Amidates/Imidates

Amidates and imidates are compounds containing a carbon-nitrogen double bond, with the nitrogen atom attached either to a hydrogen atom or an organic group, and the carbon atom having two additional single bonds. Amidate derivatives are used as intermediates and reagents in a variety of synthetic procedures, such as chiral ligands in asymmetrical Michael additions, aminations, amidine conjugations, intermolecular cyclizations, Mo-catalyzed asymmetric ring-closing metathesis, protective reagent of an alcohol as its allyl ether, the preparation of tert-butyl esters and ethers, the conversion of alcohols and carboxylic acids to their respective ethers and esters, and used as reagents for the modification of proteins via amidination.

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139661 Methyl 2,2,2-trichloroacetimidate 98% C3H4Cl3NO
717444 Methyl 2-chloroacetimidate hydrochloride C3H7Cl2NO
396788 Ethyl formimidate hydrochloride C3H7NO · HCl
254940 Methyl acetimidate hydrochloride technical grade C3H7NO · HCl
273384 Ethyl 2,2,2-trichloroacetimidate 98% C4H6Cl3NO
188840 Ethyl acetimidate hydrochloride 97% C4H9NO · HCl
346241 Isopropyl formimidate hydrochloride technical grade C4H9NO · HCl
678414 O-Allyl 2,2,2-trichloroacetimidate 96% C5H6Cl3NO
91077 tert-Butyl 2,2,2-trichloroacetimidate purum, ≥97.0% (GC) C6H10Cl3NO
364789 tert-Butyl 2,2,2-trichloroacetimidate 96% C6H10Cl3NO
67877 Ethyl butyrimidate hydrochloride ≥97.0% (AT) C6H13NO · HCl
406554 Diethyl malonimidate dihydrochloride C7H14N2O2 · 2HCl
220515 Methyl benzimidate hydrochloride 97% C8H9NO · HCl
285625 Dimethyl adipimidate dihydrochloride 97% C8H16N2O2 · 2HCl
140333 Benzyl 2,2,2-trichloroacetimidate 99% C9H8Cl3NO
12268 Ethyl benzimidate hydrochloride ≥97.0% (AT) C9H11NO · HCl
762008 Ethyl N-phenylformimidate 97% C9H11NO
324469 Ethyl 4-hydroxybenzimidate hydrochloride 96% C9H11NO2 · HCl
637114 Benzyl thioacetimidate hydrochloride 96% C9H11NS · HCl
268747 Ethyl N-(2,4-dinitrophenoxy)acetimidate 99% C10H11N3O6
179523 Dimethyl suberimidate dihydrochloride 98% C10H20N2O2 · 2HCl
74835 Dimethyl suberimidate dihydrochloride ≥98.0% (AT) C10H20N2O2 · 2HCl
278971 Diphenyl N-cyanocarbonimidate 97% C14H10N2O2