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Chemistry > Chemical Synthesis > Learning Center > ChemNews > 2009 > June 2009
 
      Hot News  |  Latest ChemBlogs  |  New Literature  |   New Products  |  Product Highlights June 2009

Welcome to ChemNews!

Our June ChemNews showcases over 40 brand NEW and innovative products for Catalysis and other new building blocks and reagents for Chemical Synthesis. In addition, we're featuring the latest literature for chemical synthesis available from Sigma-Aldrich, as well our latest product highlights — all easily accessed from one convenient location.

Make sure you subscribe to ChemNews — all ChemNews subscribers can download quarterly pdf and sdf files that contain all the new products added during the year.

Check out the categories to the right and click on the links to view the latest products in that category.

   

New Products



 

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Latest ChemBlogs


 Synthesis of Substituted Ureas via Cross Coupling Reactions 

Substituted ureas are of the utmost importance for the synthesis of common pharmacores. Kotecki and coworkers, from the Abbott Laboratories, developed a general method for the synthesis of subsituted ureas using palladium catalyzed amidation reaction. It is important to note that the common method to synthesize substituted ureas involve the use of phosgene.  
Read More...

Synthesis of Substituted Ureas via Cross Coupling Reactions



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New Literature

Aldrichimica Acta
Aldrichimica Acta Volume 41, No. 4
Vol. 41, No. 4 Carbonyl Compounds: Still Central to Organic Synthesis
(3.44 Mb PDF)
  ChemFiles
ChemFiles Volume 9 No. 2
Vol. 9, No. 2
Catalysis

(4.4 Mb PDF)
  ChemFiles
ChemFiles Volume 9, No. 1
Vol. 9, No. 1
MIDA-protected Boronate Esters

(2.87 Mb PDF)

 

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New Products
                     

NEW Catalysts

 
 
708526 Structure

708526

690392 Structure

690392

701777 Structure

701777

701211 Structure

701211

Ni precursor Ru precursor Rh precursor
 
700037 Structure

700037

707961 Structure

707961

707309 Structure

707988
681237 Structure

701483

Pt precursor Metathesis catalysts Complex used in stereoselective addition of carboxylic acids to phenylacetylene
 
689734 Structure

706000

689734 Structure

701203

707309 Structure

701556

681237 Structure

706353

 
Complex used in asymmetric aldol reactions Polymerization catalyst Catalyst for asymmetric transfer hydrogenation Catalyst for asymmetric reduction of imines


                     

NEW Ligands and Ligand Precursors

 
 
672181 Structure

695157
670006 Structure

695130
669881 Structure

698237
Phosphine precursors
 
672181 Structure

698474
670006 Structure

707430
669881 Structure

707694
Phosphine precursors Buchwald Ligand Air stable ligand for Pd catalyzed cross-coupling reactions
 
698652 Structure

708275

705519 Structure

700029
Ligand for ruthenium-catalyzed dehydrative direct arylation of arenes with phenols NHC ligand for conjugate asymmetric addition
 
698652 Structure

700770

705519 Structure

694223
Chiral phosphine ligand for enantioslective reduction Pincer ligand for Pd catalyzed cross-coupling reactions
 


                     

NEW Boron Reagents for Suzuki Coupling

 
 
672181 Structure

707899
670006 Structure

706108
669881 Structure

707252
 
672181 Structure

708828
669881 Structure

704547
670006 Structure

702927
 
672181 Structure

706094
670006 Structure

706531
669881 Structure

706078
 
698652 Structure

706051

705519 Structure

706213
 

                     

NEW Azides

 
 


712256

705152 Structure

690104

706655 Structure

712248

 
705969 Structure

690767
694355 Structure

670006
705950 Structure

669881
 

                     

NEW Alkynes

 
 
705977 Structure

690643
703273 Structure

707708

703273 Structure

708771

 
686719 Structure

708534

702285 Structure

711985

 

 

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Product Spotlight

α-Bromo Amides–Use in Asymmetric Nickel-Catalyzed Negishi Couplings
α-Bromo Amides–Use in Asymmetric Nickel-Catalyzed Negishi Couplings

 

DIH – Highly efficient and economical reagent for Iodination
DIH Tech Spotlight

 
Alkali Metal Silica Gels from SiGNa
Alkali Metal Silica Gels from SiGNa: Powerful Reducing Agents
 

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