90550
Fluka

Triethylsilane

purum, ≥97.0% (GC)

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Molecular Formula

(C₂H₅)₃SiH

Molecular Weight

116.28

CAS Number

617-86-7

Beilstein Registry Number

1098278

MDL number

MFCD00009018

EG/EC Number

210-535-3

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Descriptions

Other Notes

Reagent for the reduction of various functional groups (e.g. acyl halides to aldehydes, alkyl halides and secondary alcohols to hydrocarbons), review^1,^2,³; Silylating agent for alcohols, phenols, etc.^4,⁵

Properties

grade

purum

assay

≥97.0% (GC)

refractive index

n20/D 1.412(lit.)

n20/D 1.412

107-108 °C(lit.)

density

0.728 g/mL at 25 °C(lit.)

References

Cited Reference

1. Y. Nagai Org. Prep. Proc. Int. 12, 13, (1980)

2. H. Yoda et al. Tet. Asym. 4, 1451, (1993)

3. C. Brückner et al. J. Org. Chem. 53, 2450, (1988)

4. L. Horner, J. Mathias J. Organomet. Chem. 282, 155, (1985)

5. J. Heberle, G. Simchen Silylating Agents, 2nd ed. Buchs , (1995)

Beilstein

Beil. 4,IV,3895

Fieser

Fieser 1,1218 / Fieser 2,433 / Fieser 3,304 / Fieser 4,530 / Fieser 5,694 / Fieser 15,338 / Fieser 16,356 / Fieser 17,367

reference

Aldrich MSDS 1, 1755:B / Corp MSDS 1 (2), 3437:A / FT-IR 2 (3), 4338:D / FT-IR 1 (2), 1098:C / FT-NMR 1 (3), 629:C / NMR-Reference 2 (2), 983:B / RegBook 1 (2), 2951:C / Structure Index 1, 467:E:1 / Vapor Phase 3, 1622:B

Safety

Hazard Codes

Risk Statements

Safety Statements

9-16-29-33

RIDADR

UN 1993 3/PG 2

WGK Germany

Flash Point(F)

27 °F

Flash Point(C)

-3 °C