464643
Aldrich

1-Z-4-Piperidone

99%

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Synonym

1-(Benzyloxycarbonyl)-4-piperidinone

1-Cbz-4-Piperidone

Benzyl 4-oxo-1-piperidinecarboxylate

Molecular Formula

C₁₃H₁₅NO₃

Molecular Weight

233.26

CAS Number

19099-93-5

Beilstein Registry Number

1533716

MDL number

MFCD00673144

PubChem Substance ID

24870202

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Descriptions

Application

Protected piperidinone that can undergo interesting synthetic transformations including the Knoevenagel reaction,¹ hetero-Diels-Alder reactions,² and reactions to form N-(4-piperidinyl)oxindoles.³

Starting material in a synthesis of a GABA analogue by direct Barbier-like addition of an alkyl phosphinate.⁴

Packaging

5, 25 mL in glass btl

Properties

assay

99%

refractive index

n20/D 1.542(lit.)

114-140 °C/0.25 mmHg(lit.)

density

1.172 g/mL at 25 °C(lit.)

References

Cited Reference

1. J. Med. Chem. 45, 4589, (2002) abstract

2. J. Am. Chem. Soc. 124, 9662, (2002) abstract

3. Tet. Lett. 42, 6943, (2001)

4. Synthesis, 325, (2006)

Beilstein

Beil. 21,V,6,427

Safety

Safety Statements

23-24/25

WGK Germany

Flash Point(F)

235 °F

Flash Point(C)

113 °C

Related Categories

... Heterocyclic Building Blocks > Piperidones

MSDS

Specification Sheet

Certificate of Analysis

Certificate of Origin

More Information