661007
Aldrich

Hydroxy[-(S)-BINAP]-rhodium(I) Dimer

90%

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Molecular Formula

C₈₈H₆₆O₂P₄Rh₂

Molecular Weight

1485.17

MDL number

MFCD08561132

PubChem Substance ID

24884495

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Descriptions

Application

Catalyst employed in an asymmetric 1,6-addition of arylzinc reagents to dienones leading to chiral 5-substituted enones.¹ Also used in an asymmetric 1,4-addition of organoboron reagents to cyclic and acyclic α,β-unsaturated ketones with excellent enantioselectivity.²

Packaging

1 g in glass btl

Properties

assay

90%

total impurities

3-5% THF

3-5% ethanol

References

Cited Reference

1. Angew. Chem. Int. Ed. 44, 4224, (2005)

2. Chem. Rev. 103, 2829, (2003) abstract