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Organozinc Halides

Organozinc halides are important reagents in modern organic synthesis. Organozinc halides possess advantageous chemoselectivity and high functional group tolerance. As organozinc compounds readily undergo transmetalation reactions, they are also ideally suited as reagents for cross-coupling reactions. Indeed, the Negishi cross-coupling reaction constitutes one of the most important and versatile methods in contemporary organic synthesis. The total synthesis of resveratrol was recently accomplished with organozinc halides.

Learn More about Organozinc Halides
Pd-Catalyzed Cross-Coupling Reactions
Palladium-Catalyzed Alkenylation by the Negishi Coupling
TPGS–750–M: Second Generation Amphiphile for Organometallic Chemistry in Water at Room Temperature
"Designer" - Surfactant-Enabled Cross-Couplings in Water at Room Temperature
alpha-Bromo Amides–Use in Asymmetric Nickel-Catalyzed Negishi Couplings
Suzuki-Miyaura Coupling and a-Arylation
Q-Phos
PEPPSI Catalyst
Pd-N-Heterocyclic Carbene (NHC) Catalysts for Cross-Coupling Reactions

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Molecular Formula

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417297 Methylzinc chloride solution 2.0 M in THF Alkyl
CH3ClZn
499404 2-Thiazolylzinc bromide solution 0.5 M in THF Heteroaryl
C3H2BrNSZn
497908 2-Cyanoethylzinc bromide solution 0.5 M in THF Alkyl
C3H4BrNZn
680982 Cyclopropylzinc bromide solution 0.5 M in THF Alkyl
C3H5BrZn
680966 2-Propylzinc bromide solution 0.5 M in THF Alkyl
C3H7BrZn
499374 Propylzinc bromide solution 0.5 M in THF Alkyl
C3H7BrZn
497843 5-Chloro-2-thienylzinc bromide solution 0.5 M in THF Heteroaryl
C4H2BrClSZn
499412 2-Thienylzinc bromide solution 0.5 M in THF Heteroaryl
C4H3BrSZn
561622 3-Thienylzinc iodide solution 0.5 M in THF Heteroaryl
C4H3ISZn
497967 3-Cyanopropylzinc bromide solution 0.5 M in THF Alkyl
C4H6BrNZn
710326 (1,3-Dioxolan-2-ylmethyl)zinc bromide 0.6 M in THF Alkyl
C4H7BrO2Zn
710318 Cyclobutylzinc bromide 0.5 M in THF Alkyl
C4H7BrZn
497770 4-Chlorobutylzinc bromide solution 0.5 M in THF Alkyl
C4H8BrClZn
497746 Butylzinc bromide solution 0.5 M in THF Alkyl
C4H9BrZn
498963 Isobutylzinc bromide solution 0.5 M in THF Alkyl
C4H9BrZn
497738 sec-Butylzinc bromide solution 0.5 M in THF Alkyl
C4H9BrZn
497754 tert-Butylzinc bromide solution 0.5 M in THF Alkyl
C4H9BrZn
499382 2-Pyridylzinc bromide solution 0.5 M in THF Heteroaryl
C5H4BrNZn
525111 3-Methyl-2-thienylzinc bromide solution 0.5 M in THF Heteroaryl
C5H5BrSZn
710237 5-Methyl-2-thienylzinc bromide solution 0.5 M in THF Heteroaryl
C5H5BrSZn
497894 4-Cyanobutylzinc bromide solution 0.5 M in THF Alkyl
C5H8BrNZn
499498 (R)-(+)-3-Methoxy-2-methyl-3-oxopropylzinc bromide solution 0.5 M in THF Alkyl
C5H9BrO2Zn
498815 (S)-(−)-3-Methoxy-2-methyl-3-oxopropylzinc bromide solution 0.5 M in THF Alkyl
C5H9BrO2Zn
533688 2-(1,3-Dioxolan-2-yl)]ethyl]zinc bromide solution 0.5 M in THF Alkyl
C5H9BrO2Zn
498521 3-Ethoxy-3-oxopropylzinc bromide solution 0.5 M in THF Alkyl
C5H9BrO2Zn
499072 4-Pentenylzinc bromide solution 0.5 M in THF Alkyl
C5H9BrZn
498041 Cyclopentylzinc bromide solution 0.5 M in THF Alkyl
C5H9BrZn
497819 5-Chloropentylzinc bromide solution 0.5 M in THF Alkyl
C5H10BrClZn
498904 1,1-Dimethylpropylzinc bromide solution 0.5 M in THF Alkyl
C5H11BrZn
499277 1-Ethylpropylzinc bromide solution 0.5 M in THF Alkyl
C5H11BrZn
499269 1-Methylbutylzinc bromide solution 0.5 M in THF Alkyl
C5H11BrZn
498890 3-Methylbutylzinc bromide solution 0.5 M in THF Alkyl
C5H11BrZn
499285 Pentylzinc bromide solution 0.5 M in THF Alkyl
C5H11BrZn
535249 4-Bromo-2-fluorophenylzinc iodide solution 0.5 M in THF Aryl
C6H3BrFIZn
497630 4-Bromo-3-fluorophenylzinc iodide solution 0.5 M in THF Aryl
C6H3BrFIZn
710261 2,6-Difluorophenylzinc bromide solution 0.5 M in THF Aryl
C6H3BrF2Zn
497789 3-Chloro-4-fluorophenylzinc iodide solution 0.5 M in THF Aryl
C6H3ClFIZn
535214 2,3-Dichlorophenylzinc iodide solution 0.5 M in THF Aryl
C6H3Cl2IZn
535230 2,5-Dichlorophenylzinc iodide solution 0.5 M in THF Aryl
C6H3Cl2IZn
498068 3,4-Dichlorophenylzinc iodide solution 0.5 M in THF Aryl
C6H3Cl2IZn
498076 3,5-Dichlorophenylzinc iodide solution 0.5 M in THF Aryl
C6H3Cl2IZn
498645 4-Fluorophenylzinc bromide solution 0.5 M in THF Aryl
C6H4BrFZn
497649 3-Bromophenylzinc iodide solution 0.5 M in THF Aryl
C6H4BrIZn
497657 4-Bromophenylzinc iodide solution 0.5 M in THF Aryl
C6H4BrIZn
499803 2-Chlorophenylzinc iodide solution 0.5 M in THF Aryl
C6H4ClIZn
497835 4-Chlorophenylzinc iodide solution 0.5 M in THF Aryl
C6H4ClIZn
533513 2-Fluorophenylzinc iodide solution 0.5 M in THF Aryl
C6H4FIZn
520489 3-Fluorophenylzinc iodide solution 0.5 M in THF Aryl
C6H4FIZn
524719 Phenylzinc bromide solution 0.5 M in THF Aryl
C6H5BrZn
533475 (2-Chloro-5-pyridyl)methylzinc chloride solution 0.5 M in THF Heteroaryl
C6H5Cl2NZn
499331 Phenylzinc iodide solution 0.5 M in THF Aryl
C6H5IZn
533718 6-Methoxy-2-pyridylzinc bromide solution 0.5 M in THF Heteroaryl
C6H6BrNOZn
498971 3-Methyl-2-pyridylzinc bromide solution 0.5 M in THF Heteroaryl
C6H6BrNZn
498998 4-Methyl-2-pyridylzinc bromide solution 0.5 M in THF Heteroaryl
C6H6BrNZn
499005 5-Methyl-2-pyridylzinc bromide solution 0.5 M in THF Heteroaryl
C6H6BrNZn
499013 6-Methyl-2-pyridylzinc bromide solution 0.5 M in THF Heteroaryl
C6H6BrNZn
533556 2-(1,3-Dioxan-2-yl)ethylzinc bromide solution 0.5 M in THF Alkyl
C6H11BrO2Zn
630403 4-Acetoxybutylzinc bromide 0.5 M in THF Alkyl
C6H11BrO2Zn
498491 4-Ethoxy-4-oxobutylzinc bromide solution 0.5 M in THF Alkyl
C6H11BrO2Zn
498734 5-Hexenylzinc bromide solution 0.5 M in THF Alkyl
C6H11BrZn
498033 Cyclohexylzinc bromide solution 0.5 M in THF Alkyl
C6H11BrZn
498750 1-Ethylbutylzinc bromide solution 0.5 M in THF Alkyl
C6H13BrZn
498548 2-Ethylbutylzinc bromide solution 0.5 M in THF Alkyl
C6H13BrZn
498769 Hexylzinc bromide solution 0.5 M in THF Alkyl
C6H13BrZn
541273 2,3,4,5,6-Pentafluorobenzylzinc bromide solution 0.5 M in THF Alkyl
C7H2BrF5Zn
499064 2,3,4,5,6-Pentafluorobenzylzinc chloride solution 0.5 M in THF Alkyl
C7H2ClF5Zn
520233 2-Cyanophenylzinc bromide solution 0.5 M in THF Aryl
C7H4BrNZn
520292 4-Cyanophenylzinc bromide solution 0.5 M in THF Aryl
C7H4BrNZn
497940 3-Cyanophenylzinc iodide solution 0.5 M in THF Aryl
C7H4INZn
520306 2,4-Difluorobenzylzinc bromide solution 0.5 M in THF Alkyl
C7H5BrF2Zn
521663 2,5-Difluorobenzylzinc bromide solution 0.5 M in THF Alkyl
C7H5BrF2Zn
521671 2,6-Difluorobenzylzinc bromide solution 0.5 M in THF Alkyl
C7H5BrF2Zn
521698 3,4-Difluorobenzylzinc bromide solution 0.5 M in THF Alkyl
C7H5BrF2Zn
499471 3,5-Difluorobenzylzinc bromide solution 0.5 M in THF Alkyl
C7H5BrF2Zn
498092 2,5-Difluorobenzylzinc chloride solution 0.5 M in THF Alkyl
C7H5ClF2Zn
498440 3,5-Difluorobenzylzinc chloride solution 0.5 M in THF Alkyl
C7H5ClF2Zn
535257 2-Chloro-6-fluorobenzylzinc chloride solution 0.5 M in THF Alkyl
C7H5Cl2FZn
533351 2,6-Dichlorobenzylzinc chloride solution 0.5 M in THF Alkyl
C7H5Cl3Zn
497541 4-Bromobenzylzinc chloride solution 0.5 M in THF Alkyl
C7H6BrClZn
635650 2-Iodobenzylzinc bromide solution 0.5 M in THF Alkyl
C7H6BrIZn
533297 3-Iodobenzylzinc bromide solution 0.5 M in THF Alkyl
C7H6BrIZn
533289 4-Iodobenzylzinc bromide solution 0.5 M in THF Alkyl
C7H6BrIZn
520314 2-Bromobenzylzinc bromide solution 0.5 M in THF Alkyl
C7H6Br2Zn
499463 4-Bromobenzylzinc bromide solution 0.5 M in THF Alkyl
C7H6Br2Zn
498580 2-Fluorobenzylzinc chloride solution 0.5 M in THF Alkyl
C7H6ClFZn
498599 3-Fluorobenzylzinc chloride solution 0.5 M in THF Alkyl
C7H6ClFZn
498602 4-Fluorobenzylzinc chloride solution 0.5 M in THF Alkyl
C7H6ClFZn
497800 3-Chloro-4-methylphenylzinc iodide solution 0.5 M in THF Aryl
C7H6ClIZn
497568 2-Chlorobenzylzinc chloride solution 0.5 M in THF Alkyl
C7H6Cl2Zn
497576 3-Chlorobenzylzinc chloride solution 0.5 M in THF Alkyl
C7H6Cl2Zn
497762 4-Chlorobenzylzinc chloride solution 0.5 M in THF Alkyl
C7H6Cl2Zn
498610 3-Fluoro-4-methylphenylzinc iodide solution 0.5 M in THF Aryl
C7H6FIZn
498629 5-Fluoro-2-methylphenylzinc iodide solution 0.5 M in THF Aryl
C7H6FIZn
533696 5-(1,3-Dioxolan-2-yl)-2-thienylzinc bromide solution 0.5 M in THF Heteroaryl
C7H7BrO2SZn
533548 5-Ethoxycarbonyl-2-thienylzinc bromide solution 0.5 M in THF Heteroaryl
C7H7BrO2SZn
641812 5-Ethoxycarbonyl-2-furylzinc bromide solution 0.5 M in THF Heteroaryl
C7H7BrO3Zn
497517 Benzylzinc bromide solution 0.5 M in THF Alkyl
C7H7BrZn
498823 2-Methoxyphenylzinc iodide solution 0.5 M in THF Aryl
C7H7IOZn
498831 3-Methoxyphenylzinc iodide solution 0.5 M in THF Aryl
C7H7IOZn
498858 4-Methoxyphenylzinc iodide solution 0.5 M in THF Aryl
C7H7IOZn
499420 2-(Methylthio)phenylzinc iodide solution 0.5 M in THF Aryl
C7H7ISZn
498947 3-Methylphenylzinc iodide solution 0.5 M in THF Aryl
C7H7IZn
498955 4-Methylphenylzinc iodide solution 0.5 M in THF Aryl
C7H7IZn
499056 exo-2-Norbornylzinc bromide solution 0.5 M in THF Alkyl
C7H11BrZn
497924 6-Cyanohexylzinc bromide solution 0.5 M in THF Alkyl
C7H12BrNZn
630381 5-Acetoxypentylzinc bromide 0.5 M in THF Alkyl
C7H13BrO2Zn
498513 5-Ethoxy-5-oxopentylzinc bromide solution 0.5 M in THF Alkyl
C7H13BrO2Zn
498025 (Cyclohexylmethyl)zinc bromide solution 0.5 M in THF Alkyl
C7H13BrZn
498718 1-Ethylpentylzinc bromide solution 0.5 M in THF Alkyl
C7H15BrZn
498696 1-Methylhexylzinc bromide solution 0.5 M in THF Alkyl
C7H15BrZn
498726 1-Propylbutylzinc bromide solution 0.5 M in THF Alkyl
C7H15BrZn
533270 Heptylzinc bromide solution 0.5 M in THF Alkyl
C7H15BrZn
520322 2-Cyanobenzylzinc bromide solution 0.5 M in THF Alkyl
C8H6BrNZn
517372 3-Cyanobenzylzinc bromide solution 0.5 M in THF Alkyl
C8H6BrNZn
517380 4-Cyanobenzylzinc bromide solution 0.5 M in THF Alkyl
C8H6BrNZn
561045 3-(Trifluoromethyl)benzylzinc chloride solution 0.5 M in THF Alkyl
C8H6ClF3Zn
499390 1-Phenylvinylzinc bromide solution 0.5 M in THF Alkenyl
C8H7BrZn
630357 2-Acetoxyphenylzinc iodide 0.5 M in THF Aryl
C8H7IO2Zn
630373 3-Acetoxyphenylzinc iodide solution 0.5 M in THF Aryl
C8H7IO2Zn
630365 4-Acetoxyphenylzinc iodide solution 0.5 M in THF Aryl
C8H7IO2Zn
533394 5-Bromo-2-methoxybenzylzinc chloride solution 0.5 M in THF Alkyl
C8H8BrClOZn
498777 α-Methylbenzylzinc bromide solution 0.5 M in THF Alkyl
C8H9BrZn
499307 Phenethylzinc bromide solution 0.5 M in THF Alkyl
C8H9BrZn
498785 2-Methoxybenzylzinc chloride solution 0.5 M in THF Alkyl
C8H9ClOZn
498793 3-Methoxybenzylzinc chloride solution 0.5 M in THF Alkyl
C8H9ClOZn
498807 4-Methoxybenzylzinc chloride solution 0.5 M in THF Alkyl
C8H9ClOZn
533564 5-Ethoxycarbonyl-2-fufurylzinc chloride solution 0.5 M in THF Heteroaryl
C8H9ClO3Zn
498866 2-Methylbenzylzinc chloride solution 0.5 M in THF Alkyl
C8H9ClZn
498874 3-Methylbenzylzinc chloride solution 0.5 M in THF Alkyl
C8H9ClZn
498882 4-Methylbenzylzinc chloride solution 0.5 M in THF Alkyl
C8H9ClZn
498378 2,3-Dimethylphenylzinc iodide solution 0.5 M in THF Aryl
C8H9IZn
498386 2,4-Dimethylphenylzinc iodide solution 0.5 M in THF Aryl
C8H9IZn
498394 2,5-Dimethylphenylzinc iodide solution 0.5 M in THF Aryl
C8H9IZn
498408 2,6-Dimethylphenylzinc iodide solution 0.5 M in THF Aryl
C8H9IZn
498564 2-Ethylphenylzinc iodide solution 0.5 M in THF Aryl
C8H9IZn
498416 3,4-Dimethylphenylzinc iodide solution 0.5 M in THF Aryl
C8H9IZn
498424 3,5-Dimethylphenylzinc iodide solution 0.5 M in THF Aryl
C8H9IZn
498505 6-Ethoxy-6-oxohexylzinc bromide solution 0.5 M in THF Alkyl
C8H15BrO2Zn
498556 2-Ethylhexylzinc bromide solution 0.5 M in THF Alkyl
C8H17BrZn
520470 2-(Ethoxycarbonyl)phenylzinc bromide solution 0.5 M in THF Aryl
C9H9BrO2Zn
520284 4-(Ethoxycarbonyl)phenylzinc bromide solution 0.5 M in THF Aryl
C9H9BrO2Zn
498467 3-(Ethoxycarbonyl)phenylzinc iodide solution 0.5 M in THF Aryl
C9H9IO2Zn
498475 4-(Ethoxycarbonyl)phenylzinc iodide solution 0.5 M in THF Aryl
C9H9IO2Zn
499447 2-Ethoxybenzylzinc chloride solution 0.5 M in THF Alkyl
C9H11ClOZn
499455 4-Ethoxybenzylzinc chloride solution 0.5 M in THF Alkyl
C9H11ClOZn
533319 2,5-Dimethoxybenzylzinc chloride solution 0.5 M in THF Alkyl
C9H11ClO2Zn
533327 3,4-Dimethoxybenzylzinc chloride solution 0.5 M in THF Alkyl
C9H11ClO2Zn
533335 3,5-Dimethoxybenzylzinc chloride solution 0.5 M in THF Alkyl
C9H11ClO2Zn
499358 2-Isopropylphenylzinc iodide solution 0.5 M in THF Aryl
C9H11IZn
499366 4-Isopropylphenylzinc iodide solution 0.5 M in THF Aryl
C9H11IZn
499048 1-Naphthylzinc iodide solution 0.5 M in THF Aryl
C10H7IZn
714356 2-Bromo-3-hexyl-5-thienylzinc bromide solution 0.5 M in THF Heteroaryl
C10H14Br2SZn
497606 1-Adamantylzinc bromide solution 0.5 M in THF Alkyl
C10H15BrZn
497614 2-Adamantylzinc bromide solution 0.5 M in THF Alkyl
C10H15BrZn
499021 (2-Naphthylmethyl)zinc bromide solution 0.5 M in THF Alkyl
C11H9BrZn
710296 4-[(4-Morpholino)methyl]phenylzinc iodide solution 0.25 M in THF Aryl
C11H14INOZn
524727 4-Biphenylzinc bromide solution 0.5 M in THF Aryl
C12H9BrZn
630411 2-Biphenylzinc iodide solution 0.5 M in THF Aryl
C12H9IZn