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92766 Sigma-Aldrich

(Trimethylsilyl)methanol

purum, ≥97.0% (GC)

Synonym: (Hydroxymethyl)trimethylsilane

  • CAS Number 3219-63-4

  • Linear Formula (CH3)3SiCH2OH

  • Molecular Weight 104.22

  •  Beilstein Registry Number 1731486

  •  EC Number 221-746-5

  •  MDL number MFCD00004596

  •  PubChem Substance ID 24889720

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Properties

Related Categories Alcohols, Building Blocks, C2 to C6, Chemical Synthesis, Organic Building Blocks,
InChI Key   ZQKNBDOVPOZPLY-UHFFFAOYSA-N
grade   purum
assay   ≥97.0% (GC)
refractive index   n20/D 1.419(lit.)
  n20/D 1.419
bp   120-122 °C/754 mmHg(lit.)
density   0.826 g/mL at 25 °C(lit.)
storage temp.   2-8°C

Description

Other Notes

Starting material for the synthesis of trimethylsilylmethyl triflate; nucleophilic hydroxymethylation with the corresponding lithium carbonate; oxidation to the aldehyde and addition reactions

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Warning
Hazard statements 
Precautionary statements 
RIDADR 
UN 1987C 3 / PGIII
WGK Germany 
3
RTECS 
PC4100000
Flash Point(F) 
132.8 °F
Flash Point(C) 
56 °C
Protocols & Articles
Peer-Reviewed Papers
15

References

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305294 (Trimethylsilyl)methanol, 98%

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