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Chemistry > Chemical Synthesis > Learning Center > ChemNews > 2008 > December 2008
 
      Hot News  |  Latest ChemBlogs  |  New Literature  |   New Products  |  Product Highlights December 2008       

Welcome to ChemNews!

Our December ChemNews showcases over 40 brand NEW and innovative products for Asymmetric Synthesis and other new building blocks and reagents. In addition, we're featuring the latest literature for chemical synthesis available from Sigma-Aldrich, as well our latest product highlights — all easily accessed from one convenient location.

Make sure you subscribe to ChemNews — all ChemNews subscribers can download quarterly pdf and sdf files that contain all the new products added during the year.

Check out the categories to the right and click on the links to view the latest products in that category.

   

New Products



ChemBlogs Button

Hot News

NEW! Cheminar 4.1
The Efficient Application of Olefin Metathesis in Pharmaceuticals and Fine Chemicals
by Richard Pederson, PhD, Director Fine Chemicals R & D, Materia, Inc.

NEW!
Did You Know Challenge
We’ve extended our Did You Know? Challenge --- enter for a chance to win your choice of either a $250 voucher towards the purchase of Aldrich chemicals, books or labware, or a $250 Apple® Gift Card.  There’s a new winner each week!

Latest ChemBlogs


 First Total Synthesis of (+)-Wasabidienone B1

The first total synthesis of the fungal metabolite (+)-wasabidienone B1 was achieved in 10 steps and 5% overall yield from 1,2,3-trimethoxybenzene.  The key step was an ortho-selective hydroxylative phenol dearomatization (HPD) mediated by stabilized IBX (SIBX), which proceeded cleanly to provide 1:1 diastereomeric mixtures of the target compound and the unnatural (–)-6-epi-wasabidienone B1.
Read More...

Wasabidienone Scheme

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New Literature

Aldrichimica Acta
Aldrichimica Acta Volume 41, No. 3
Vol. 41, No. 3 Green, Mild, and Versatile Synthetic Methods
(4.47 Mb PDF)
  ChemFiles
ChemFiles Volume 8, No. 6
Vol. 8, No. 6
Asymmetric Synthesis
(2.62 Mb PDF)
  ChemFiles

Vol. 8, No. 5
Organic Building Blocks
(5.34 Mb PDF)

 

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New Products
                     

NEW Ligands for Asymmetric Epoxidation

 
 
700592 Structure

700592
700576 Structure

700576
700584 Structure

700584
 
700568 Structure

700568
700541 Structure

700541
700533 Structure

700533
 

                     

NEW Unnatural Amino Acids

 
 
670774 Structure

670774
670871 Structure

670871
690902 Structure

690902

691011 Structure

691011

 
690694 Structure

690694

690791 Structure

690791
669563 Structure

669563
 


                     

NEW Chiral Amines

 
 
670537 Structure

670537

670421 Structure

670421

671436 Structure

671436

671312 Structure

671312

 
671533 Structure

671533

671207 Structure

671207

671096 Structure

671096

 

                     

NEW Chiral Pyrrolidines

 
 
702412 Structure

702412

702498 Structure

702498

699837 Structure

699837

688622 Structure

688622

 


                     

Other NEW Chiral Ligands, Catalysts and Building Blocks

 
 
711543 Structure

711543


711497 Structure

711497


700673 Structure

700673

New BINOL ligand
 
703915 Structure

703915
703907 Structure

703907
Ts-DPEN catalysts for asymmetric hydrogenation
 

                     

NEW Phosphines

 
 
695815 Structure

695815

Phosphine ligand precursor
698555 Structure

698555

Phosphine ligand precursor
695823 Structure

695823

Phosphine ligand precursor
698261 Structure

698261


 
701289 Structure

701289

Symphos ligand for Suzuki Coupling
702951 Structure

702951

Cy-cBRIDP ligand for cross-couping
702943 Structure

702943

Cy-vBRIDP ligand for cross-coupling
 
700711 Structure

700711



701920 Structure

701920

Pincer ligand for Milstein catalyst

699535 Structure

699535

BiPhePhos ligand used in hydroamination of alkenes
 

 

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Product Spotlight

Dudley Reagents: Benzyl and p-Methoxy Benzyl Protections Using Benzyloxypyridinium Triflate and 2-(4-Methoxybenzyloxy)-4-methylquinoline
Dudley Reagents Tech Spotlight
 
BRIDP from Takasago - New Ligands for Cross-Coupling Catalysis
BRIDP Technology Spotlight
 
MIDA Boronates
MIDA Technology Spotlight
 

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