cataCXium® Catalysts

cataCXium Ligands are highly effective ligands for palladium catalyzed cross-coupling reactions. Di-adamantylalkylphosphine, called cataCXium A, is a bulky and electron rich phosphine ligand used for Heck and Suzuki coupling, Buchwald-Hartwig amination of arylchlorides, and a-arylation reactions of ketones. In reactions, the catalysts are used with low catalyst loadings under mild conditions. Recently, another class of basic, sterically hindered phosphines featuring phosphino-substituted N-aryl pyrroles (cataCXium P) has shown high catalyst turnover numbers for the Suzuki coupling of both electron rich and electron deficient aryl chlorides.
cataCXium A and P

Product #

Image

Description

Molecular Formula

Add to Cart

691100 (9-Benzyl-9-fluorenyl)dicyclohexylphosphonium tetrafluoroborate 95% C32H38BF4P
671916 trans-Bis(acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II) 98% C46H46O4P2Pd2
672785 (9-Butyl-9-fluorenyl)dicyclohexylphosphonium tetrafluoroborate 97% C29H40BF4P
671479 cataCXium® A 95% C24H39P
671800 Di(1-adamantyl)benzylphosphine 95% C27H37P
671584 Di(1-adamantyl)-n-butylphosphine hydriodide 95% C24H40IP
672564 2-(Di-tert-butylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole 95% C19H28NOP
672343 2-(Di-tert-butylphosphino)-1-phenylindole 95% C22H28NP
672661 2-(Di-tert-butyl-phosphino)-1-phenyl-1H-pyrrole 95% C18H26NP
688681 Dicyclohexyl[9-(3-phenylpropyl)-9-fluorenyl]phosphonium tetrafluoroborate 95% C34H42BF4P
672459 2-(Dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole 95% C23H32NOP
672246 2-(Dicyclohexylphosphino)-1-phenylindole 95% (NMR) C26H32NP
672017 2-(Dicyclohexylphosphino)-1-phenyl-1H-pyrrole 95% C22H30NP
672122 2-(Dicyclohexylphosphino)-1-(2,4,6-trimethyl-phenyl)-1H-imidazole 95% C24H35N2P
688800 Dicyclohexyl-{2-sulfo-9-[3-(4-sulfo-phenyl)propyl]-9-fluorenyl}phosphonium-hydrogensulfate 95% C34H43O10PS3