Palladium Reagents and Catalysts: New Perspectives for the 21st Century 

0-47085033-7

978-0-47085033-6

J. Tsuji, John Wiley & Sons, 2004, 670 pp., soft cover

1. The Basic Chemistry of Organopalladium Compounds.
1.1 Characteristic Features of Pd-Promoted or –Catalyzed Reactions.
1.2 Palladium Compounds, Complexes, and Ligands Widely Used in Organic Synthesis.
1.3 Fundamental Reactions of Pd Compounds.
2. Oxidative Reactions with Pd(II) Compounds.
2.1 Introduction.
2.2 Reactions of Alkenes.
2.3 Stoichiometric Reactions of p-Allyl Complexes.
2.4 Reactions of Conjugated Dienes.
2.5 Reactions of Allenes.
2.6 Reaction of Alkynes.
2.7 Homocoupling and Oxidative Substitution Reactions of Aromatic Compounds.
2.8 Regioselective Reactions Based on Chelation and Participation of Heteroatoms.
2.9 Oxidative Carbonylation of Alcohols and Amines.
2.10 Oxidation of Alcohols.
2.11 Enone Formation from Ketones and Cycloalkenylation.
3. Pd(0)-Catalyzed Reactions of sp²Organic Halides and Pseudohalides.
3.1 Introduction.
3.2 Reactions with Alkenes (Mizoroki–Heck Reaction).
3.3 Reactions of Aromatics and Heteroaromatics.
3.4 Reactions with Alkynes.
3.5 Carbonylation and Reactions of Acyl Chlorides.
3.6 Cross-Coupling Reactions with Organometallic Compounds of the Main Group Metals via Transmetallation.
3.7 Arylation and Alkenylation of C, N, O, S, and P Nucleophiles.
3.8 Miscellaneous Reactions of Aryl Halides.
4. Pd(0)-Catalyzed Reactions of Allylic Compounds via ? -Allylpalladium Complexes.
4.1 Introduction and Range of Leaving Groups.
4.2 Allylation.
4.3 Reactions with Main Group Organometallic Compounds via Transmetallation.
4.4 Carbonylation Reactions.
4.5 Intramolecular Reactions with Alkenes and Alkynes.
4.6 Hydrogenolysis of Allylic Compounds.
4.7 Allyl Group as a Protecting Group.
4.8 1,4-Elimination.
4.9 Reactions via p -Allylpalladium Enolates.
4.10 Pd(0) and Pd(II)-Catalyzed Allylic Rearrangement.
4.11 Reactions of 2,3-Alkadienyl Derivatives via Methylene-p -allylpalladiums.
5. Pd(0)-Catalyzed Reactions of 1,3-Dienes, 1,2-Dienes (Allenes), and Methylenecyclopropanes.
5.1 Reactions of Conjugated Dienes.
5.2 Reactions of Allenes.
5.3 Reactions of Methylenecyclopropanes.
6. Pd(0)-Catalyzed Reactions of Propargyl Compounds.
6.1 Introduction and Classification of Reactions.
6.2 Reactions via Insertion of Alkenes and Alkynes.
6.3 Carbonylations.
6.4 Reactions of Main Group Metal Compounds.
6.5 Reactions of Terminal Alkynes; Formation of 1,2-Alkadien-4-ynes.
6.6 Reactions of Nucleophiles on Central sp Carbon of Allenylpalladium Intermediates.
6.7 Hydrogenolysis and Elimination of Propargyl Compounds.
7. Pd(0)- and Pd(II)-Catalyzed Reactions of Alkynes and Benzynes.
7.1 Reactions of Alkynes.
7.2 Reactions of Benzynes.
8. Pd(0)-Catalyzed Reactions of Alkenes.
8.1 Carbonylation.
8.2 Hydroamination.
8.3 Hydrometallation.
8.4 Miscellaneous Reactions.
9. Pd(0)-Catalyzed Miscellaneous Reactions of Carbon Monoxide.
References.
10. Miscellaneous Reactions Catalyzed by Chiral and Achiral Pd(II) Complexes.
References.
Index.