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95365 Sigma-Aldrich

(+)-Dimethyl L-tartrate

purum, ≥99.0% (sum of enantiomers, GC)

Synonym: L-(+)-Tartaric acid dimethyl ester

  • CAS Number 608-68-4

  • Linear Formula [-CH(OH)CO2CH3]2

  • Molecular Weight 178.14

  •  Beilstein Registry Number 1726256

  •  EC Number 210-166-8

  •  MDL number MFCD00064437

  •  PubChem Substance ID 329770449

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Properties

Related Categories Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Epoxidation,
InChI Key   PVRATXCXJDHJJN-QWWZWVQMSA-N
grade   purum
assay   ≥99.0% (sum of enantiomers, GC)
optical activity   [α]20/D +21±1°, c = 1% in H2O
bp   163 °C/23 mmHg(lit.)
mp   57-60 °C (dec.)(lit.)
  ~58 °C
density   1.238 g/mL at 25 °C(lit.)

Description

Other Notes

Chiral auxiliary used for the enantioselective epoxidation of allylic alcohols, Sharpless AE ; Asymmetric α-halogenation of acetals ; Starting material for the synthesis of chiral building blocks

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Safety & Documentation

Safety Information

RIDADR 
NONH for all modes of transport
WGK Germany 
3
Flash Point(F) 
>235.4 °F
Flash Point(C) 
>113 °C
Protocols & Articles
Peer-Reviewed Papers
15

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163457 (+)-Dimethyl L-tartrate, 99%

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