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PS1051 Supelco

Glyphosate

analytical standard

Synonym: N-(Phosphonomethyl)glycine, Glyphosate

  • CAS Number 1071-83-6

  • Linear Formula (HO)2P(O)CH2NHCH2CO2H

  • Molecular Weight 169.07

  •  Beilstein Registry Number 2045054

  •  EC Number 213-997-4

  •  MDL number MFCD00055350

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Description

Testing Method

Purity determined by HPLC C18 method.

Price and Availability

QuEChERS SPE Tubes


QuEChERS SPE TubesSupelco provides a range of routine and specialty products for this popular sample prep technique used in multi-pesticide residue analysis.




Solvents for Pesticide Residue Analysis


Solvents for Pesticide Residue AnalysisFluka solvents for residue analysis of pesticides are glass-distilled and
extensively tested by GC/ECD to ensure minimum halogenated residue.




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Safety & Documentation

Safety Information

Symbol 
Signal word 
Danger
Hazard statements 
Precautionary statements 
Personal Protective Equipment 
Hazard Codes (Europe) 
Risk Statements (Europe) 
Safety Statements (Europe) 
26-39-61
RIDADR 
UN 3077 9 / PGIII
WGK Germany 
2
RTECS 
MC1075000

Documents

Certificate of Analysis

Protocols & Articles

Peer-Reviewed Papers

References

Set your institution to view full text papers.

Glyphosate resistance in Sorghum halepense and Lolium rigidum is reduced at suboptimal growing temperatures. Vila-Aiub MM, Gundel PE, Yu Q, et al. Pest Manag. Sci. 69(2), 228-32, (2013)

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Toxicological studies on the short term exposure of Clarias albopunctatus (Lamonte and Nichole 1927) to sub-lethal concentrations of roundup. Okonkwo FO, Ejike CE, Anoka AN, et al. Pak. J. Biol. Sci. 16(18), 939-44, (2013)

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Agriculture. What happens when weed killers stop killing? Service RF Science 341(6152), 1329, (2013)

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The effects of pesticides on bacterial nitrogen fixers in peanut-growing area. Angelini J, Silvina G, Taurian T, et al. Arch. Microbiol. 195(10-11), 683-92, (2013)

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[Effect of glyphosate on the energy exchange in carp organs]. Zhidenko AA, Bibchuk EV, and Barbukho EV Ukr. Biokhim. Zh. 85(3), 22-30, (2013)

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Differences between conventional and glyphosate tolerant soybeans and moisture effect in their discrimination by near infrared spectroscopy. Esteve Agelet L, Armstrong PR, Tallada JG, et al. Food Chem. 141(3), 1895-901, (2013)

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Comparative toxicity of methidathion and glyphosate on early life stages of three amphibian species: Pelophylax ridibundus, Pseudepidalea viridis, and Xenopus laevis. Güngördü A Aquat. Toxicol. 140-141, 220-8, (2013)

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Evaluation of biochemical markers in the golden mussel Limnoperna fortunei exposed to glyphosate acid in outdoor microcosms. Iummato MM, Di Fiori E, Sabatini SE, et al. Ecotoxicol. Environ. Saf. 95, 123-9, (2013)

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Effects of the glyphosate-based herbicide Roundup WeatherMax® on metamorphosis of wood frogs (Lithobates sylvaticus) in natural wetlands. Lanctôt C, Robertson C, Navarro-Martín L, et al. Aquat. Toxicol. 140-141, 48-57, (2013)

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Case studies: A hard look at GM crops. Gilbert N Nature 497(7447), 24-6, (2013)

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Toxic, cytotoxic, and genotoxic effects of a glyphosate formulation (Roundup®SL-Cosmoflux®411F) in the direct-developing frog Eleutherodactylus johnstonei. Meza-Joya FL, Ramírez-Pinilla MP, and Fuentes-Lorenzo JL Environ. Mol. Mutagen. 54(5), 362-73, (2013)

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Synergistic effects between pesticide stress and predator cues: conflicting results from life history and physiology in the damselfly Enallagma cyathigerum. Janssens L and Stoks R Aquat. Toxicol. 132-133, 92-9, (2013)

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Toxic and genotoxic effects of Roundup on tadpoles of the Indian skittering frog (Euflictis cyanophlyctis) in the presence and absence of predator stress. Yadav SS, Giri S, Singha U, et al. Aquat. Toxicol. 132-133, 1-8, (2013)

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Effects of glyphosate on cholinesterase activity of the mussel Perna perna and the fish Danio rerio and Jenynsia multidentata: in vitro studies. Sandrini JZ, Rola RC, Lopes FM, et al. Aquat. Toxicol. 130-131, 171-3, (2013)

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Glyphosate suppresses the antagonistic effect of Enterococcus spp. on Clostridium botulinum. Krüger M, Shehata AA, Schrödl W, et al. Anaerobe 20, 74-8, (2013)

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Physiological and biochemical responses of Microcystis aeruginosa to glyphosate and its Roundup® formulation. Qiu H, Geng J, Ren H, et al. J. Hazard. Mater. 248-249, 172-6, (2013)

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Effects of glyphosate-based herbicides on embryo-larval development and metamorphosis in the Pacific oyster, Crassostrea gigas. Mottier A, Kientz-Bouchart V, Serpentini A, et al. Aquat. Toxicol. 128-129, 67-78, (2013)

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Preparation and adsorption performance of MnO2/PAC composite towards aqueous glyphosate. Cui H, Li Q, Qian Y, et al. Environ. Technol. 33(16-18), 2049-56, (2012)

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Direct determination of glyphosate and its major metabolite, aminomethylphosphonic acid, in fruits and vegetables by mixed-mode hydrophilic interaction/weak anion-exchange liquid chromatography coupled with electrospray tandem mass spectrometry. Chen MX, Cao ZY, Jiang Y, et al. J. Chromatogr. A 1272, 90-9, (2013)

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Improvements in the analytical methodology for the residue determination of the herbicide glyphosate in soils by liquid chromatography coupled to mass spectrometry. Botero-Coy AM, Ibáñez M, Sancho JV, et al. J. Chromatogr. A 1292, 132-41, (2013)

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Ethoxylated adjuvants of glyphosate-based herbicides are active principles of human cell toxicity. Mesnage R, Bernay B, and Séralini GE Toxicology 313(2-3), 122-8, (2013)

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Dynamics and environmental risk assessment of the herbicide glyphosate and its metabolite AMPA in a small vineyard river of the Lake Geneva catchment. Daouk S, Copin PJ, Rossi L, et al. Environ. Toxicol. Chem. 32(9), 2035-44, (2013)

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Determination of glyphosate and AMPA in blood and urine from humans: about 13 cases of acute intoxication. Zouaoui K, Dulaurent S, Gaulier JM, et al. Forensic Sci. Int. 226(1-3), e20-5, (2013)

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Evaluation of the genotoxic and cytotoxic effects of glyphosate-based herbicides in the ten spotted live-bearer fish Cnesterodon decemmaculatus (Jenyns, 1842). Vera-Candioti J, Soloneski S, and Larramendy ML Ecotoxicol. Environ. Saf. 89, 166-73, (2013)

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Effect of intravenous lipid emulsion in patients with acute glyphosate intoxication. Gil HW, Park JS, Park SH, et al. Clin. Toxicol. (Phila.) 51(8), 767-71, (2013)

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Severe adverse effects related to dermal exposure to a glyphosate-surfactant herbicide. Mariager TP, Madsen PV, Ebbehøj NE, et al. Clin. Toxicol. (Phila.) 51(2), 111-3, (2013)

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Effects of chronic exposures to the herbicides atrazine and glyphosate to larvae of the threespine stickleback (Gasterosteus aculeatus). Le Mer C, Roy RL, Pellerin J, et al. Ecotoxicol. Environ. Saf. 89, 174-81, (2013)

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Evaluation of developmental toxicity studies of glyphosate with attention to cardiovascular development. Kimmel GL, Kimmel CA, Williams AL, et al. Crit. Rev. Toxicol. 43(2), 79-95, (2013)

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Genome-wide transcriptional responses of Escherichia coli to glyphosate, a potent inhibitor of the shikimate pathway enzyme 5-enolpyruvylshikimate-3-phosphate synthase. Lu W, Li L, Chen M, et al. Mol. Biosyst. 9(3), 522-30, (2013)

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Plurality of opinion, scientific discourse and pseudoscience: an in depth analysis of the Séralini et al. study claiming that Roundup™ Ready corn or the herbicide Roundup™ cause cancer in rats. Arjó G, Portero M, Piñol C, et al. Transgenic Res. 22(2), 255-67, (2013)

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A new bis-tetraamine ligand with a chromophoric 4-(9-anthracenyl)-2,6-dimethylpyridinyl linker for glyphosate and ATP sensing. Pouessel J, Abada S, Le Bris N, et al. Dalton Trans. 42(14), 4859-72, (2013)

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Composite hollow fiber nanofiltration membranes for recovery of glyphosate from saline wastewater. Song J, Li XM, Figoli A, et al. Water Res. 47(6), 2065-74, (2013)

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Herbicide mitigation in microcosms simulating stormwater basins subject to polluted water inputs. Bois P, Huguenot D, Jézéquel K, et al. Water Res. 47(3), 1123-35, (2013)

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Hemodialysis clearance of glyphosate following a life-threatening ingestion of glyphosate-surfactant herbicide. Garlich FM, Goldman M, Pepe J, et al. Clin. Toxicol. (Phila.) 52(1), 66-71, (2014)

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Direct liquid chromatography-tandem mass spectrometry determination of underivatized glyphosate in rice, maize and soybean. Botero-Coy AM, Ibáñez M, Sancho JV, et al. J. Chromatogr. A 1313, 157-65, (2013)

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Fast and interference-free determination of glyphosate and glufosinate residues through electrophoresis in disposable microfluidic chips. Wei X, Gao X, Zhao L, et al. J. Chromatogr. A 1281, 148-54, (2013)

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Subacute toxicity of copper and glyphosate and their interaction to earthworm (Eisenia fetida). Zhou CF, Wang YJ, Li CC, et al. Environ. Pollut. 180, 71-7, (2013)

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Use of a glyphosate-based herbicide-induced nephrotoxicity model to investigate a panel of kidney injury biomarkers. Wunnapuk K, Gobe G, Endre Z, et al. Toxicol. Lett. 225(1), 192-200, (2014)

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Comparative toxicity of two glyphosate-based formulations to Eisenia andrei under laboratory conditions. Piola L, Fuchs J, Oneto ML, et al. Chemosphere 91(4), 545-51, (2013)

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Co-biosorption of copper and glyphosate by Ulva lactuca. Trinelli MA, Areco MM, and Afonso Mdos S Colloids Surf. B Biointerfaces 105, 251-8, (2013)

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Effects of low levels of herbicides on prairie species of the Willamette Valley, Oregon. Olszyk D, Blakeley-Smith M, Pfleeger T, et al. Environ. Toxicol. Chem. 32(11), 2542-51, (2013)

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Acetylcholinesterase in honey bees (Apis mellifera) exposed to neonicotinoids, atrazine and glyphosate: laboratory and field experiments. Boily M, Sarrasin B, Deblois C, et al. Environ. Sci. Pollut. Res. Int. 20(8), 5603-14, (2013)

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Derivation of South African water quality guidelines for Roundup(®) using species sensitivity distribution. Mensah PK, Palmer CG, and Muller WJ Ecotoxicol. Environ. Saf. 96, 24-31, (2013)

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DNA damage and oxidative stress modulatory effects of glyphosate-based herbicide in freshwater fish, Channa punctatus. Nwani CD, Nagpure NS, Kumar R, et al. Environ. Toxicol. Pharmacol. 36(2), 539-47, (2013)

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Effects of sprout cutting plus systemic herbicide application on the initial growth of giant reed. Santín-Montanyá MI, Jiménez J, Ocaña L, et al. J. Environ. Sci. Health B 48(4), 285-90, (2013)

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New bacterial strain of the genus Ochrobactrum with glyphosate-degrading activity. Hadi F, Mousavi A, Noghabi KA, et al. J. Environ. Sci. Health B 48(3), 208-13, (2013)

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Effectiveness evaluation of glyphosate oxidation employing the H(2)O(2)/UVC process: toxicity assays with Vibrio fischeri and Rhinella arenarum tadpoles. Junges CM, Vidal EE, Attademo AM, et al. J. Environ. Sci. Health B 48(3), 163-70, (2013)

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Annual glyphosate treatments alter growth of unaffected bentgrass (Agrostis) weeds and plant community composition. Ahrens CW and Auer CA PLoS ONE 7(12), e50643, (2012)

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[Early continuous dialysis in acute glyphosate-surfactant poisoning]. Knežević V, Božić D, Budošan I, et al. Srp. Arh. Celok. Lek. 140(9-10), 648-52, (2012)

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Merck 14,4512

FT-IR 2 (1), 1559:C / FT-NMR 1 (1), 1480:A / RegBook 1 (1), 1103:K / Sax 6, 2212 / Structure Index 1, 170:A:7

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