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Formation of C—C Bonds via Catalytic Hydrogenation.

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Stoltz and coworkers have reported an elegant method for the preparation of synthetically challenging alpha-hydroxyesters and acids. The method involves alkylation of dioxanones, which are relatively difficult substrates to alkylate using classical methods because of competing ketone reduction, self-condensation, and decomposition.
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NEW Boron Reagents for Suzuki Coupling

698709			698199			698040			698156
698024				698091				699179
699845				699853				699861

NEW Esters

694363			688711			695750			695742
695777			695785			695807			695793

NEW Nitriles

697044				696358				697176
697206				697168				697192

NEW Chiral Building Blocks

672033			681709			671762			671959
670863				670987				670650
670766				698725				698733

NEW Ionic Liquids

689483			689041			688940			690473
30367			698270			689157			690597
690708				691054				690821
690937				688649				688762
691151				691267				691372

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Chiral Phase-Transfer Catalysts—Maruoka Catalysts

Symphos Ligands for Efficient Suzuki Cross-Coupling

UPDATED - Gold Catalysts: The 21st Century Gold Rush

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