The application of radical chemistry towards organic synthesis is well-developed and wide-reaching, though often hampered by a dependence on toxic radical initiators. These initiators are often used in sub- and even fully stoichiometric amounts and can require the use of short-wave light sources. Alternatively, the burgeoning field of photocatalysis has provided a number of transition-metal complexes and organocatalysts capable of initiating radical formation in the presence of visible light. The application of visible-light mediated photocatalysis has now been demonstrated in scores of noteworthy chemical transformations, and progress in the field continues unabated.

For more information, visit our Photocatalysis technology spotlight.

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ALDKIT001 Aldrich® Micro Photochemical Reactor, blue LED lights AC input 100 V / 240 V, universal plug set  
90819 Bis(2,2′-bipyridine)-(5-aminophenanthroline)ruthenium bis(hexafluorophosphate) BioReagent, suitable for fluorescence C32H25N7Ru · 2 PF6
798819 (S)-N-Butyl-1-[(S)-2-((E)-2-hydroxybenzylideneamino)-3-methylbutanoyl]pyrrolidine-2-carboxamide C21H31N3O3
388076 tert-Butyl peracetate solution 50 wt. % in odorless mineral spirits C6H12O3
L511803 Cu(dap)2 chloride AldrichCPR C52H40ClCuN4O4
747629 Cu(dap)2 chloride C52H40ClCuN4O4
658383 Dichlorotetrakis(2-(2-pyridinyl)phenyl)diiridium(III) C44H32Cl2Ir2N4
343714 Dichlorotris(1,10-phenanthroline)ruthenium(II) hydrate 98% C36H24Cl2N6Ru · xH2O
804215 [Ir{dFCF3ppy}2(bpy)]PF6 C34H18F16IrN4P
747793 (Ir[dF(CF3)ppy]2(dtbpy))PF6 C42H34F16IrN4P
747769 [Ir(dtbbpy)(ppy)2]PF6 C40H40F6IrN4P
793876 9-Mesityl-2,7-dimethyl-10-phenylacridinium tetrafluoroborate C30H28BF4N
L511811 9-Mesityl-10-methylacridinium perchlorate AldrichCPR C23H22ClNO4
747610 9-Mesityl-10-methylacridinium perchlorate 95% C23H22ClNO4
794171 9-Mesityl-10-methylacridinium tetrafluoroborate C23H22BF4N
793221 9-Mesityl-10-phenylacridinium tetrafluoroborate C28H24BF4N
108995 Methyl thioglycolate 95% C3H6O2S
L511781 [Ru(bpm)3][Cl]2 AldrichCPR C24H18Cl2N12Ru
754730 Tris(2,2′-bipyridine)ruthenium(II) hexafluorophosphate 97% C30H24F12N6P2Ru
224758 Tris(2,2′-bipyridyl)dichlororuthenium(II) hexahydrate powder C30H24Cl2N6Ru · 6H2O
688096 Tris[2-phenylpyridinato-C2,N]iridium(III) 99% C33H24IrN3