Titanium

Sigma-Aldrich offers titanium complexes with a variety of organic ligands to form useful titanium catalysts for organic synthesis. For example, CpTiCl3 has been employed as an effective titanium catalyst for room-temperature heterocycle annulation reactions. Whereas the conversion of electron-deficient olefins to diastereomerically pure 7-hydroxynorbornenes and methyl acrylates to highly substituted norbornene derivatives employs titanocene dichloride and bis(methylcyclopentadienyl)titanium dichloride as the titanium catalysts.

Search below for the titanium catalysts to fit your research needs.

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204749 Ammonium hexafluorotitanate 99.99% trace metals basis H8F6N2Ti
256552 Barium titanate(IV) powder, 99.995% trace metals basis BaO3Ti
467634 Barium titanate(IV) nanopowder (cubic crystalline phase), <100 nm particle size (BET), ≥99% trace metals basis BaO3Ti
342939 Barium titanate(IV) pieces, 3-12 mm, 99.8% trace metals basis BaO3Ti
338842 Barium titanate(IV) powder, <2 μm, 99.5% trace metals basis BaO3Ti
208108 Barium titanate(IV) powder, <3 μm, 99% BaO3Ti
346926 Bis(2,4-cyclopentadien-1-yl)[(4-methylbicyclo[2.2.1]heptane-2,3-diyl)methylene]titanium(IV) C19H24Ti
416681 Bis(cyclopentadienyl)titanium(IV) bis(trifluoromethanesulfonate) 98% C12H10F6O6S2Ti
234826 Bis(cyclopentadienyl)titanium(IV) dichloride 97% C10H10Cl2Ti
710415 Bis(isopropylcyclopentadienyl)titanium dichloride 95% C16H22Cl2Ti
250627 Chlorotriisopropoxytitanium(IV) 95% C9H21ClO3Ti
252670 Chlorotriisopropoxytitanium(IV) solution 1.0 M in hexanes C9H21ClO3Ti
234834 Cyclopentadienyltitanium(IV) trichloride 97% C5H5Cl3Ti
461822 Dichlorobis(indenyl)titanium(IV) C18H14Cl2Ti
497436 Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]titanium(IV) C20H24Cl2Ti
38433 Diisopropoxytitanium bis(acetylacetonate) solution purum, ~75% in isopropanol C16H28O6Ti
668214 3-Hydroxy-1,2-propanedioxytitanium dichloride, polymer-bound 100-200 mesh, extent of labeling: 0.5-1.5 mmol/g Ti loading  
749249 Oxobis(2,2,6,6-tetramethyl-3,5-heptanedionato)titanium(IV) 95% C22H38O5Ti
308382 Potassium hexafluorotitanate(IV) F6K2Ti
14007 Potassium titanium oxide oxalate dihydrate ≥98% Ti basis C4K2O9Ti · 2H2O
401307 Sodium metatitanate −200 mesh Na2O7Ti3
517011 Strontium titanate nanopowder, <100 nm particle size, 99% trace metals basis O3SrTi
396141 Strontium titanate powder, 99% O3SrTi
638161 Strontium titanate single crystal substrate, <111>, 99.99% trace metals basis O3SrTi
634689 Strontium titanate single crystal substrate, <100> O3SrTi
469866 Tetrakis(diethylamido)titanium(IV) 99.999% trace metals basis C16H40N4Ti
407399 Tetrakis(diethylamido)titanium(IV) technical grade C16H40N4Ti
725536 Tetrakis(diethylamido)titanium(IV) packaged for use in deposition systems C16H40N4Ti
388165 Titanium(IV) bis(ammonium lactato)dihydroxide solution 50 wt. % in H2O C6H18N2O8Ti
307793 Titanium(IV) bromide 98% Br4Ti
244112 Titanium(IV) butoxide reagent grade, 97% C16H36O4Ti
86910 Titanium(IV) butoxide purum, ≥97.0% (gravimetric) C16H36O4Ti
462551 Titanium(IV) tert-butoxide deposition grade C16H36O4Ti
510718 Titanium(IV) butoxide, polymer  
514381 Titanium(III) chloride ≥99.995% trace metals basis Cl3Ti
14010 Titanium(III) chloride solution ≥12% TiCl3 basis Cl3Ti
643394 Titanium(III) chloride solution ~10 wt. % in 20-30 wt. % hydrochloric acid Cl3Ti
254312 Titanium(IV) chloride ≥99.995% trace metals basis Cl4Ti
208566 Titanium(IV) chloride ReagentPlus®, 99.9% trace metals basis Cl4Ti
404985 Titanium(IV) chloride solution 0.09 M in 20% HCl Cl4Ti
249866 Titanium(IV) chloride solution 1.0 M in methylene chloride Cl4Ti
345695 Titanium(IV) chloride solution 1.0 M in toluene Cl4Ti
460702 Titanium(III) chloride tetrahydrofuran complex (1:3) 97% C12H24Cl3O3Ti
395404 Titanium(IV) chloride tetrahydrofuran complex 97% C8H16Cl4O2Ti
325252 Titanium diisopropoxide bis(acetylacetonate) 75 wt. % in isopropanol C16H28O6Ti
494143 Titanium(IV) diisopropoxidebis(2,2,6,6-tetramethyl-3,5-heptanedionate) 99.99% C28H52O6Ti
86710 Titanium(IV) ethoxide C8H20O4Ti
244759 Titanium(IV) ethoxide technical grade C8H20O4Ti
333484 Titanium(IV) 2-ethylhexyloxide 95% C32H68O4Ti
399817 Titanium(III) fluoride F3Ti
333239 Titanium(IV) fluoride F4Ti
209279 Titanium(II) hydride −325 mesh, 98% Green Alternative H2Ti
377996 Titanium(IV) isopropoxide 99.999% trace metals basis C12H28O4Ti
205273 Titanium(IV) isopropoxide 97% C12H28O4Ti
87560 Titanium(IV) isopropoxide ≥97.0% C12H28O4Ti
687502 Titanium(IV) isopropoxide packaged for use in deposition systems C12H28O4Ti
463582 Titanium(IV) methoxide ≥99.99% trace metals basis C4H12O4Ti
404950 Titanium(IV) methoxide 95% C4H12O4Ti
89502 Titanium(II) oxide coating quality, granular, 99.5% OTi
379174 Titanium(II) oxide pieces, ≥99.5% trace metals basis OTi
481041 Titanium(II) oxide powder, −325 mesh, 99.9% trace metals basis OTi
481033 Titanium(III) oxide −100 mesh, 99.9% trace metals basis O3Ti2
677469 Titanium(IV) oxide contains 1% Mn as dopant, nanopowder, <100 nm particle size (BET), ≥97% O2Ti
204730 Titanium(IV) oxide, rutile 99.995% trace metals basis O2Ti
204757 Titanium(IV) oxide, rutile ≥99.98% trace metals basis O2Ti
224227 Titanium(IV) oxide, rutile powder, <5 μm, ≥99.9% trace metals basis O2Ti
330833 Titanium(IV) oxyacetylacetonate 90% C10H14O5Ti
14023 Titanium(IV) oxysulfate ≥29% Ti (as TiO2) basis, technical O5STi · xH2O
495379 Titanium(IV) oxysulfate solution ~15 wt. % in dilute sulfuric acid, 99.99% trace metals basis O5STi
333980 Titanium(IV) oxysulfate - sulfuric acid hydrate synthesis grade  
89532 Titanium(IV) oxysulfate - sulfuric acid solution 27-31% H2SO4 basis, for the detection of H2O2 and ether peroxides O5STi · xH2SO4
253081 Titanium(IV) propoxide 98% C12H28O4Ti
641731 Titanium silicon oxide nanopowder, <50 nm particle size (BET), 99.8% trace metals basis O4SiTi
495182 Titanium(III) sulfate solution ~45 wt. % in dilute sulfuric acid, ≥99.9% trace metals basis O12S3Ti2
333492 Titanium(IV) sulfide powder, -200 mesh, 99.9% S2Ti
697079 Titanium tetrachloride packaged for use in deposition systems Cl4Ti
388173 Titanium(IV) (triethanolaminato)isopropoxide solution 80 wt. % in isopropanol C9H19NO4Ti
760854 Trichloro[hydrotris(pyrazol-1-yl)borato]titanium(IV) 97% C9H10BCl3N6Ti
446289 Trichloro(pentamethylcyclopentadienyl)titanium(IV) 97% C10H15Cl3Ti
421073   TYZOR® 131 organic titanate