US EPA Method 502.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap, PID Signal
Keywords: Chromatography, Gas chromatography, Hall electrolytic conductivity detector, Photo-ionization detector, Purification

US EPA Method 524.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 524.2: GC Analysis of Volatiles on VOCOL® (105 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap
Keywords: Chromatography, Gas chromatography, Purification, Size-exclusion chromatography

US EPA Method 624: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 624: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 624: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 624: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 624: GC Analysis of Volatiles on VOCOL® (60 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 624: GC Analysis of Volatiles on VOCOL® (60 m x 0.53 mm I.D.) after Purge & Trap using "K" Trap
Keywords: Chromatography, Gas chromatography, Purification, Size-exclusion chromatography

US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on Equity®-1 (15 m x 0.10 mm I.D., 0.10 μm), Direct Injection, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on Equity®-1 (15 m x 0.10 mm I.D., 0.10 μm), Direct Injection, Fast GC Analysis
Keywords: Chromatography, Flame ionization detector, Gas chromatography, Purification, Size-exclusion chromatography

US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on Equity®-1 after Purge & Trap using "M" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on Equity®-1 after Purge & Trap using "M" Trap
Keywords: Chromatography, Environmental, Flame ionization detector, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on VOCOL® after Purge & Trap using "M" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 8015 (modified): GC Analysis of Gasoline Range Organics (GRO) on VOCOL® after Purge & Trap using "M" Trap
Keywords: Chromatography, Environmental, Flame ionization detector, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Gas chromatography, Gas chromatography mass spectrometry, Mass spectrometry, Purge and trap, Purification, Solid phase microextractions

US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 8260: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 8260: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method 8260: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Gas chromatography, Purification, Solid phase microextractions

US EPA Method 8260: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap

From our library of Articles, Sigma-Aldrich presents US EPA Method 8260: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap
Keywords: Chromatography, Gas chromatography, Purification, Solid phase microextractions

US EPA Method OLM04.2 VOA: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method OLM04.2 VOA: GC Analysis of Volatiles on SPB®-624 after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method OLM04.2 VOA: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap, Fast GC Analysis

From our library of Articles, Sigma-Aldrich presents US EPA Method OLM04.2 VOA: GC Analysis of Volatiles on VOCOL® after Purge & Trap using "K" Trap, Fast GC Analysis
Keywords: Chromatography, Environmental, Gas chromatography, Purification, Solid phase microextractions

US EPA Method TO-17: GC Analysis of Volatiles on Equity®-1 after Collection/Desorption using Carbotrap 300 Tube

From our library of Articles, Sigma-Aldrich presents US EPA Method TO-17: GC Analysis of Volatiles on Equity®-1 after Collection/Desorption using Carbotrap 300 Tube
Keywords: Chromatography, Gas chromatography

US EPA Method TO-17: GC Analysis of Volatiles on VOCOL® after Collection/Desorption using Air Toxics Tube

From our library of Articles, Sigma-Aldrich presents US EPA Method TO-17: GC Analysis of Volatiles on VOCOL® after Collection/Desorption using Air Toxics Tube
Keywords: Air Monitoring, Chromatography, Flame ionization detector, Gas chromatography, Purification

Peer-Reviewed Papers
15

References

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