63860
Fluka

2-Thiazoline-2-thiol

technical, ≥97.0% (T)

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Synonym

2-Mercapto-2-thiazoline

Molecular Formula

C₃H₅NS₂

Molecular Weight

119.21

CAS Number

96-53-7

Beilstein Registry Number

106332

MDL number

MFCD00126013

PubChem Substance ID

24882953

EG/EC Number

202-512-1

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Descriptions

Other Notes

Reagent for the iodomethylation of alkyl halides¹; Educt for the preparation of active derivatives of carboxylic acids; these may be reduced to the aldehydes^2,³; or aminolyzed to amides, e.g. chemoselective acylation of amino acids, e.g. selective prepn. of N_delta-Z-lysine from lysine⁴

Properties

grade

technical

assay

≥97.0% (T)

100-105 °C(lit.)

100-105 °C

References

Cited Reference

1. K. Hirai, Y. Kishida Org. Synth. 56, 77, (1976)

2. Y. Nagoa et al. J. Chem. Soc., Chem. Commun., 330, (1978)

3. T. Izawa, T. Mukaiyama Bull. Chem. Soc. Jpn. 52, 555, (1979)

4. Y. Nagao et al. J. Chem. Soc. Perkin Trans. I, 2439, (1984)

Beilstein

Beil. 27,IV,2540

Fieser

Fieser 11,518

reference

Corp MSDS 1 (2), 2214:A / FT-IR 2 (1), 1407:A / FT-IR 1 (1), 830:C / IR-Spectra (3), 493:G / IR-Spectra (2), 437:D / NMR-Reference 2 (1), 687:C / RegBook 1 (1), 975:A / Sax 6, 2577 / Structure Index 1, 152:B:2

Safety

Hazard Codes

Risk Statements

RIDADR

UN 2811 6.1/PG 3

WGK Germany

RTECS

XJ6122000

Related Categories

... Coupling > Active Esters/Additives

FT-IR Condensed Phase

FT-IR Raman

MSDS

Certificate of Analysis

More Information