211346
Aldrich

(S)-(+)-1-(9-Anthryl)-2,2,2-trifluoroethanol

≥98%

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Synonym

(S)-(+)-α-(Trifluoromethyl)anthracene-9-methanol

(S)-(+)-2,2,2-Trifluoro-1-(9-anthryl)ethanol

Molecular Formula

C₁₆H₁₁F₃O

Molecular Weight

276.25

CAS Number

60646-30-2

Beilstein Registry Number

4695162

MDL number

MFCD00062968

PubChem Substance ID

24852670

EG/EC Number

262-348-1

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Descriptions

Packaging

25, 100 mg in glass btl

Application

These enantiomerically pure (+)- and (−)-2,2,2-trifluoro-1-(9-anthryl)ethanols have been used for the NMR spectral determination of optical purity (and in some cases, absolute configuration) of a wide variety of sulfoxides,¹ lactones,^2,³ amines,⁴ sulfinate esters,⁵ oxaziridines⁶ and allenes.⁷

Properties

assay

≥98%

optical activity

[α]25/D +29°, c = 6.3 in chloroform

optical purity

ee: 98% (HPLC)

132-135 °C(lit.)

References

Cited Reference

1. J. Chromatogr. 123, 400, (1976)

2. J. Org. Chem. 42, 384, 1370, (1977)

3. J. Org. Chem. 43, 378, (1978)

4. J. Org. Chem. 42, 2436, (1977)

5. J. Am. Chem. Soc. 98, 1832, (1976)

6. J. Org. Chem. 42, 3217, (1977)

7. J. Org. Chem. 42, 3697, (1977)

reference

Aldrich MSDS 1, 1758:B / Corp MSDS 1 (2), 3443:A / FT-IR 2 (2), 1965:A / FT-IR 1 (1), 1152:A / FT-NMR 1 (2), 384:B / IR-Spectra (3), 694:C / NMR-Reference 2 (1), 954:C / RegBook 1 (1), 1341:D / Sigma FT-IR 1 (2), 947:A / Structure Index 1, 207:B:3

Safety

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36

WGK Germany