134821
Aldrich

Boron trifluoride-methanol solution

50% w/w in methanol

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Molecular Formula

BF₃ · MeOH

Molecular Weight

99.85

CAS Number

373-57-9

Beilstein Registry Number

3611499

MDL number

MFCD00071635

PubChem Substance ID

24848188

EG/EC Number

206-766-4

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Descriptions

Packaging

1 L in glass btl

50, 250 mL in glass btl

Application

Reagent for the GC analysis of ritalinic acid.¹ Alternative to Cl₂CHCO₂H for synthesis of purine rich oligomers.²
Lewis acid used in the preparation of geminal bis-peroxides from ketals and enol ethers with t-butyl hydroperoxide.³ Reagent used for the mild deacetylation of amines.⁴

Properties

vapor pressure

19.5 mmHg ( 20 °C)

autoignition temp.

788 °F

concentration

50% w/w in methanol

59 °C/4 mmHg

density

1.203 g/mL at 25 °C

References

Cited Reference

1. J. Pharm. Biomed. Anal. 10, 187, (1992) abstract

2. Nucleic Acids Res. 18, 5321, (1990) abstract

3. Synthesis, 2215, (2005)

4. Tet. Lett. 44, 2301, (2003)

Beilstein

Beil. 1,IV,1220 / Beil. 1,IV,1220

Fieser

Fieser 1,73 / Fieser 9,64

reference

Aldrich MSDS 1, 220:C / Corp MSDS 1 (1), 484:A / Corp MSDS 1 (1), 484:B / Sigma FT-IR 1 (2), 1017:B / Structure Index 1, 479:A:8

Safety

Hazard Codes

T,C

Risk Statements

20/22-34-48/23

Safety Statements

23-26-36/37/39-45

RIDADR

UN 2924 3/PG 2

WGK Germany

Flash Point(F)

52 °F

Flash Point(C)

11 °C

Related Categories

... Catalysis and Inorganic Chemistry > Boron

... Lewis Acids > Boron

FT-IR Raman

MSDS

Specification Sheet

Certificate of Analysis

Certificate of Origin

More Information