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C0125 Sigma

Cacodylic acid

≥98%

Synonym: Dimethylarsinic acid, Dimethylarsonic acid, Hydroxydimethylarsine oxide

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Related Categories Biochemicals and Reagents, Biological Buffers, Buffers A to Z More...
assay   ≥98%

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5, 10, 25, 50, 100, 250 g in glass bottle

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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
RIDADR 
UN 1572 6.1 / PGII
WGK Germany 
3
RTECS 
CH7525000

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Peer-Reviewed Papers

References

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Humans seem to produce arsenobetaine and dimethylarsinate after a bolus dose of seafood. Molin M, Ulven SM, Dahl L, et al. Environ. Res. 112, 28-39, (2012)

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Arsenic speciation in saliva of acute promyelocytic leukemia patients undergoing arsenic trioxide treatment. Chen B, Cao F, Yuan C, et al. Anal. Bioanal. Chem 405(6), 1903-11, (2013)

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Formation of methylated oxyarsenicals and thioarsenicals in wild-type and arsenic (+3 oxidation state) methyltransferase knockout mice exposed to arsenate. Naranmandura H, Rehman K, Le XC, et al. Anal. Bioanal. Chem 405(6), 1885-91, (2013)

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Silicic acid competes for dimethylarsinic acid (DMA) immobilization by the iron hydroxide plaque mineral goethite. Kersten M and Daus B Sci. Total Environ. 508, 199-205, (2015)

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Rice consumption and urinary arsenic concentrations in U.S. children. Davis MA, Mackenzie TA, Cottingham KL, et al. Environ. Health Perspect. 120(10), 1418-24, (2012)

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Methylated arsenic species in plants originate from soil microorganisms. Lomax C, Liu WJ, Wu L, et al. New Phytol. 193(3), 665-72, (2012)

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Speciation and monitoring test for inorganic arsenic in white rice flour. Narukawa T, Hioki A, and Chiba K J. Agric. Food Chem. 60(4), 1122-7, (2012)

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Possible carcinogenic potential of dimethylarsinic acid as assessed in rat in vivo models: a review. Yamamoto S, Wanibuchi H, Hori T, et al. Mutat. Res. 386(3), 353-61, (1997)

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Release of apoptotic cytochrome C from mitochondria by dimethylarsinous acid occurs through interaction with voltage-dependent anion channel in vitro. Naranmandura H, Chen X, Tanaka M, et al. Toxicol. Sci. 128(1), 137-46, (2012)

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The endoplasmic reticulum is a target organelle for trivalent dimethylarsinic acid (DMAIII)-induced cytotoxicity. Naranmandura H, Xu S, Koike S, et al. Toxicol. Appl. Pharmacol. 260(3), 241-9, (2012)

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In vitro toxicological characterisation of the S-containing arsenic metabolites thio-dimethylarsinic acid and dimethylarsinic glutathione. Leffers L, Unterberg M, Bartel M, et al. Toxicology 305, 109-19, (2013)

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A concise review of the toxicity and carcinogenicity of dimethylarsinic acid. Kenyon EM and Hughes MF Toxicology 160(1-3), 227-36, (2001)

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Renal, hepatic, pulmonary and adrenal tumors induced by prenatal inorganic arsenic followed by dimethylarsinic acid in adulthood in CD1 mice. Tokar EJ, Diwan BA, and Waalkes MP Toxicol. Lett. 209(2), 179-85, (2012)

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A novel pathway for arsenic elimination: human multidrug resistance protein 4 (MRP4/ABCC4) mediates cellular export of dimethylarsinic acid (DMAV) and the diglutathione conjugate of monomethylarsonous acid (MMAIII). Banerjee M, Carew MW, Roggenbeck BA, et al. Mol. Pharmacol. 86(2), 168-79, (2014)

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The relationship between obesity, insulin and arsenic methylation capability in Taiwan adolescents. Su CT, Lin HC, Choy CS, et al. Sci. Total Environ. 414, 152-8, (2012)

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Trivalent arsenic species induce changes in expression and levels of proinflammatory cytokines in intestinal epithelial cells. Calatayud M, Gimeno-Alcañiz JV, Vélez D, et al. Toxicol. Lett. 224(1), 40-6, (2014)

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Identification of catalytic residues in the As(III) S-adenosylmethionine methyltransferase. Marapakala K, Qin J, and Rosen BP Biochemistry 51(5), 944-51, (2012)

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In vitro study of intestinal transport of inorganic and methylated arsenic species by Caco-2/HT29-MTX cocultures. Calatayud M, Vázquez M, Devesa V, et al. Chem. Res. Toxicol. 25(12), 2654-62, (2012)

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Effect of dietary treatment with dimethylarsinous acid (DMA(III)) on the urinary bladder epithelium of arsenic (+3 oxidation state) methyltransferase (As3mt) knockout and C57BL/6 wild type female mice. Dodmane PR, Arnold LL, Pennington KL, et al. Toxicology 305, 130-5, (2013)

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Reduction of dimethylarsinic acid to the highly toxic dimethylarsinous acid by rats and rat liver cytosol. Németi B and Gregus Z Chem. Res. Toxicol. 26(3), 432-43, (2013)

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Differential toxicity and gene expression in Caco-2 cells exposed to arsenic species. Calatayud M, Devesa V, and Vélez D Toxicol. Lett. 218(1), 70-80, (2013)

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Mechanisms underlying the inhibitory effects of arsenic compounds on protein tyrosine phosphatase (PTP). Rehman K, Chen Z, Wang WW, et al. Toxicol. Appl. Pharmacol. 263(3), 273-80, (2012)

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Role of glutathione in dimethylarsinic acid-induced apoptosis. Sakurai T, Ochiai M, Kojima C, et al. Toxicol. Appl. Pharmacol. 198(3), 354-65, (2004)

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ATR-FTIR studies on the adsorption/desorption kinetics of dimethylarsinic acid on iron-(oxyhydr)oxides. Tofan-Lazar J and Al-Abadleh HA J. Phys. Chem. A 116(6), 1596-604, (2012)

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Effects of manganese and arsenic species on the level of energy related nucleotides in human cells. Bornhorst J, Ebert F, Lohren H, et al. Metallomics 4(3), 297-306, (2012)

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Kinetic ATR-FTIR studies on phosphate adsorption on iron (oxyhydr)oxides in the absence and presence of surface arsenic: molecular-level insights into the ligand exchange mechanism. Tofan-Lazar J and Al-Abadleh HA J. Phys. Chem. A 116(41), 10143-9, (2012)

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Binational arsenic exposure survey: methodology and estimated arsenic intake from drinking water and urinary arsenic concentrations. Roberge J, O'Rourke MK, Meza-Montenegro MM, et al. Int. J. Environ. Res. Public Health 9(4), 1051-67, (2012)

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Methylation capacity of arsenic and skin lesions in smelter plant workers. Wen J, Wen W, Li L, et al. Environ. Toxicol. Pharmacol. 34(2), 624-30, (2012)

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Urinary excretion of arsenic following rice consumption. Meharg AA, Williams PN, Deacon CM, et al. Environ. Pollut. 194, 181-7, (2014)

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Arsenic speciation of geothermal waters in New Zealand. Lord G, Kim N, and Ward NI J. Environ. Monit. 14(12), 3192-201, (2012)

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Effect of topical dimethylarsinic acid on the expression of apoptosis-related proteins in mouse skin. Kim E, Kim M, Sung K, et al. Bull. Environ. Contam. Toxicol. 88(5), 672-7, (2012)

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Element of Surprise? Rice as a source of arsenic in children's diets. Kessler R Environ. Health Perspect. 120(10), a402, (2012)

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Merck 14,1604

Beil. 4,IV,3681

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