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Organotin

Organotin compounds have classically been one of the more utilized synthons in palladium-catalyzed cross coupling reactions. Since the first report by Stille in 1977, numerous applications of organotin reagents have found to be commonplace in the formation of new C-C bonds in the synthesis of natural products and other small molecules for drug discovery. Sigma-Aldrich also offers an extensive portfolio of organoditin and organotin hydride reagents for the generation of Stille Coupling precursors to obtain more complex coupling partners and dehalogenation reactions to afford hydrocarbons in late-stage synthetic sequences.

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Heterocyclic Organotin Reagents for Stille Coupling

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Description

Molecular Formula

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CDS001577 Tin(II) pyrophosphate AldrichCPR Organotins
O7P2Sn2
288039 Methyltin trichloride 97% Organotin Halides
CH3Cl3Sn
288012 Dimethyltin dichloride 97% Organotin Halides
C2H6Cl2Sn
748382 Dimethyltin oxide Organotin Oxides
C2H6OSn
257915 Trimethyltin bromide 95% Organotin Halides
C3H9BrSn
146498 Trimethyltin chloride Organotin Halides
C3H9ClSn
375187 Trimethyltin chloride solution 1.0 M in hexanes Organotin Halides
C3H9ClSn
375195 Trimethyltin chloride solution 1.0 M in THF Organotin Halides
C3H9ClSn
349488 Azidotrimethyltin(IV) 97% Organotins
C3H11N3Sn
201057 Butyltin trichloride 95% Organotin Halides
C4H9Cl3Sn
344931 Butyltin hydroxide oxide hydrate 97% Organotin Oxides
C4H10O2Sn · xH2O
344923 Butyltin chloride dihydroxide 96% Organotin Halides
C4H11ClO2Sn
481394 Tetramethyltin 95% Green Alternative Organotins
C4H12Sn
429287 (Dimethylamino)trimethyltin(IV) technical grade Organotins
C5H15NSn
277231 Phenyltin trichloride 98% Organotin Halides
C6H5Cl3Sn
288047 Triethyltin bromide 97% Organotin Halides
C6H15BrSn
288020 Hexamethylditin 99% Organoditins
C6H18Sn2
328669 Tetravinyltin 97% Organotins
C8H12Sn
278009 Di-tert-butyltin dichloride 98% Organotin Halides
C8H18Cl2Sn
205494 Dibutyltin dichloride 96% Organotin Halides
C8H18Cl2Sn
34980 Dibutyltin(IV) oxide purum Organotin Oxides
C8H18OSn
183083 Dibutyltin(IV) oxide 98% Organotin Oxides
C8H18OSn
483613 Bis(trimethylstannyl)acetylene Organotins
C8H18Sn2
229229 Tetraethyltin 97% Organotins
C8H20Sn
366331 Trimethyl(phenyl)tin 98% Organotins
C9H14Sn
725374 2,2-Dibutyl-[1,3,2]dioxastannolane 96% Organotin Oxides
C10H22O2Sn
D49806 Dibutyldimethoxytin Organotins
C10H24O2Sn
34684 Dibutyldimethoxytin technical, ≥90% Sn basis Organotins
C10H24O2Sn
429953 Trimethyl(phenylethynyl)tin 97% Organotins
C11H14Sn
229202 Diphenyltin dichloride 96% Organotin Halides
C12H10Cl2Sn
479462 Diphenyltin(IV) oxide 97% Organotin Oxides
C12H10OSn
440477 Dibutyltin maleate 95% Organotins
C12H20O4Sn
271446 Tetraallyltin 97% Organotins
C12H20Sn
290890 Dibutyltin diacetate technical grade Organotins
C12H24O4Sn
257893 Tributyltin bromide technical grade, 90% Organotin Halides
C12H27BrSn
T50202 Tributyltin chloride 96% Organotin Halides
C12H27ClSn
615633 Tributyltin chloride-d27 98 atom % D, 96% (CP) Organotin Halides
C12D27ClSn
333034 Tributyltin iodide technical grade, 90% Organotin Halides
C12H27ISn
349453 Azidotributyltin(IV) 98% Organotins
C12H27N3Sn
234788 Tributyltin hydride contains 0.05% BHT as stabilizer, 97% Organotins
C12H28Sn
366420 Tributylstannyl trifluoromethanesulfonate 90% Organotins
C13H27F3O3SSn
530786 Tributyltin isocyanate Organotins
C13H27NOSn
235164 Tributyltin cyanide 97% Organotins
C13H27NSn
229245 Tributyltin methoxide 97% Organotins
C13H30OSn
711063 Tributyl(perfluoroethyl)stannane 97% Organotins
C14H27F5Sn
275069 Ethynyltributylstannane 95% Organotins
C14H28Sn
95085 Tributyl(vinyl)stannane purum, ≥97.0% (GC) Organotins
C14H30Sn
271438 Tributyl(vinyl)tin 97% Organotins
C14H30Sn
251518 Tributyltin ethoxide 97% Organotins
C14H32OSn
SYX00076 1-Tributylstannyl-3,3,3-trifluoro-1-propyne AldrichCPR Organotins
C15H27F3Sn
706965 4-Bromo-2-(tributylstannyl)thiazole Organotins
C15H28BrNSSn
728896 2-Chloro-5-(tributylstannyl)thiazole 96% Organotins
C15H28ClNSSn
638617 2-(Tri-n-butylstannyl)oxazole Organotins
C15H29NOSn
642541 2-Tributylstannylthiazole 97% Organotins
C15H29NSSn
499854 Allenyltributyltin(IV) technical grade, 80% Organotins
C15H30Sn
499862 Tributyl(1-propynyl)tin 95% Organotins
C15H30Sn
SYX00013 2-(Tributylstannyl)propene AldrichCPR Organotins
C15H32Sn
271411 Allyltributylstannane 97% Organotins
C15H32Sn
SYX00050 Tributyl[(methoxymethoxy)methyl]stannane AldrichCPR Organotins
C15H34O2Sn
92781 Tributyl(trimethylsilyl)stannane purum, ≥97.0% (GC) Organotins
C15H36SiSn
367265 Trimethyl(tributylstannyl)silane 97% Organotins
C15H36SiSn
718807 2,6-Dichloro-3-(tributylstannyl)pyrazine 97% Organotins
C16H28Cl2N2Sn
706868 2-Chloro-5-(tributylstannyl)pyrimidine 95% Organotins
C16H29ClN2Sn
675660 2-(Tributylstannyl)pyrazine 95% Organotins
C16H30N2Sn
721174 2-(Tributylstannyl)pyrimidine 95% Organotins
C16H30N2Sn
719730 5-(Tributylstannyl)pyrimidine 95% Organotins
C16H30N2Sn
414506 2-(Tributylstannyl)furan 97% Organotins
C16H30OSn
414492 2-(Tributylstannyl)thiophene 97% Organotins
C16H30SSn
707813 1-Methyl-4-(tributylstannyl)-1H-pyrazole 97% Organotins
C16H32N2Sn
739499 1-Methyl-5-(tributylstannyl)-1H-pyrazole 97% Organotins
C16H32N2Sn
718793 1-Methyl-5-(tributylstannyl)imidazole 95% Organotins
C16H32N2Sn
719501 N-Methyl-4-(tributylstannyl)imidazole 95% Organotins
C16H32N2Sn
734055 Tributyl(4,5-dihydrofuran-2-yl)stannane 97% Organotins
C16H32OSn
707937 cis-Tributyl[2-ethoxyethenyl]stannane 97% Organotins
C16H34OSn
275123 Tributyl(1-ethoxyvinyl)tin 97% Organotins
C16H34OSn
331090 Bis(dibutylchlorotin(IV)) oxide 98% Organotin Halides
C16H36Cl2OSn2
T6008 Tetrabutyltin technical grade, 93% Organotins
C16H36Sn
739480 2,3-Difluoro-4-(tributylstannyl)pyridine 95% Organotins
C17H29F2NSn
704849 2-Bromo-5-(tributylstannyl)pyridine 97% (H-NMR) Organotins
C17H30BrNSn
704865 2-Bromo-6-(tributylstannyl)pyridine 97% (H-NMR) Organotins
C17H30BrNSn
704830 5-Bromo-2-(tributylstannyl)pyridine 97% (H-NMR) Organotins
C17H30BrNSn
719609 2-Chloro-6-(tributylstannyl)pyridine Organotins
C17H30ClNSn
696692 2-Fluoro-3-(tributylstannyl)pyridine 97% Organotins
C17H30FNSn
719315 2-Fluoro-4-(tributylstannyl)pyridine Organotins
C17H30FNSn
678333 2-(Tributylstannyl)pyridine 85% Organotins
C17H31NSn
698598 3-(Tributylstannyl)pyridine 97% Organotins
C17H31NSn
731684 2-(Tributylstannyl)-3-methoxypyrazine 97% Organotins
C17H32N2OSn
707031 6-Methoxy-2-(tributylstannyl)pyrimidine 95% Organotins
C17H32N2OSn
723355 2-Methylthio-5-(tributylstannyl)pyrimidine 95% Organotins
C17H32N2SSn
675679 1-Methyl-2-(tributylstannyl)pyrrole 95% Organotins
C17H33NSn
734063 Tributyl(5,6-dihydro-4H-pyran-2-yl)stannane Organotins
C17H34OSn
499846 Tributyl(3-methyl-2-butenyl)tin 90% Organotins
C17H36Sn
615625 Triphenyl-d15-tin chloride ≥98 atom % D Organotin Halides
C18D15ClSn
348104 Triphenyltin hydroxide Organotins
C18H16OSn
244775 Triphenyltin hydride Organotins
C18H16Sn
721158 Tributyl(4-chloro)phenylstannane 95% Organotins
C18H31ClSn
520586 Dibutyltin bis(acetylacetonate) 95% Organotins
C18H32O4Sn
79226 Tributylphenylstannane purum, ≥97.0% (GC) Organotins
C18H32Sn
374601 Tributylphenylstannane 97% Organotins
C18H32Sn
480827 Tricyclohexyltin chloride 97% Organotin Halides
C18H33ClSn
721115 2-methoxy-6-(tributylstannyl)pyridine 96% Organotins
C18H33NOSn
706981 Ethyl-5-(tributylstannyl)isoxazole-3-carboxylate Organotins
C18H33NO3Sn
721220 2-Methyl-6-(tributylstannyl)pyridine Organotins
C18H33NSn
739782 5-Methyl-2-(tributylstannyl)pyridine 95% Organotins
C18H33NSn
SYX00093 Tributyl[2,2-difluoro-1-(2-methoxyethoxymethoxy)vinyl]stannane AldrichCPR Organotins
C18H36F2O3Sn
773654 1,3,5-Trimethyl-4-(tributylstannyl)-1H-pyrazole 97% Organotins
C18H36N2Sn
277657 Bis[(trimethylsilyl)tributyl]stannyl phosphate 97% Organotins
C18H45O4PSi2Sn
721166 2-(Tributylstannyl)benzo[d]thiazole 95% Organotins
C19H31NSSn
530158 Dibutyldiphenyltin 97% Organotins
C20H28Sn
683930 2-Tributylstannylbenzo[b]thiophene 95% Organotins
C20H32SSn
340359 Tributyl(phenylethynyl)tin 95% Organotins
C20H32Sn
729256 2-(N-Boc-amino)-5-(tributylstannyl)thiazole Organotins
C20H38N2O2SSn
176214 1,3-Diacetoxy-1,1,3,3-tetrabutyldistannoxane 97% Organotin Oxides
C20H42O5Sn2
332364 Allyltriphenylstannane 97% Organotins
C21H20Sn
719366 N-Methyl-2-(tributylstannyl)indole 97% Organotins
C21H35NSn
721212 4-(4-(Tributylstannyl)phenyl)morpholine Organoditins
Organotins
C22H39NOSn
T26727 Tetraphenyltin 97% Organotins
C24H20Sn
B53383 Bis(tributyltin) oxide 96% Organotin Oxides
C24H54OSn2
720585 Bis(tributyltin)sulfide 97% Organotins
C24H54SSn2
251127 Bis(tributyltin) 95% Organoditins
C24H54Sn2
721131 (4-Benzyloxyphenyl)tributylstannane Organotins
C25H38OSn
271403 Bis(tributylstannyl)acetylene 95% Organotins
C26H54Sn2
731625 trans-1,2-Bis(tributylstannyl)ethene 97% Organotins
C26H56Sn2
717703 2,5-Bis(tributylstannyl)thiophene 97% Organotins
C28H56SSn2
721190 1,3-Bis(tributylstannyl)benzene Organotins
C30H58Sn2
721204 1,4-Bis(tributylstannyl)benzene Organotins
C30H58Sn2
717614 5,5′-Bis(tributylstannyl)-2,2′-bithiophene 97% Organotins
C32H58S2Sn2
291234 Dibutyltin dilaurate 95% Organotins
C32H64O4Sn
595322 Hexaphenylditin(IV) 97% Organoditins
C36H30Sn2