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Chemistry > Chemical Synthesis > Learning Center > ChemNews > 2009 > April 2009
 
      Hot News  |  Latest ChemBlogs  |  New Literature  |   New Products  |  Product Highlights April 2009

Welcome to ChemNews!

Our April ChemNews showcases over 40 brand NEW and innovative products for C–C and C–X Bond Formation and other new building blocks and reagents for Chemical Synthesis.  In addition, we're featuring the latest literature for chemical synthesis available from Sigma-Aldrich, as well our latest product highlights — all easily accessed from one convenient location.

Make sure you subscribe to ChemNews — all ChemNews subscribers can download quarterly pdf and sdf files that contain all the new products added during the year.

Check out the categories to the right and click on the links to view the latest products in that category.

   

New Products


ChemBlogs Button

Hot News

NEW! Cheminar 4.1
The Efficient Application of Olefin Metathesis in Pharmaceuticals and Fine Chemicals
by Richard Pederson, PhD, Director Fine Chemicals R & D, Materia, Inc.

NEW!
2009-2010 Aldrich Handbook
Reserve your copy of the NEW 2009-2010 Aldrich Handbook – complete with over 6,000 innovative new products, 10,000 chemical structures, 8,500 updated literature citations, and the companion Labware Catalog, the Handbook is an indispensable reference for any lab.

Latest ChemBlogs


 Imidazolylsulfonates as Alternatives to Triflates in Cross-Coupling Reactions

Due to limitations with cost and stability of triflates, alternative electrophilic coupling partners for cross-coupling reactions are continually being researched. I recently came across a communication in Organic Letters which details the use of imidazolylsulfonates as electrophilic coupling partners. These products show significantly improved shelf-stability versus the corresponding triflates, and better reactivity than the tosylates or mesylates. 
Read More...

Imidazolylsulfonates as Alternatives to Triflates in Cross-Coupling Reactions



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New Literature

Aldrichimica Acta
Aldrichimica Acta Volume 41, No. 4
Vol. 41, No. 4 Carbonyl Compounds: Still Central to Organic Synthesis
(3.44 Mb PDF)
  ChemFiles
ChemFiles Volume 9 No. 2
Vol. 9, No. 2
Catalysis

(4.4 Mb PDF)
  ChemFiles
ChemFiles Volume 9, No. 1
Vol. 9, No. 1
MIDA-protected Boronate Esters

(2.87 Mb PDF)

 

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New Products
                     

NEW Boron Reagents for Suzuki Coupling

 
 
706256 Structure

706256

704741 Structure

704741

706221 Structure

706221

706086 Structure

706086

 
704687 Structure

704687

706205 Structure

706205

704520 Structure

704520

704652 Structure

704652

 
706043 Structure

706043

703699 Structure

703699

706140 Structure

706140

706175 Structure

706175

 
706183 Structure

706183

706132 Structure

706132

698016 Structure

698016

 
707945 Structure

707945

706167 Structure

706167

 


                     

NEW Catalysts and Ligands for Cross-Coupling

 
 
701289 Structure

701289

702013 Structure

702013
Pincer ligand for cross-coupling

707007 Structure

707007
Catalyst for Buchwald-type cross-coupling
 
697591 Structure

697591

697605 Structure

697605

 Ligands for asymmetric alkylation

 


                     

NEW Alkenes for Heck Coupling

 
 
706744 Structure

706744
706736 Structure

706736
706728 Structure

706728

706760 Structure

706760

 
706787 Structure

706787
690961 Structure

690961
691194 Structure

691194

 

                     

Other NEW Reagents for C-C and C-X Bond Formation

 
 
690740 Structure

690740

Reagent for chlorination

706345 Structure

706345

Useful reagent for creation of heterocycles
705055 Structure

705055

Mitsunobu reagent 

 
705144 Structure

705144

Mitsunobu-type reagent for synthesis of hydroxylamines
704830 Structure

704830


704865 Structure

704865


 

 


                     

NEW Halogenated Substrates

 
 
689610 Structure

689610

706701 Structure

706701

706892 Structure

706892

 
705896 Structure

705896

690066 Structure

690066

705411 Structure

705411

 

                     

NEW Solutions of Common Reagents

Sigma-Aldrich is pleased to introduce a series of solutions designed to make common reagents easier to measure, handle, and dispense for your chemical reactions.
 
 
704083 Structure

704083

1M solution in dichloromethane
704091 Structure

704091

1M solution in cyclohexane
705284 Structure

705284

0.4M solution in dichloromethane
 
703745 Structure

703745

2M solution in ethyl acetate
703753 Structure

703753

2M solution in THF
703737 Structure

703737

2M solution in dichloromethane
 
706450 Structure

706450

0.05M solution in toluene

706442 Structure

706442

0.05M solution in toluene

689327 Structure

689327

Solution for quantitative analysis of butyllithium
 

 

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Product Spotlight

DIH – Highly efficient and economical reagent for Iodination
DIH Tech Spotlight

 

Alkali Metal Silica Gels from SiGNa
Alkali Metal Silica Gels from SiGNa: Powerful Reducing Agents

 

(S)-(–)-5-(2-Pyrrolidinyl)-1H-tetrazole – L-Proline’s Isosteric Companion in Organocatalysis

(<i>S</i>)-(—)-5-(2-Pyrrolidinyl)-1<i>H</i>-tetrazole
 

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