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Chemistry > Chemical Synthesis > Learning Center > ChemNews > 2009 > January 2009
 
      Hot News  |  Latest ChemBlogs  |  New Literature  |   New Products  |  Product Highlights January 2009

Welcome to ChemNews!

Our January ChemNews showcases over 40 brand NEW and innovative Organic Building Blocks and other new reagents for Chemical Synthesis. In addition, we're featuring the latest literature for chemical synthesis available from Sigma-Aldrich, as well our latest product highlights — all easily accessed from one convenient location.

Make sure you subscribe to ChemNews — all ChemNews subscribers can download quarterly pdf and sdf files that contain all the new products added during the year.

Check out the categories to the right and click on the links to view the latest products in that category.

   

New Products



ChemBlogs Button

Hot News

NEW! Cheminar 4.1
The Efficient Application of Olefin Metathesis in Pharmaceuticals and Fine Chemicals
by Richard Pederson, PhD, Director Fine Chemicals R & D, Materia, Inc.

NEW!
2009-2010 Aldrich Handbook
Reserve your copy of the NEW 2009-2010 Aldrich Handbook – complete with over 6,000 innovative new products, 10,000 chemical structures, 8,500 updated literature citations, and the companion Labware Catalog, the Handbook is an indispensable reference for any lab.

Latest ChemBlogs


 Ni Catalyzed Borylation and Cross-Coupling of Aryl Halides

Rosen et al. devised a new way to synthesize aryl neopentylglycolborane using [(diphenylphosphino)propane]dichloronickel as a catalyst. The resulting aryl is then cross-coupled with a variety of aryl halides using [(diphenylphosphino)etane]dichloronickel as a catalyst. This method allows for the synthesis of a variety of functional biaryls using inexpensive catalysts. It was noted that 10 mol% of the ligand, (diphenylphosphino)propane was needed to increase the yields of the borylation reaction.
Read More...

Ni Catalyzed Borylation and Cross-Coupling of Aryl Halides

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New Literature

Aldrichimica Acta
Aldrichimica Acta Volume 41, No. 3
Vol. 41, No. 3 Green, Mild, and Versatile Synthetic Methods
(4.47 Mb PDF)
  ChemFiles
Chemfiles Volume 8 Number 7
Vol. 8, No. 7
Unnatural Amino Acids

(6.65 Mb PDF)
  ChemFiles
ChemFiles Volume 8, No. 6
Vol. 8, No. 6
Asymmetric Synthesis
(2.62 Mb PDF)

 

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New Products
                     

NEW Aldehydes

 
 
681105 Structure

681105
702676 Structure

702676
702994 Structure

702994
 
702986 Structure

702986
702439 Structure

702439
694886 Structure

694886
 
687030 Structure

687030
699934 Structure

699934
703265 Structure

703265
 

                     

NEW Heterocyclic Carboxylic Acids

 
 
689416 Structure

689416
703397 Structure

703397
689300 Structure

689300

 
703834 Structure

703834

702528 Structure

702528
702536 Structure

702536
 


                     

NEW Boron Reagents for Suzuki Coupling

 
 
704407 Structure

704407

704415 Structure

704415

704997 Structure

704997

 
702919 Structure

702919

699446 Structure

699446

 

                     

NEW Pyrazoles

 
 
689750 Structure

689750

711527 Structure

711527

711500 Structure

711500

 
700118 Structure

700118

700126 Structure

700126

 


                     

Other NEW Carboxylic Acids

 
 
711659 Structure

711659

703931 Structure

703931

701041 Structure

701041

 
690899 Structure

690899
711675 Structure

711675
 

                     

NEW Esters

 
 
699675 Structure

699675

705446 Structure

705446

704482 Structure

704482

 
696404 Structure

696404

704636 Structure

704636

703818 Structure

703818

 

                     

NEW Nitriles

 
 
688991 Structure

688991

701181 Structure

701181

696447 Structure

696447

703303 Structure

703303

 

 

 

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Product Spotlight

(S)-(–)-5-(2-Pyrrolidinyl)-1H-tetrazole – L-Proline’s Isosteric Companion in Organocatalysis

(<i>S</i>)-(—)-5-(2-Pyrrolidinyl)-1<i>H</i>-tetrazole
 
Bis-Hydroxamic Acid (BHA) Ligands – New Chiral Ligands for Asymmetric Oxidation
Bis-Hydroxamic Acid (BHA) Ligands – New Chiral Ligands for Asymmetric Oxidation
 
Dudley Reagents: Benzyl and p-Methoxy Benzyl Protections Using Benzyloxypyridinium Triflate and 2-(4-Methoxybenzyloxy)-4-methylquinoline
Dudley Reagents Tech Spotlight
 

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