Non-Precious Metal Catalysis

A gathering of non-precious metal catalysts proficient at carrying out important synthetic transformations. In many cases, these catalysts derived from highly abundant metal sources are as effective (if not more so) than their precious metal derived brethren.

Cobalt

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60811 Cobalt carbonyl moistened with hexane (hexane 1-10%), ≥90% (Co) C8Co2O8
262676 Dichlorobis(triphenylphosphine)cobalt(II) 98% C36H30Cl2CoP2

Iron

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731382 (2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Green Alternative C24H32F12FeN6Sb2
730459 (2S,2′S-(−)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate Green Alternative C24H32F12FeN6Sb2
225487 Cyclopentadienyl iron(II) dicarbonyl dimer 99% C14H10Fe2O4
251119 Dicarbonylcyclopentadienyliodoiron(II) 97% C7H5FeIO2
225460 Diironnonacarbonyl 98% C9Fe2O9
ALD00386 Fe(dibm)3 C27H45FeO6
L512869 ((iPr)PNN)FeBr2 C19H25N2OPBr2Fe
F300 Iron(III) acetylacetonate 97% C15H21FeO6
400831 Iron(II) bromide 98% Br2Fe
217883 Iron(III) bromide 98% Br3Fe
372870 Iron(II) chloride 98% Cl2Fe
236489 Iron(III) chloride hexahydrate ACS reagent, 97% Cl3Fe · 6H2O
F2877 Iron(III) chloride hexahydrate reagent grade, ≥98%, chunks Cl3Fe · 6H2O
12322 Iron(III) chloride solution purum, 45% FeCl3 basis Cl3Fe
710857 Iron(III) chloride solution 0.2 M in 2-methyltetrahydrofuran Green Alternative Cl3Fe
216828 Iron(III) nitrate nonahydrate ACS reagent, ≥98% FeN3O9 · 9H2O
F3002 Iron(III) nitrate nonahydrate ≥98% FeN3O9 · 9H2O
481718 Iron(0) pentacarbonyl >99.99% trace metals basis C5FeO5
195731 Iron(0) pentacarbonyl C5FeO5
737968 Iron(III) trifluoroacetylacetonate 99.5% trace metals basis C15H12F9FeO6
698172 Iron(II) trifluoromethanesulfonate ≥85% C2F6FeO6S2
708801 Iron(III) trifluoromethanesulfonate 90% C3F9FeO9S3
RNI00086 Ritter 2,6-diisopropyl iminopyridine ferrous chloride C18H22Cl2N2Fe
RNI00087 Ritter Iminopyridine Ferrous Chloride Polymerization Catalyst C30H22Cl2FeN2
RNI00089 Ritter Iminopyridine Iron Polymerization Catalyst C14H22Cl2FeN2
L512850 (tBu)PNN(iPr)FeCl2 C27H42N2OPCl2Fe
381411 Triirondodecacarbonyl contains 1-10% methyl alcohol C12Fe3O12

Manganese

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245267 Manganese(0) carbonyl 98% C10Mn2O10
700223 Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III) 97% C33H57MnO6

Nickel

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244988 Bis(1,5-cyclooctadiene)nickel(0) C16H24Ni
328219 [1,2-Bis(diphenylphosphino)ethane]dichloronickel(II) C26H24Cl2NiP2
470554 [1,1′-Bis(diphenylphosphino)ferrocene]dichloronickel(II) 97% C34H28Cl2FeNiP2
708526 Bis(tricyclohexylphosphine)nickel(II) dichloride 97% C36H66Cl2NiP2
213934 Bis(triphenylphosphine)dicarbonylnickel C38H30NiO2P2
331708 Dibromobis(triphenylphosphine)nickel(II) 99% C36H30Br2NiP2
L511706 [(dppf)Ni(cinnamyl)Cl] AldrichCPR C43H37ClFeNiP2
L511714 [(dppf)Ni(cinnamyl)]ZnCl3 AldrichCPR C43H37Cl3FeNiP2Zn
776254 Nickel(II) bis(trifluoromethanesulfonimide) hydrate 95% C4F12N2NiO8S4 · xH2O
406341 Nickel(II) bromide ethylene glycol dimethyl ether complex 97% C4H10Br2NiO2
339350 Nickel(II) chloride 98% Cl2Ni
31462 Nickel(II) chloride hexahydrate puriss. p.a., ≥98% Cl2Ni · 6H2O
696668 Nickel(II) chloride ethylene glycol dimethyl ether complex 98% C4H10O2 · Cl2Ni
339709 Nickel(II) hexafluoroacetylacetonate hydrate 98% C10H2F12NiO4 · xH2O
244996 Tetrakis(triphenylphosphine)nickel(0) Ni 4-7 % (approx.) C72H60NiP4
804398 [(TMEDA)Ni(o-tolyl)Cl] C13H23ClN2Ni

Titanium

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L511749 Schafer′s Ti-Amidate Catalyst AldrichCPR C23H34N3OTi